1. Uniform dispersion of SiC in Yb-filled skutterudite nanocomposites with high thermoelectric and mechanical performance
- Author
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Jianlin Li, Akira Kawasaki, Zhenxing Zhou, Wan Jiang, Xiaofang Lu, Qihao Zhang, Yuchi Fan, Keiko Kikuchi, Naoyuki Nomura, Shengjie Fan, and Lianjun Wang
- Subjects
010302 applied physics ,Materials science ,Phonon scattering ,Mechanical Engineering ,Machinability ,Metals and Alloys ,Spark plasma sintering ,02 engineering and technology ,engineering.material ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Cryogenic grinding ,Thermoelectric materials ,01 natural sciences ,Mechanics of Materials ,Seebeck coefficient ,0103 physical sciences ,Thermoelectric effect ,engineering ,General Materials Science ,Skutterudite ,Composite material ,0210 nano-technology - Abstract
Although filled skutterudites are very promising thermoelectric (TE) materials at intermediate temperature, most of the high-performance skutterudites reported are multiple-filled materials that tend to have poor stability and machinability. Here, we successfully fabricate single-filled skutterudite based composites with uniformly dispersed β-SiC nanoparticles via cryogenic grinding and spark plasma sintering. The nanocomposites show not only increased Seebeck coefficient owing to a possible energy filtering effect, but also reduced lattice thermal conductivity through enhanced phonon scattering. A maximum ZT value of 1.42 at 850 K with greatly improved mechanical properties is achieved, which is very attractive for the application in TE devices.
- Published
- 2019
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