1. Kinked silicon nanowires-enabled interweaving electrode configuration for lithium-ion batteries.
- Author
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Sandu G, Coulombier M, Kumar V, Kassa HG, Avram I, Ye R, Stopin A, Bonifazi D, Gohy JF, Leclère P, Gonze X, Pardoen T, Vlad A, and Melinte S
- Abstract
A tri-dimensional interweaving kinked silicon nanowires (k-SiNWs) assembly, with a Ni current collector co-integrated, is evaluated as electrode configuration for lithium ion batteries. The large-scale fabrication of k-SiNWs is based on a procedure for continuous metal assisted chemical etching of Si, supported by a chemical peeling step that enables the reuse of the Si substrate. The kinks are triggered by a simple, repetitive etch-quench sequence in a HF and H
2 O2 -based etchant. We find that the inter-locking frameworks of k-SiNWs and multi-walled carbon nanotubes exhibit beneficial mechanical properties with a foam-like behavior amplified by the kinks and a suitable porosity for a minimal electrode deformation upon Li insertion. In addition, ionic liquid electrolyte systems associated with the integrated Ni current collector repress the detrimental effects related to the Si-Li alloying reaction, enabling high cycling stability with 80% capacity retention (1695 mAh/gSi ) after 100 cycles. Areal capacities of 2.42 mAh/cm2 (1276 mAh/gelectrode ) can be achieved at the maximum evaluated thickness (corresponding to 1.3 mgSi /cm2 ). This work emphasizes the versatility of the metal assisted chemical etching for the synthesis of advanced Si nanostructures for high performance lithium ion battery electrodes.- Published
- 2018
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