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Geopolymer is an environment friendly construction material that could be synthesized using either the natural source or the industrial byproducts such as flyash and GGBS. The characteristics of the Geopolymer rely on the proportion of the flyash and GGBS and the concentration of the activator solution used. In this research work, the effect of partial replacement of flyash with GGBS in proportions such as 0, 10, 20, 30 and 40% is investigated. Also Molarity of NaOH are tested from 8 to 14 M and both the parameters are optimized. In this optimized Geopolymer concrete, the utilization of iron slag as a partial substitute for river sand in various proportions such as 10, 15, 20, 25, 30 35, 40 and 45% are investigated. The optimized Geopolymer concrete with iron slag is investigated for its performance as a paver block with incorporation of banana fiber in proportions such as 0, 0.5, 1 and 1.5 and is compared with conventional cement concrete paver block. The results show that there is a significant enhancement in the properties of Geopolymer concrete with the different levels of optimization and the utilization of natural banana fiber. The developed sustainable paver block was found to with stand medium traffic conditions as per IS 15658:2006. Further this study employed random forest (RF) algorithm for the prediction of compressive strength of geopolymer concrete specimens for the variable parameters such as molarity of alkaline solution, Flyash/GGBS ratio and partial replacement of river sand with iron slag. The performance evaluation parameters represented high accuracy of developed RF model. This research work unleashes a heft potential of Geopolymer concrete to develop economical eco-friendly sustainable paver blocks to the society through mitigation of environmental strain on the ecosystem. [ABSTRACT FROM AUTHOR]

Geopolymer is an environment friendly construction material that could be synthesized using either the natural source or the industrial byproducts such as flyash and GGBS. The characteristics of the Geopolymer rely on the proportion of the flyash and GGBS and the concentration of the activator solution used. In this research work, the effect of partial replacement of flyash with GGBS in proportions such as 0, 10, 20, 30 and 40% is investigated. Also Molarity of NaOH are tested from 8 to 14 M and both the parameters are optimized. In this optimized Geopolymer concrete, the utilization of iron slag as a partial substitute for river sand in various proportions such as 10, 15, 20, 25, 30 35, 40 and 45% are investigated. The optimized Geopolymer concrete with iron slag is investigated for its performance as a paver block with incorporation of banana fiber in proportions such as 0, 0.5, 1 and 1.5 and is compared with conventional cement concrete paver block. The results show that there is a significant enhancement in the properties of Geopolymer concrete with the different levels of optimization and the utilization of natural banana fiber. The developed sustainable paver block was found to with stand medium traffic conditions as per IS 15658:2006. Further this study employed random forest (RF) algorithm for the prediction of compressive strength of geopolymer concrete specimens for the variable parameters such as molarity of alkaline solution, Flyash/GGBS ratio and partial replacement of river sand with iron slag. The performance evaluation parameters represented high accuracy of developed RF model. This research work unleashes a heft potential of Geopolymer concrete to develop economical eco-friendly sustainable paver blocks to the society through mitigation of environmental strain on the ecosystem. [ABSTRACT FROM AUTHOR]

Advanced and eco-friendly construction materials are being developed to reduce pollution and improve wastewater treatment efficiency. One such material is a photocatalytic nanocomposite that uses industrial wastes and natural substances to eliminate pollution. A recent study explored using an inorganic polymer composite (FM) made from a mixture of 70% fly ash and 30% metakaolin, with sodium hydroxide and sodium silicate as an alkali activator. The study evaluated the mechanical and hydration characteristics of the FM composite after 28 days in 100% humidity at room temperature. The study also examined the effect of adding 2.5 wt.% of Nano-TiO2 to FM composite and how it affects its properties. Results indicate that adding Nano-TiO2 to FM composite enhances its mechanical, antibacterial, and photocatalytic capabilities. Specifically, FM-TiO2 composite showed 90% removal of reactive blue 19 dye effluent in sunlight after 90 min, making it an excellent choice for sustainable wastewater treatment. This study presents a cost-effective, eco-friendly solution to wastewater treatment, with added antimicrobial properties from Nano-TiO2. [ABSTRACT FROM AUTHOR]

Geopolymer is an environment friendly construction material that could be synthesized using either the natural source or the industrial byproducts such as flyash and GGBS. The characteristics of the Geopolymer rely on the proportion of the flyash and GGBS and the concentration of the activator solution used. In this research work, the effect of partial replacement of flyash with GGBS in proportions such as 0, 10, 20, 30 and 40% is investigated. Also Molarity of NaOH are tested from 8 to 14 M and both the parameters are optimized. In this optimized Geopolymer concrete, the utilization of iron slag as a partial substitute for river sand in various proportions such as 10, 15, 20, 25, 30 35, 40 and 45% are investigated. The optimized Geopolymer concrete with iron slag is investigated for its performance as a paver block with incorporation of banana fiber in proportions such as 0, 0.5, 1 and 1.5 and is compared with conventional cement concrete paver block. The results show that there is a significant enhancement in the properties of Geopolymer concrete with the different levels of optimization and the utilization of natural banana fiber. The developed sustainable paver block was found to with stand medium traffic conditions as per IS 15658:2006. Further this study employed random forest (RF) algorithm for the prediction of compressive strength of geopolymer concrete specimens for the variable parameters such as molarity of alkaline solution, Flyash/GGBS ratio and partial replacement of river sand with iron slag. The performance evaluation parameters represented high accuracy of developed RF model. This research work unleashes a heft potential of Geopolymer concrete to develop economical eco-friendly sustainable paver blocks to the society through mitigation of environmental strain on the ecosystem. [ABSTRACT FROM AUTHOR]

The discharging of lead-contaminated wastewater is a concern because of its toxicity to living organisms and water quality resulting in dangerous water consumption, so it is highly recommended to remove lead from wastewater to be below water quality standards for a safe environment. Zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) were synthesized and characterized in various techniques. Their lead removal efficiencies were investigated by batch experiments, adsorption isotherms, and kinetics. The specific surface area, pore volume, and pore size of ZB were close values to zeolite A standard (STD), and ZBF had the highest specific surface area and the smallest pore size than others. ZB and ZBF demonstrated crystalline phases whereas ZBB, ZBFB, and ZBBF were amorphous phases. The surface morphology of ZB was a cubic shape similar to STD. ZBF demonstrated an agglomerated formation of ZB and iron(III) oxide-hydroxide whereas ZBFB and ZBBF had sphere shapes with coarse surfaces. Si, Al, O, Fe, Na, Ca, O–H, (Si, Al)–O, H2O, and D4R were detected in all materials. The surface charges of all zeolite A materials had negatively charged at all pH values, and their surfaces increased more negatively charged with increasing pH value which pH 5 illustrated as the highest negatively charged in all materials. Their lead removal efficiencies were higher than 82%. Langmuir isotherm and pseudo-second-order kinetic models were well explained for their adsorption patterns and mechanisms. Finally, ZBBF is a good offer for applying in industrial wastewater treatment systems because of its easy operation and saving costs than ZBF. [ABSTRACT FROM AUTHOR]

The discharging of lead-contaminated wastewater is a concern because of its toxicity to living organisms and water quality resulting in dangerous water consumption, so it is highly recommended to remove lead from wastewater to be below water quality standards for a safe environment. Zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) were synthesized and characterized in various techniques. Their lead removal efficiencies were investigated by batch experiments, adsorption isotherms, and kinetics. The specific surface area, pore volume, and pore size of ZB were close values to zeolite A standard (STD), and ZBF had the highest specific surface area and the smallest pore size than others. ZB and ZBF demonstrated crystalline phases whereas ZBB, ZBFB, and ZBBF were amorphous phases. The surface morphology of ZB was a cubic shape similar to STD. ZBF demonstrated an agglomerated formation of ZB and iron(III) oxide-hydroxide whereas ZBFB and ZBBF had sphere shapes with coarse surfaces. Si, Al, O, Fe, Na, Ca, O–H, (Si, Al)–O, H2O, and D4R were detected in all materials. The surface charges of all zeolite A materials had negatively charged at all pH values, and their surfaces increased more negatively charged with increasing pH value which pH 5 illustrated as the highest negatively charged in all materials. Their lead removal efficiencies were higher than 82%. Langmuir isotherm and pseudo-second-order kinetic models were well explained for their adsorption patterns and mechanisms. Finally, ZBBF is a good offer for applying in industrial wastewater treatment systems because of its easy operation and saving costs than ZBF. [ABSTRACT FROM AUTHOR]

Gold mine tailings, fly ash, and bagasse ash has been repurposed to produce geopolymer (GP) with enhanced electromagnetic interference shielding efficiency (EMI-SE) and high thermal property. GP has low shielding efficiency compared to concrete. Due to this, an appropriate filler must be incorporated into its matrix to enhance its EMI-SE. For this study, bismuth oxide nanomaterial (BiNP) was utilized as the additive filler. The percent content of BiNP was varied to evaluate its influence on the EMI-SE of GP. Morphology shows that Bi2O3 was embedded in the matrix of GP, and no new aluminu-phyllosilicate minerals were formed. This indicates that some minerals acted only as internal fillers in the matrix. Compressive strength shows synthesized GP composites were more than 20 MPa, with neat GP reaching the maximum strength. Moreover, the EMI-SE of neat GP was 21.2 dB for 20–4500 MHz range. This indicates that GP alone has sufficient characteristics to attenuate EMI radiation. Addition of 5%, 10% and 15% weight of BiNP improves EMI-SE by 4–10%, with 5% BiNP shown to be the optimum ratio. Lastly, the addition of BiNP improves the thermal stability of GP. This study shows that GP incorporated with Bi2O3 can be recommended for small-scale construction and small residential building. [ABSTRACT FROM AUTHOR]

To reduce the filling cost of high-water backfilling material (HWBM) in mining backfill and improve the recycling utilization of the industrial waste such as the coal fly ash. The ultra-fine fly ash (UFA) was added to the HWBM as a partial replacement in this work. Therefore, a series of experiments were performed to investigate the effect of UFA on the mechanical properties of the HWBM at the different curing conditions, then the hydration mechanism of the HWBM blended with UFA was analyzed by XRD and SEM method. The result indicates that the strength of the HWBM decreased with the increasing of UFA dosages, but the addition of UFA can improve the residual strength of the initial HWBM. Additionally, when the HWBM was cured at the laboratory air condition, its carbonation process was restrained obviously as the UFA dosages were less than 15% at the ages of 28 days, which indicates the UFA can improve the weathering resistance of the HWBM with the curing ages increasing effectively. The XRD and SEM results also shows that the degree of crystallinity of the HWBM increased when UFA dosages were less than 15% effectively, while there were few obvious changes on types of hydration products. It indicates that the main affects of UFA on the performance of HWBM is filler and dilution, which reduced the contact area between hydration products of HWBM and CO2 in the air, further improved the carbonation resistance of HWBM. [ABSTRACT FROM AUTHOR]

A new adsorbent with chromium removal function was synthesized by carbon thermal method using iron-containing waste Fenton sludge and carbon-containing solid waste fly ash to treat high pH scoring wastewater generated from industrial processes. The results showed that the adsorbent used T = 273.15 K, pH = 10, t = 1200 min, C0 = 100 mg/L, had a removal rate of Cr(VI) of more than 80%, and the adsorption capacity could reach 393.79 mg/g. The characterization results show that the synthesized mesoporous nitrogen-doped composite material has a large specific surface area and mesoporous structure, and the surface of the material is rich in oxygen-containing functional groups and active sites. Compared with other studies, the adsorption capacity of the material is larger, which indicates that the removal effect of Cr(VI) in this study is better. The adsorption kinetic results show that the adsorption follows a pseudo second kinetic model, and the adsorption process is a chemisorption involving electron sharing or electron exchange. This experiment designed a simple method to synthesize mesoporous nitrogen-doped composites using industrial solid waste, with raw materials from cheap and easily available industrial solid waste, and solved the dual problems of heavy metals in wastewater and solid waste, providing a new idea for the resource utilization of Fenton sludge while not producing secondary pollution. [ABSTRACT FROM AUTHOR]

One-part alkali-activated materials (AAMs) are developed to improve conventional two-part systems. One-part AAMs technology has been used in cement binders to produce concrete, mortar, and paste. Current research mainly focuses on synthesizing raw materials obtained from industrial and agricultural waste as the main aluminosilicate precursors of the cement binder for a concrete application. The one-part AAMs were reported to have higher early compressive strength at 7 days of age, contributed by its fast-setting time, mainly when the binder activates by a higher dosage of alkaline activator and containing OPC-rich. Due to bonding issues, single or combination, FA/GGBFS/MK precursors were reported as unsuitable for use as a concrete repair material. They were the reason for the lack of one-part AAMs application of mortar compared to concrete usage. This study was conducted to determine the potential of one-part AAMs used as concrete patch mortar by investigating its rheology and mechanical properties. The compressive strength of the mortar was tested under lab ambient temperature in the tropical climate country of Malaysia. The setting time of fresh mortar and bonding strength were set under controlled lab temperature. The one-part alkali-activated mortar was composed of hybrid aluminosilicate precursors between fly ash (FA), Ground Granulated Blast Furnace Slag (GGBFS) and ordinary Portland cement (OPC). A low alkaline activator of solid potassium carbonate was used for the geopolymerization process. Three types of solid admixtures were added to complete the composition of the new mix design. The experiment's outcome showed that the mortar composed with the combination of conventional Portland cement and industrial waste products has compressive and pull-off adherence strength that meets with Class R3—EN1504-3 standard for structural concrete repair materials requirement. [ABSTRACT FROM AUTHOR]

The Congo Red dye was removed from a simulated textile wastewater solution using fly ash from a local power plant. The characterisation of fly ash was studied in detail by SEM, EDX, XRD, FTIR, BET surface area and TGA techniques. The influence of four parameters (contact time, initial concentration, adsorbent dose, and temperature) was analysed, the results showing that the adsorption capacity depends on these parameters. Thermodynamic and regeneration investigations as well are presented. The fit to pseudo-second-order kinetics models suggests that the removal process is a chemical adsorption. The Langmuir model fitted the experimental data, with a maximum adsorption capacity of 22.12 mg/g. The research is a preliminary case study that highlights that fly ash posed a very good potential as a material for Congo Red dye removal. [ABSTRACT FROM AUTHOR]

Heavy metals are perceived as a significant environmental concern because of their toxic effect, bioaccumulation, and persistence. In this work, a novel sodium alginate (SA) and carboxymethylcellulose (CMC) entrapped with fly ash derived zeolite stabilized nano zero-valent iron and nickel (ZFN) (SA/CMC-ZFN), followed by crosslinking with CaCl2, is synthesized and applied for remediation of Cu(II) and Cr(VI) from industrial effluent. The characterization of the adsorbent and its surface mechanism for removing metals were investigated using advanced instrumental techniques, including XRD, FT-IR, SEM–EDX, BET, and XPS. The outcomes from the batch experiments indicated that monolayer adsorption on homogeneous surfaces (Langmuir isotherm model) was the rate-limiting step in both heavy metals sorption processes. The maximum adsorption capacity of as-prepared SA/CMC-ZFN was 63.29 and 10.15 mg/g for Cu(II) and Cr(VI), respectively. Owing to the fact that the wastewater released from industries are large and continuous, a continuous column is installed for simultaneous removal of heavy metal ions from real industrial wastewater. The outcomes revealed the potential of SA/CMC-ZFN as an efficient adsorbent. The experimental breakthrough curves fitted well with the theoretical values of Thomas and Yoon-Nelson models. Overall, the results indicated that SA/CMC-ZFN is a viable, efficient, and cost-effective water treatment both interms of batch and column processes. [ABSTRACT FROM AUTHOR]