1. Sub-ppm-Level Ammonia Detection Using Photoacoustic Spectroscopy with an Optical Microphone Based on a Phase Interferometer
- Author
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Oscar E. Bonilla-Manrique, Julio E. Posada-Roman, Jose A. Garcia-Souto, and Marta Ruiz-Llata
- Subjects
photoacoustic spectroscopy ,gas detection ,optical microphone ,resonant cell ,membrane ,Chemical technology ,TP1-1185 - Abstract
A sensitive optical microphone for photoacoustic spectroscopy based on the common path topology of a fibre laser Doppler vibrometer (FLDV) using phase-generated carrier demodulation and a slim diaphragm as an acoustic wave transducer was demonstrated. A resonant gas cell was adapted to enhance gas-detection performance and simultaneously provide efficient cancellation of the window background acoustic signal. Ammonia (NH3) was selected as the target gas. The absorption line was experimentally identified using a distributed feedback laser diode emitting at 1530 nm. The linearity and sensitivity of the gas sensor were measured using wavelength modulation spectroscopy with second harmonic detection. A Teflon diaphragm was used to implement the optical microphone, along with the FLDV, showing a minimum detectable pressure of 79.5 μPa/Hz1/2. The noise-equivalent absorption sensitivity for NH3 detection at the absorption line at 1531.7 nm was 1.85 × 10−8 W cm−1 Hz−1/2, and the limit of detection was 785 ppbv.
- Published
- 2019
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