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Application of the “quadrupolar Carr–Purcell Meiboom–Gill” (QCPMG) sequence permits the first natural abundance solid-state 25Mg NMR study of an organometallic magnesium compound, bis(cyclopentadienyl)magnesium. Analytical and numerical simulations of both static and magic-angle spinning QCPMG NMR spectra beget an axially symmetric 25Mg electric field gradient (EFG) tensor (quadrupolar asymmetry parameter, ηQ=0.01(1)) with a nuclear quadrupole coupling constant of CQ=5.80(5) MHz. Restricted Hartree–Fock and hybrid density functional theory (B3LYP) calculations are in good agreement with experimental EFG values and predict a chemical shielding anisotropy of about 40–50 ppm, which we attempt to elucidate by numerical simulations. The parameters and orientation of the 25Mg EFG tensor are rationalized from examination of the crystal structure and molecular symmetry. The NMR properties of the cyclopentadienyl rings are examined by 13C{1H} CPMAS NMR, RHF and hybrid-DFT (B3LYP) calculations, and simulations of the effects of chemical exchange on the 13C powder pattern. [Copyright &y& Elsevier]