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Pteris vittata (P. vittata) possesses significant potential in remediating arsenic (As) soil pollution. Understanding the habitat suitability of P. vittata in China and pinpointing the key drivers that influence its distribution can facilitate the identification of optimal areas for using P. vittata as a remediation tool for As-polluted soils. In this study, a comparative analysis was conducted using ten machine learning models to assess the habitat suitability of P. vittata based on 744 specimen records and 20 environmental factors. The key drivers affecting the distribution of P. vittata were also investigated based on the optimal model. The results indicate that the XGBOOST model was the most reliable and stable, achieving a coefficient of determination of 0.95. Approximately 24.47 % of China's land area was identified as suitable for P. vittata. Particularly, it was predominantly found in Hainan (45.9 %), Guangxi (92.96 %), Guangdong (91.68 %), Hunan (91.26 %), Guizhou (90.83 %), Chongqing (88.17 %), Fujian (85.70 %), Yunnan (77.44 %), Jiangxi (73.99 %) and Zhejiang (57.05 %). Furthermore, this study pinpointed the lowest temperature, annual temperature range, and mining density as key drivers, contributing 45.9 %, 31.9 %, and 7.2 %, respectively. Spatial correlation analysis revealed a significant correlation between mining density and the habitat distribution of P. vittata (Moran' I = 0.519). This study confirmed that both natural factors and anthropogenic activities affect the distribution of P. vittata and provided valuable insights for optimizing the application of P. vittata in soil phytoremediation and reclamation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)

Groundwater recharge is a viable solution to groundwater overexploitation. However, the injection of recharge water may break the dissolution balance and induce the release of trace elements especially arsenic (As), which has been identified in river deltas. Only a few studies have been conducted in inland basins with high As concentration, high pH, and low Eh. Aiming to analyze As release with groundwater recharge in inland high-As regions and determine the effects of coexisting ions in recharge water, this study established PHase Equilibria Calculation (PHREEQC) models using rainwater and groundwater data from three inland sedimentary basins with slow groundwater flow in semi-arid regions. The simulations fitted with the batch experiments, achieving an R-squared (R 2 ) of 0.98. The coexisting ions in the recharge water significantly affected As release during recharge. Ca 2+ inhibited the release of total arsenic (Total-As) by increasing the surface charge of iron oxides. NO 3 - inhibited Total-As release by promoting the conversion of trivalent As into pentavalent As. Conversely, HCO 3 - facilitated As release by competing with arsenate for adsorption sites. On the basis of the modeling and batch experiment results, Total-As release with groundwater recharge was predicted. The results indicated that the high Ca 2+ concentration in the recharge water inhibited the As release by 83.5 %, which can be used as a strategy to control As release during groundwater recharge in high-As inland basins., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Diagnostic features in near-infrared reflectance spectroscopy (NIRS) are the foundation of knowledge-based approach of petroleum hydrocarbon determination. However, a significant challenge arises when analyzing samples with low levels of petroleum hydrocarbon pollution, as they often lack distinctive diagnostic features in their sample NIRS spectra, limiting the effectiveness of this approach. To address this issue, we have developed a technical workflow for diagnostic spectrum construction and parameterization based on spectral subtraction. This method was applied on a set of NIRS spectra from soil samples that were contaminated with petroleum hydrocarbons (ranged between 178 and 1716 mg/kg of total petroleum hydrocarbon). Then two diagnostic features for low-level petroleum hydrocarbon pollution were found: (1) An overall downward concave emerged on diagnostic spectrum within both 2290-2370 nm and 1700-1780 nm for all low pollution levels even below 200 mg/kg; (2) An indicative pattern of asymmetric "W-shaped" double absorption valley occurred for those exceeding 1000 mg/kg, and its valleys located near 2310 nm, 2348 nm or 1727 nm, 1762 nm stably. These two features on diagnostic spectrum could be parameterized to detect, and the detection limit was at least about 10-50 times lower than that based on sample spectrum. These findings update our understanding on the detectability of spectral response from low petroleum hydrocarbon pollution, and widely extend the application of knowledge-based NIRS approach in either field detection or remote sensing identification for environmental management., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)

Microplastics (MPs), a new type of pollutant, have attracted much attention worldwide. MPs are often complexed with other pollutants such as heavy metals, resulting in combined toxicity to organisms in the environment. Studies on the combined toxicity of MPs and heavy metals have usually focused on the marine, while on the freshwater are lacking. In order to understand the combined toxic effects of MPs and heavy metals in the freshwater, five typical MPs (PVC, PE, PP, PS, PET) were selected to investigate the adsorption characteristics of MPs to Pb 2+ before and after the MPs aging by ultraviolet (UV) irradiation through static adsorption tests. The results showed that UV aging enhanced adsorption of Pb 2+ by MPs. It is noteworthy that MPs-PET had the highest adsorption capacity for Pb 2+ , and the interaction between MPs-PET and Pb 2+ was the strongest. We specifically selected MPs-PET to study its combined toxicity with Pb 2+ to Chlorella pyrenoidosa. In the combined toxicity test, MPs-PET and Pb 2+ had significant toxic effects on Chlorella pyrenoidosa in the individual exposure, and the toxicity of individual Pb 2+ exposure was greater than that of individual MPs-PET exposure. In the combined exposure, when MPs-PET and Pb 2+ without adsorption (MPs-PET/Pb 2+ ), MPs-PET and Pb 2+ had a synergistic effect, which would produce strong physical and chemical stress on Chlorella pyrenoidosa simultaneously, and the toxic effect was the most significant. After the adsorption of MPs-PET and Pb 2+ (MPs-PET@Pb 2+ ), the concentration and activity of Pb 2+ decreased due to the adsorption and fixation of MPs-PET, and the chemical stress on Chlorella pyrenoidosa was reduced, but the physical stress of MPs-PET still existed and posed a serious threat to the survival of Chlorella pyrenoidosa. This study has provided a theoretical basis for further assessment of the potential environmental risks of MPs in combination with other pollutants such as heavy metals., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Soil contamination by multimetals is widespread. Hyperaccumulator-crop intercropping has been confirmed to be an effective method for arsenic (As)- or cadmium (Cd)-contaminated soil that can achieve soil cleanup and agricultural production. However, the influencing factors and response of hyperaccumulator-crop intercropping to multimetal-contaminated soil are still unclear. In this study, intercropping of the As hyperaccumulator Pteris vittata and maize was conducted on two typical types of multimetal-contaminated soil, namely, Soil A contaminated by As, Cd, and lead (Pb) and Soil B contaminated by As, Cd, and chromium (Cr). Intercropping reduced As, Cd, and Pb in the maize grains by 60 %, 66.7 %, and 20.4 %, respectively. The concentrations of As, Cd, Pb, and Cr in P. vittata increased by 314 %, 300 %, 447.3 %, and 232.6 %, respectively, relative to their concentrations in the monoculture plants. Two soils with different levels of contamination showed that higher heavy metal content might diminish the ability of intercropping to reduce soil heavy metal risk. No notable difference in soil microbial diversity was found between the intercropped and monocultured plants. The composition of microbial communities of intercropping groups were more similar to those of monoculture P. vittata on two different soils (Soils A and B). An imbalance between the amount of As taken up by the plants and the reduction in As in the soil was observed, and this imbalance may be related to watering, As leaching, and heterogeneity of soil As distribution. Reducing the risk resulting from As leaching and enhancing the efficiency of phytoextraction should be emphasized in remediation practices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

When precious nano-metals are used as environmental catalysts, it is important to tune the particle sizes and the reusability of the nano-metals for achieving their highly efficient catalytic performance at a low cost. In the present work, magnetic iron oxides (FeO x -Y) nanoparticles were pre-prepared as supports of nano-metals, where Y represented the mole percentage of Fe(III) in the total iron (Y ≥ 50 %). FeO x -Y (support), PdCl 4 2- (Pd source) and NaBH 4 (reducing agent) were added into the organic pollutant solution containing 2,2',4,4'-tetrabromodiphenyl ether (BDE47). After the NaBH 4 was added, the followed reaction realized not only the rapid in-situ preparation of a Pd-loaded FeO x -Y composite catalyst (Pd-FeO x -Y), but also the ultra-fast and complete debromination of BDE47 within 30 s. Comparing the case without adding FeO x -Y, the debromination efficiency of BDE47 was much promoted in the presence of FeO x -Y. The support-induced enhancing effect on the catalytic ability of Pd nanoparticles was improved by increasing the Fe(III) content in the support, being attributed to the much more hydroxyl groups on the support surface. Considering both the catalytic and recovery abilities of Pd-FeO x -Y, Pd-FeO x -75 was the optimal choice because it could be magnetically recovered and re-used for multiple cycles with high catalytic activities. The presently developed "catalyst preparation-pollutant degradation" one-pot system could be applied to conduct complete debromination of all the PBDEs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

Pteris vittata L. (PV), an arsenic (As) hyperaccumulator, has a potential to extract As from As-polluted soils. Since available As in soils can be taken up by PV, As fraction variation associated rhizosphere environmental characteristics caused by municipal sewage sludge compost (MSSC) could provide possible to strengthen As phytoextraction by PV. In this study, the mechanism of phytoextraction of PV aided by MSSC was revealed from aspect of environmental characteristics of rhizosphere soils and physiological properties of PV. The effect of MSSC on available As in soils was investigated by soil incubation experiment. Furthermore, the influences of MSSC on enzymes activities, communities of soil bacteria and fungi, As concentrations, and As fraction in rhizosphere soils of PV were explored, and then the biomass and As accumulation of PV were examined by greenhouse pot experiments. After 90 days, available As in soil incubation experiment significantly increased by 32.63 %, 43.05 %, and 36.84 % under 2 %, 5 %, and 10 % treatment, respectively, compared with control treatment. Moreover, As concentrations in rhizosphere soils of PV under 2 %, 5 %, and 10 % treatment decreased by 4.62 %, 8.68 %, and 7.47 %, respectively, compared with control treatment. The available nutrients and enzyme activities in rhizosphere soils of PVs were improved under the MSSC treatment. Affected by MSSC, the dominant phylum and genus for both bacterial and fungal communities didn't change, but their relative abundance increased. Additionally, MSSC significantly increased biomass of PV with corresponding mean ranging from 2.82 to 3.42 g in shoot and 1.82 to 1.89 g in root, respectively. And the concentrations of As in shoot and root of PV treated by MSSC increased by 29.04 %-144.7 % and 26.34 %-81.78 %, respectively, in relative to control. The results of this study provided a basis for MSSC-strengthened phytoremediation for As-polluted soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Comprehensive analysis of spatiotemporal distribution characteristics of potentially toxic elements (PTEs) in soils of China, and associated driving mechanism and health risks is crucial for soil pollution prevention and risk control. In this study, a total of 8 PTEs in agricultural soils of 236 city case data from 31 provinces of China were collected from literatures published between 2000 and 2022. The pollution level, dominant drivers and probabilistic health risks of PTEs were analyzed using geo-accumulation index (I geo ), geo-detector model, and Monte Carlo simulation, respectively. The results indicated a notably accumulation of Cd and Hg, with I geo of 1.13 and 0.63, respectively. Cd, Hg and Pb showed strong spatial heterogeneity, whereas As, Cr, Cu, Ni, and Zn has no significant differentiation. PM 10 was the dominant driver for accumulation of Cd (0.248), Cu (0.141), Pb (0.108), and Zn (0.232), and PM 2.5 has a significant effect on accumulation of Hg (0.245); however, soil parent material was primary driver for accumulation of As (0.066), Cr (0.113), and Ni (0.149). PM 10 ∩ wind speed accounted for 72.6 % of Cd accumulation, and mining industry ∩ soil parent materials for 54.7 % of As accumulation. Approximately 38.53 %, 23.90 %, and 12.08 % of the hazard index values exceeded 1 for the minors aged 3- < 6, 6- < 12, and 12- < 18 years, respectively; whereas approximately 0.22 %, 0.21 %, 0.20 %, 0.54 % and 0.42 % of the carcinogenic risk values were greater than 1E-04 for individuals aged 3- < 6, 6- < 12, 12- < 18, 18- < 44, and 44- < 70 years, respectively. As and Cd were considered as priority elements for soil pollution prevention and risk control in China. Moreover, the hotspots of PTE pollution and associated health risks were mainly observed in southern, southwestern and central China. The results of this study provided a scientific basis for developing strategies for pollution prevention and risk control of soil PTEs in China., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Investigation of heavy metal pollution degree, pollution sources, and spatial distribution structure is crucial for the country's soil pollution prevention, but relevant research is lacking. In this study, As, Cd, Cr, Cu, Pb and Zn in the national scope are taken as research objects. Among them, Cd has the highest pollution level. Four sources were quantitatively allocated as soil type, mining and dressing industry, GDP, and NDVI, which accounted for 92.93, 97.81, 99.30 and 96.24 % of Cr, Cd, Zn and As contamination, respectively. In addition, according to the geographical detector, the spatial distribution of As was affected by three diffusion pathways, whose influence degree were 0.822-0.947, especially the slope. Cadmium was primarily affected by both receptor attributes and diffusion pathways, with an influence degree of 0.010-0.175, especially soil water content and slope; Cr and Pb were affected by receptor attributes, with an influence degree of 0.886-0.986 and 0.007-0.288, respectively, especially for soil water content and soil organic carbon; Cu and Zn were affected by receptor attributes, with an influence degree of 0.182-0.823 and 0.002-0.150, respectively, especially for soil texture. There are two spatial distribution structures with nested scales in east-west and north-south directions. The large spatial structure has a more significant impact on the spatial distribution of heavy metals, especially in the east-west direction. Overall, the mining and dressing industry is the main source in Hunan, Yunnan, and Liaoning, where many mines exist and mining activities are frequent. GDP was the main source in Shanghai and Zhejiang areas, where the economy is developed. NDVI was the main source in Guangdong and Anhui areas, where agriculture is relatively developed. These results provide a basis for determining remediation and prevention objectives in soil pollution remediation and prevention in the national scope., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

Organic waste comprises a large amount of hydrocarbon containing organic substances, which is regarded as a potential resource rather than simply a waste. A field experiment was conducted in a poly-metallic mining area to investigate the potential of organic waste to facilitate the soil remediation process. Different organic wastes and a commonly used commercial fertilizer were added to heavy metal contaminated soil, which was under phytoremediation using the As hyperaccumulator Pteris vittata. The influence of diverse fertilizer regimes on the biomass of P. vittata and heavy metal removal by P. vittata, was investigated. The soil properties were analyzed after the application of phytoremediation with or without the addition of organic wastes. Results indicated that sewage sludge compost is an appropriate amendment to improve the phytoremediation efficiency. Compared to the control, the application of sewage sludge compost significantly reduced the extractability of As in soil by 26.8 %, and increased the removal of As and Pb by 26.9 % and 186.5 %, respectively. The highest removal of As and Pb reached 33 and 34 kg/ha, respectively. The sewage sludge compost-strengthened phytoremediation improved soil quality. And the diversity and richness of the bacterial community were improved, as represented by the increase in Shannon and Chao index. With improved efficiency and acceptable cost, the organic waste-strengthened phytoremediation can be used to control the risks posed by high concentrations of heavy metals in mining areas., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

The lateral transport of heavy metals can expand the scope of original contamination, and an accurate prediction of heavy metal migration is necessary to control heavy metal transport. However, previous studies have mainly focused on the migration of soil pollutants in the runoff-soil-groundwater system, whereas research on the lateral migration of heavy metals in surface soil driven by rainfall is relatively scarce. Therefore, in this study we analyzed the horizontal migration of water-soluble heavy metals with surface runoff and non-water-soluble heavy metals with sediment particles, investigated the main factors affecting the processes of runoff and sediment transport and the main factors affecting the mobility of heavy metals in soils, summarized the existing methods for the simulation of heavy metal transportation. The construction of a lateral migration model based on the migration mechanism of soil heavy metals, the hydrological model, and the application of the lateral migration model should be the focus of future research. This study provides a theoretical basis for establishing a model of the lateral migration of soil heavy metals and is of great significance for the prevention and control of the risks related to the lateral migration of soil heavy metals., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

The existing spatial interpolation methods in the prediction of soil heavy metal distribution are generally based on spatial auto correlation theory, rarely considering the pollution patterns. By contrast, in polluted sites, heavy metals have a strong heterogeneity even within a very small area, which is not exactly in line with auto correlation theory. This contradiction may lead to inaccuracy in spatial prediction. Atmospheric diffusion and deposition are one of the main sources of soil heavy metal pollution caused by coal-related production activities. To improve the prediction accuracy, the diffusion patterns of pollutants were considered in this paper by integrating Geodetector, Co-Kriging (COK), and partition interpolation. Geodetector was used to identify the main driving factors of soil pollution, based on which, the main driving factors were used as covariates introduced into the interpolation method (COK). Specifically, the amount of particulate matter deposition obtained by a pollutant diffusion model (AERMOD) was used as a covariate. For comparison, the distances to quenching, coke oven, and ammonium sulfate section were also used as covariates. Compared with the Ordinary Kriging method, the method COK-AERMOD established here decreased the root mean square error values of As (2.05 reduced to 1.89), Cd (0.18 reduced to 0.16), Cr (19.07 reduced to 12.97), Cu (6.92 reduced to 4.72), Hg (0.32 reduced to 0.28), Ni (16.92 reduced to 16.10), Pb (18.29 reduced to 16.62), and Zn (159.68 reduced to 153.66). This method in this paper is informative for the interpolation of soil elements in contaminated areas with known pollution source and diffusion patterns., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Due to the public health concern of arsenic, environmental management measures in mining areas had been implemented. To assess the effect of environmental management measures in the mining area comprehensively, arsenic accumulation in the urine, hair, nails, and urinary metabolites of residents in a realgar mining area in Hunan province, China were investigated in 2019, and the changes in arsenic levels in the biomarkers during 2012-2019 were tracked. The importance of confounding factors (age, sex, occupation, residence, clinical history, vegetable source, cooking fuel, smoking, alcohol consumption, BMI) was analyzed using the Boruta algorithm. After the implementation of environmental management measures (including ceasing mining and smelting activities, building landfills, adjusting the planting structure, and soil restoration), urine, hair, and nail arsenic concentration decreased drastically but were still excessive. Arsenic accumulation was highest in older male miners who were long settled in the mining area and consumed homegrown vegetables. The only factor for changes in urinary arsenic levels was the cooking fuel type; residents using wood as cooking fuel experienced sustained arsenic exposure. Occupation and sex were important for determining arsenic changes in the hair and nails. Short-term arsenic accumulation in urine was affected by arsenic exposure, while long-term accumulation in hair and nails by arsenic metabolic capacity. The percentage of urinary arsenic metabolism and arsenic methylation indices of the participants in the mining area were within the normal range (%iAs: 10-30 %, %MMA: 10-20 %, % DMA: 60-80 %); samples indicated worse metabolic capacity than the reference population. The arsenic metabolic capacity of male miners was relatively weak, probably aggravated by alcohol drinking and smoking. Without soil remediation, arsenic exposure will continue. Homegrown vegetables and biomass fuels should be abandoned; reduced cigarette and alcohol consumption is recommended. Urinary arsenic would be more proper for assessing environmental remediation in mining areas., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Phytoremediation is an effective way to remove metals from contaminated soil, and selecting remediation plants suitable for climate conditions is a prerequisite for effective phytoremediation. In this study, a MaxEnt model was applied to investigate the potential distribution and habitat suitability of three Cd-accumulating plants in China- Sedum alfredii, Phytolacca americana, and Hylotelephium spectabile and explore the key environmental factors that affect their habitat suitability. A total of 44 environmental parameters, including bioclimatic variables, altitude, and soil property parameters were used. The results showed that: (1) For S. alfredii, suitable areas account for 14.9 % of the area of China, which are mainly distributed in the middle and lower reaches of the Yangtze River. (2) The suitable areas of P. americana account for 22.7 % of China and are mainly located in the regions of the Qinling Mountains and the south of China. (3) While that for H. spectabile are mainly located in the regions of northeastern China and certain regions of central China, with suitable areas account for 8.3 % of the area of China. (4) The distribution of these three plants is significantly affected by precipitation; specifically, solar radiation is an influential factor for the distribution of S. alfredii and H. spectabile, and temperature limits the distribution of P. americana. The selection and agronomic management of hyperaccumulators for phytoremediation requires multifactor consideration (e.g., climate, soil conditions and planting patterns). The results can provide guidance for identifying suitable areas for planting these three accumulating plants, which could not only prevent the unscientific cultivation of them in unsuitable habitats but also enhance the efficiency of phytoremediation. Meanwhile, these findings are expected to contribute to agronomic management for improved phytoremediation effects in different Cd-contaminated regions of China., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier B.V.)

Intercropping of arsenic (As) hyperaccumulator (Pteris vittata L.) with crops can reduce the As concentration in soil and the resulting ecological and health risks, while maintaining certain economic benefits. However, it is still unclear how As-transforming functional bacteria and dominant bacteria in the rhizosphere of P. vittata affect the microbial properties of crop rhizosphere soil, as well as how As concentration and speciation change in crop rhizosphere soil under intercropping. This is of great significance for understanding the biogeochemical cycle of As in soil and crops. This study aimed to use high-throughput sequencing and quantitative polymerase chain reaction (qPCR) to analyze the effects of different rhizosphere isolation patterns on the bacterial diversity and the copy number of As-transforming functional genes in pomegranate (Punica granatum L.) rhizosphere soil. The results showed that the abundance of bacteria in the rhizosphere soil of pomegranate increased by 16.3 %, and the soil bacterial community structure significantly changed. C&#95;Alphaproteobacteria and o&#95;Rhizobiales bacteria significantly accumulated in the rhizosphere of pomegranate. The copy number of As methylation (arsM) gene in pomegranate rhizosphere soil significantly increased by 63.37 %. The concentrations of nonspecifically sorbed As (F1), As associated with amorphous Fe (hydr)oxides (F3), and the total As (FT) decreased; the proportion of As (III) in pomegranate rhizosphere soil decreased; and the proportion of As (V) increased in pomegranate rhizosphere soil. c&#95;Alphaproteobacteria and o&#95;Rhizobiales accumulated in crop rhizosphere soil under the intercropping of P. vittata with crops. Also, the copy number of As methylation functional genes in crop rhizosphere soil significantly increased, which could reduce As (III) proportion in crop rhizosphere soil. These changes favored simultaneous agricultural production and soil remediation. The results provided the theoretical basis and practical guidance for the safe utilization of As-contaminated soil in the intercropping of As-hyperaccumulator and cash crops., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier B.V.)

The arsenic (As) hyperaccumulator has become a model plant for the study of the interaction between plants and trace elements. However, the change in As concentration, distribution and speciation of hyperaccumulator Pteris vittata at different growth stages, especially with the aging process remains unknown. We collected P. vittata at different growth ages and analyzed As concentration, distribution, and speciation. Furthermore, metabolic profiling was conducted for P. vittata at different growth stages. With aging, the reduced glutathione/ oxidized glutathione ratio decreased while the malondialdehyde content increased, accompanied by the change in the main As speciation in P. vittata from arsenite to arsenate. Metabolic profiling also indicated significant difference in the compositions of metabolites during different growth stages. Specifically, flavonoid compounds were found to be positively correlated with As concentration. Results indicated that with the aging of P. vittata, the redox potential increased in the pinnae, leading to the oxidation of As, which may have impacted the distribution of As in this fern. Furthermore, the correlation between As concentration and flavonoid compounds implied the essential role of flavonoid metabolism in the accumulation and transport of As in this plant., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Manganese sulfide (MnS) has unique reactive abilities and can affect the fate and toxicity of contaminants in the natural environment, specifically sulfidic sediments that undergo biogeochemical changes due to natural and artificial processes. However, the effect of oxidization induced by the oxygenation of MnS on organic contaminants remains poorly understood. Herein, we revealed that the hydroxyl radical (HO·) was the dominant reactive oxidant for the rapid degradation of the assessed hydrophobic organic contaminants (including azo dye, nitroaromatic compounds, pesticide, and an endocrine disrupt chemical) during the oxygenation of MnS based on the competitive dynamic experiments, quenching experiments and electron spin resonance (ESR) methods. The removal rates of the assessed organic contaminants were significantly dependent on MnS dosage and co-solutes, including sediment humic acid, metal ions (Mn 2+ and Fe 3+ ), and inorganic anions (PO 4 3- and Cl - ). HO· scavenging by sulfide and its oxidation products (e.g., elemental sulfur), rather than dissolved Mn 2+ , was responsible for the low utilization efficiency of HO· for the assessed contaminants. The contribution of the manganese oxide (MnO 2 ) generated by the oxygenation of MnS to the examined degradation of contaminants could be neglected. Considered collectively, the reaction between H 2 O 2 and MnO 2 generated superoxide radicals (O 2 - ·) which dominated the generation of HO· in an oxic MnS suspension. The results suggest that the impact of oxidization induced by the oxygenation of MnS on environmental contaminants should be of concern in both natural and engineered systems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Roadside soils may be affected by potential toxicity elements (TPEs) from vehicles; however, pollution status, ecological and health risks of PTEs in roadside soils were rarely reported on national scale. In this study, a dataset of PTEs in roadside soils was compiled based on the literatures published in 2000-2021, and then pollution level, ecological and health risks of PTEs were evaluated using geochemical accumulation index (I geo ), potential ecological risk index (ER), and human risk assessment coupled with Monte Carlo simulation. Driving factors of PTE accumulation in soils were determined by Geo-detector method. Results indicated that Cd exhibited moderate pollution and considerable ecological risk with the highest I geo of 1.25 and ER of 100.1, respectively. Vehicle ownership (VP) and precipitation (PP) significantly affected accumulation of PTEs, with q values of 0.209 and 0.191 (P < 0.05), respectively. VP paired with PP enhanced nonlinearly PTE accumulation (q = 0.77). Only 6.89% and 1.54% of non-carcinogenic risks for children and adolescent exceeded the threshold of 1, respectively, whereas 93.11%, 95.67%, 58.80% and 58.14% of carcinogenic risks for senior, adults, adolescent, and children surpassed 1E-06, respectively. The results of this study provided valuable implication for managers to design effective strategies for pollution prevent and risk control., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Quantitative source apportionment of soil potential toxicity elements (PTEs) and associated driving factor identification are critical for prevention and control of soil PTEs. In this study, 421 soil samples from a typical area in southeastern Yunnan Province of China were collected to evaluate the pollution level of soil PTE using pollution factors, pollution load index, and enrichment factors. Positive matrix factorization (PMF), absolute principal component score/multiple line regression (APCS/MLR), edge analysis (UNMIX) and self-organizing map (SOM) were applied for source apportionment of soil PTEs. The geo-detector method (GDM) was used to identify the driving factor to PTE pollution sources, which assisted in source interpretation derived from receptor models. The results showed that the geometric mean of As, Cd, Cu, Cr, Ni, Pb, and Zn were 94.94, 1.02, 108.6, 75.40, 57.14, 160.2, and 200.3 mg/kg, which were significantly higher than their corresponding background values (P < 0.00). Particularly, As and Cd were 8.71 and 12.75 times higher than their corresponding background values, respectively. SOM yielded four clusters of soil PTEs: AsCd, PbZn, CrNi, and Cu. APCS/MLR was regarded as the preferred receptor model for source apportionment of soil PTEs due to its optimal performance. The results of ACPS/MLR revealed that 36.64% of Pb and 38.30% of Zn were related to traffic emissions, Cr (92.64%) and Ni (82.51%) to natural sources, As (85.83%) and Cd (87.04%) to industrial discharge, and Cu (42.78%) to agricultural activities. Distance to road, lithology, distance to industries, and land utilization were the respective major driving factor influencing these four sources, with the q values of 0.1213, 0.1032, 0.2295 and 0.1137, respectively. Additionally, GDM revealed that nonlinear interactions between anthropogenic and natural factors influencing PTEs sources. Based on these results, comprehensive prevention and control strategies should be considered for pollution prevention and risk controlling., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Soil enzymes are crucial for carbon and nutrient cycling and are highly sensitive to warming. Biochemical reaction rates increase with temperature according to the Arrhenius law, but changes in microbial physiology may partially counteract this warming-induced acceleration that leads enzymatic rates to deviate from Arrhenius law. Here, we attempt to reconcile disparate views on the enzyme responses to warming based on the Arrhenius law and physiological theory by enzyme catalytic efficiency. In this study, we tested the kinetic parameters of five key enzymes of C, N, and P cycling to warming (from 0 to 40 °C) in cropland soils originating from 5 different temperate zones. The soils were incubated for one month at 0, 10, 20, 30, and 40 °C (±0.5 °C) with 60% water holding capacity (WHC). The kinetic parameters were calculated and measured at a range of 4-methyumbelliferone (MUB)-substrate concentrations. We found that catalytic efficiency (V max /K m ) of individual enzymes ranged from 0.05 to 27 s -1 between 0 and 40 °C. Maximum reaction rate (V max ) increased with warming, while V max /K m of most enzymes remained stable by warming at low temperatures (up to 10 °C), and it raised from 20 to 40 °C. Most enzymes had lower substrate affinities (K m ) and increased their efficiency with warming. Consistent with studies considering Arrhenius law solely, the temperature sensitivity (Q 10 ) of V max decreased with warming. However, the Q 10 of V max /K m displayed a lower value in the cold but a higher value in warmer temperature, which confirmed microbial adaptation based on physiological theory, consequently encouraging its linking with the Arrhenius law. Therefore, Arrhenius linked with physiological theory could correct explanation of enzyme activities by warming. Considering the microbial adaptation to temperature, the present predicted warming-induced acceleration of soil organic matter decomposition might be overestimated in cold and underestimated in warm environments., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Understanding the source-specific human health risk of soil potential toxicity elements (PTEs) for human is beneficial for pollution control and risk prevention. Multivariate statistics, absolute principal component score/multiple linear regression (APCS/MLR) model, positive matrix factorization (PMF) model, and GIS mapping were used to identify and apportion the sources of soil PTEs in typical mining and industrial area, southwestern China. Furthermore, source-specific health risks were apportioned by combining source apportionment with probabilistic health risk assessment based on Monte Carlo simulation which can define the probability that the risk exceed the guideline threshold value. The pollution factor and geo-accumulation index indicated that the soils were polluted by soil PTEs to different degrees. In particular, As and Cd were the primary pollutants. Mixed sources, agricultural activities, mining activities, and As-related smelting activities represented the potential sources of soil PTEs, with the contribution of 30.13%, 25.78%, 22.93%, and 21.16%, respectively. Source-specific probabilistic health risks indicated that As-related smelting activities contributed the most to non-carcinogenic risks (adults: 59.03%, children: 57.20%) and carcinogenic risks (adults: 81.82%; children 92.33%), despite the observation that it contributed the least to the accumulation of soil PTEs (21.16%). Non-carcinogenic and carcinogenic risk showed similar trend for children and adults. Therefore, As-related smelting activities were regarded as the priority source of soil PTEs, and corresponding prevention and control strategies should be implemented to protect human health., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

The intercropping of hyperaccumulators and fruit trees has great application prospects owing to its environmental and economic benefits. However, the variation tendency and spatial distribution characteristics of pollutants in soil are unclear. A 19-month pot positioning experiment was conducted to clarify the spatio-temporal characteristics of arsenic (As) during Pteris vittata L.-Citrus reticulata Blanco intercropping process. The results showed that: (1) In the early stage, the solubilization of soil As by P. vittata was dominant. At 3 months, the water-soluble As in P. vittata rhizosphere soil increased by 19.4-55.4% compared with the initial state. In the later stage, the As extraction from soil by P. vittata was dominant. At 19 months, the water-soluble As in P. vittata rhizosphere soil decreased by 24.6-71.2% compared with the initial state. The water-soluble As in C. reticulata rhizosphere soil in intercropping, under the role of P. vittata, reached 1.75-2.35 times that of monoculture at 7 months, and was not significantly different from that of monoculture at 19 months. (2) The spatial distribution characteristics of soil As, affected by As-hyperaccumulation of P. vittata, showed that the As variability of intercropping and P. vittata monoculture was greater than that of C. reticulata monoculture. The area of P. vittata remediating soil was approximately 15 cm horizontally around its planting point and at least 25 cm vertically. (3) P. vittata-C. reticulata intercropping did not affect the phytoremediation efficiency and effectively reduced the risk of As pollution for C. reticulata. The As concentration in C. reticulata leaves of open intercropping decreased by 39.0-64.2% (early-maturity) and 25.6-59.1% (late-maturity) compared with that of monoculture, similar to that in clean soil. This study analyzed the As migration characteristics during P. vittata-C. reticulata intercropping through time and space and provides important theoretical support for the remediation and safe use of As-contaminated farmland., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Plant roots generally enhance soil strength and stabilize slopes through hydro-mechanical effects, especially in forested areas prone to shallow slope failure. Forest fires can severely weaken the hydro-mechanical contribution of roots to slopes, however, the hydro-mechanical characteristics of soil-root systems (SRS) affected by wildfire remain poorly understood. To obtain insight into the post-fire hydro-mechanical characteristics of SRS, a subalpine conifer forested area in Sichuan Province, China that suffered a wildfire on March 30, 2019 was continuously monitored over two consecutive years. Samples from zones with different degrees of burn severity were collected and tests both for roots and SRS were performed. The results revealed a substantial decline in root number, which decreased by 46%-58% two years after the wildfire in the medium- and high-severity areas. The tensile strength tests indicated a reduction of root tensile strength by 36%-47% for roots with diameters less than 2 mm. The shear strength of the SRS determined from saturated direct shear tests strongly and had degraded by 55%-82% two years after the wildfire because of root death and reduced root reinforcement. The results of hydraulic conductivity tests over the same time period indicated an abrupt reduction of SRS hydraulic conductivity within several months after the fire owing to ash clogging and the formation of a hydrophobic layer. After more time had elapsed, however, hydraulic conductivity had increased unexpectedly by a factor of 2.2-3.2 greater than that of unburned soil. We attribute this observation to the formation of macropore flow pathways from decayed roots, which was observed by scanning electron microscopy. The findings presented here provide important insight into the temporal changes of the hydro-mechanical characteristics of SRS in burned areas and their associated mechanisms and could be a useful reference to better evaluate post-wildfire stability of subalpine conifer forest in similar environmental conditions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Identifying the inflection points and main influencing factors for arsenic (As) accumulation in Pteris vittata L. under field conditions is important to improve the phytoremediation efficiency. In this study, data on the entire growth cycle (270 days) of P. vittata over a year were recorded through a field trial. The results showed that the As accumulation characteristics of P. vittata were obviously different from those observed in greenhouse experiments. The aboveground biomass of P. vittata began to stabilize on day 180; the As concentration increased to a peak on day 90 and subsequently declined until day 180. The As accumulation was 318.11 g/hm 2 after 120 days, reaching 96.7% of the highest value predicted by the logistic model. The results indicated that soil humidity is the key influencing factor for As accumulation by P. vittata. Increasing the soil humidity can substantially improve the As extraction efficiency. Based on the results of As accumulation in P. vittata, it could be suggested that the effect of As efflux on P. vittata was not significant. According to theoretical calculations, the total As loss caused by rainfall leaching accounted for less than 2.2% of the total As accumulation. The parameters obtained herein are significant for guiding the remediation of As-contaminated soils under similar climatic conditions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Boundary layer height (BLH) plays an important role in regulating global weather/climate, as well as the dispersion and transportation of pollutants. Until now, however, the attribution and contributions of different controlling factors to BLH long-term variability and trends have not been quantified on a global scale. The long-term radiosonde dataset was used in this study to retrieve global BLH climatology; seasonal, diurnal, long-term variation and trends were analyzed over a 39-year period (1980-2018). Statistical results show that the global distribution of the BLH and its trend have apparent day-night differences. BLH during daytime is deeper during clear-sky conditions compared to cloudy sky conditions, indicating a significant effect of clouds; BLH during nighttime is deeper under cloudy conditions. BLH was also found to vary over different land types; dry and hot soil exhibits a deeper BLH than those of wet and cool soil. The long-term variation and trend of BLH are highly influenced by near-surface meteorological parameters. In particular, based on multiple linear stepwise regression models and the contribution calculation method, this investigation initiatively quantifies the influences of meteorological parameters on global BLH long-term variation and trend. Our results emphasized that a 10 m wind speed (WS) and low tropospheric stability (LTS) have significant contributions to long-term BLH variation; WS and LTS anomalies alternately dominated the contribution of the diurnal cycle of the BLH anomaly. Annual BLH recorded an average increasing trend (38.9-42.1 m/decade), and LTS is more dominant than WS from a contribution perspective, especially for increased BLH anomaly. Contributions from near-surface temperature (T) and relative humidity (RH) also play important roles. However, a decreasing WS trend dominated the decreased trends of BLH anomaly, accounting for nearly 40% of the total contribution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

The fine particulate matter (PM 2.5 ) emitted by burning biomass has become the main source of pollution in cities; this pollution seriously threatens the ecosystem and inhabitants' health. A major challenge in dealing with this issue is the uncertainty regarding the influence of burning biomass on PM 2.5 regional transport. In this study, Harbin-Changchun Megalopolis is the research area. Using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model combined with satellite data and PM 2.5 monitoring data, we quantitatively analyzed the regional transport of PM 2.5 from burning biomass upwind of each city under different emission conditions. Conditions at burn sites, especially emission intensity and meteorological factors, as well as transport distance play significant roles in the regional transport of PM 2.5 . Higher emission intensity aggravated the concentration of downwind PM 2.5 , at most 19.7 μg ⋅ m -3 . Shorter transport distance strengthened the impact of biomass burning on downstream PM 2.5 by weakening elimination, which could be up to 96.8 μg ⋅ m -3 . Moreover, meteorological factors at fire points were closely related to the transport of PM 2.5 . First, lower planetary boundary layer height could enhance the transport of PM 2.5 from the burning biomass by inhibiting vertical diffusion, and the enhancement could be up to 46.1 μg ⋅ m -3 . Second, compared to strong wind, light wind caused the weaker dilution, enhancing PM 2.5 regional transport by as much as 32.5 μg ⋅ m -3 . Third, relatively humidity at 30%-40% had the strongest effect in facilitating the transport of PM 2.5 from burning biomass. We conclude that comprehensively considering these three factors, namely the emission intensity, transport distance and meteorological factors at burn sites can facilitate the cross-regional development of accurate prediction models and effective pollution control measures., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

There is a growing recognition of the broader environmental significance of exploring the relative importance of climate change and anthropogenic impacts on hydrologic fluctuations in river-lake systems. In the case of Dongting Lake, the typical river-lake system, we collected the water level from 1990 to 2019, spanning before and after the operation of the Three Gorges Dam (TGD) in 2003. This study was conducted to detect water level fluctuations in Dongting Lake and to quantify the relative influence of climate, land cover and dam construction on water levels. We defined the impact of the dam construction as the three inlets inflow of Yangtze River (In-YR), and four waters inflow of Hunan (In-HN). The Mann-Kendall (M-K) test revealed the trends and change points of water level fluctuations. Structural Equation Model (SEM) was used to detect the direct and indirect effects of these factors on water level and quantify their relative importance. The MIKE21 hydrodynamic model reflected the spatial-temporal variability of water levels under the action of key driver. The results showed that the water level appeared a downward trend during 1990-2019 and the change point appeared in 2003; During 1990-2002, the significant factors were: precipitation (V = 0.469, P = 0.013), evaporation (V = -0.424, P = 0.029), non-agricultural cover (V = -0.334, P = 0.025), and agricultural cover (V = 0.235, P = 0.033); During 2003-2019, the significant factors were: In-YR (V = 0.436, P = 0.007), In-HN (V = 0.431, P = 0.012), and precipitation (V = 0.349, P = 0.045); The In-YR was the key factor affecting the changes of the water level during 1990-2019; Under the influence of In-YR, the most obvious fluctuation of water level was in the flood adjustment period (Jun-Aug) and the impoundment period (Sep-Nov) when the average declined by about 0.50 and 0.67 m, respectively. Our findings provide a new insight into how to better maintain the stability of river-water system water resources under the influence of multiple factors., Competing Interests: Declaration of competing interest There is no actual or potential conflict of interest including any financial, personal or other relationships with other people or organizations within five years of beginning the submitted work that could inappropriately influence, or be perceived to influence, their work., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Ranking assessment of potentially contaminated sites (PCS) provides a great quantity of information (namely the risk screening list) that is usually examined by environmental managers, and therefore reduces the cost of risk management in terms of site investigation. Here we propose an integrated assessment methodology to establish a risk screening list of PCS in China using the Choquet integral correlation coefficient (ICC), which takes the uncertainty and interaction of PCS attributes into explicit account. The proposed method globally considers the importance and ordered positions of PCS attributes while reflecting their overall ranking. The model evaluation and actual validation results demonstrate the success in PCS ranking by the proposed method, which is superior to other methods such as the intuitionistic fuzzy multiple attribute decision-making, the technique for order preference by similarity to an ideal solution, and the weighted average. The resulting spatial distribution of Choquet ICC indicates that high-attention PCS in China are mainly located in Guangdong, Jiangsu, Zhejiang, and Shandong Provinces. This study is the first attempt to conduct a ranking assessment of PCS across China. The proposed assessment method based on Choquet ICC offers a step towards establishing a risk screening list of PCS globally., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

For exploring the key factors affecting trace element accumulation in crops in limestone soil derived from limestone area of different stratums, the loquat (Eriobotrya japonica Lindl.) orchard of three limestone units (Middle Devonian, Upper Devonian and Middle Cambrian) in Mengzi city of Yunnan Province, China were investigated. Loquat fruits grown on soil from Middle Devonian limestone exhibited significantly higher bio-enrichment in cadmium. The Middle Devonian (Chemical Index of Alteration [CIA] = 86.07) and Upper Devonian (CIA = 84.84) soils were more weathered than those derived from Middle Cambrian rocks (CIA = 74.42). In the Middle Devonian limestone area, Fe element (for As uptake into fruit), Al element (for Cu and Zn) and metal speciation (for Cd, extracted by diethylene triamine pentaacetic acid) in the soil were the important influencing factors. For the Upper Devonian, soil weathering was found to be the key factors controlling fruit Cu uptake, respectively. For the Middle-Cambrian-derived soils, soil Ca concentration and pH played a critical role in Cd accumulation in fruit. In conclusion, under acidic soil conditions derived from limestone, the Ca concentration and metal fraction in the soil are the pivotal factors affecting Cd accumulation of fruit, whereas the soil Fe element content control the fruit As and Pb uptake. These results are helpful to further understand the migration regularity of trace elements into fruit in different limestone geology types., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Recycling the arsenic-rich biomass of Pteris vittata is a critical problem during phytoremediation primarily because of the low value and high risk of arsenic-rich biomass. Nevertheless, extracts of P. vittata have been found to have a variety of bio-activities (e.g., anti-oxidation, anti-cancer, and anti-bacterial) and abundant valuable bio-active compositions (e.g., flavonoids), which might present a new solution for the recycling of P. vittata harvests. This work demonstrated a pilot-scale experiment to extract and purify the phenolic compounds from 1 t of arsenic-rich P. vittata biomass. Result showed that 47.9 kg of phenolic-rich extract with a potential value of US$908.66-8345.14 was obtained. This extract showed no acute oral toxicities (LD 50  > 10 g/kg), no skin irritation, and no chronic risks in the long-term skin contact exposure pathways. All of the wastes from production have been recycled and safely disposed with low cost (US$28.44), and the cost may be further reduced. The calculated benefits from this method showed a potential to provide 995-53,050 US$/hm 2 per year to a phytoremediation project. Therefore, this strategy could address the issue of expensive phytoremediation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Air pollution and its resulting health risks in Beijing City have been widely investigated by scientists and administrators. However, the health risks caused by willow and poplar catkins in April and May (known as "spring snow") have been rarely reported. Poplar and willow are the two common trees in Beijing City that generate many whirling catkins in the air. The chemical composition of catkins remains unknown. In this study, catkins and dust samples were collected in several parks in Beijing. The total concentrations of metals/metalloids in catkins measured through inductively coupled plasma mass spectrometry were generally lower than those of the corresponding dust samples, and they were lower than the risk control standard for soil contamination of development land. The simulated rain and lung fluid extraction rates of catkin samples were significantly higher than those of the dust samples. The concentration of extracted Pb and Zn using simulated rainwater exceeded the environmental quality standards for surface water (0.1 and 2.0 mg/L for Pb and Zn, respectively), indicating the possibility of runoff pollution. Scanning electron microscopy images showed that fine particles (<10 μm) are attached to the surface of catkins. Therefore, the metals/metalloids in fine particles adsorbed by the catkin samples possess higher bioaccessibility than that in the dust samples based on different sizes of particles. A significant correlation is found between Pb in catkin and Pb in dust. Therefore, attention should be paid to the possible increase in metal/metalloid concentrations in catkins planted in contaminated areas., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

A stability-enhanced magnetic catalyst, composed of α-Fe 2 O 3 @Fe 3 O 4 shell-core magnetic nanoparticles and graphene oxide (MGO), was prepared and characterized by scanning electron micrope (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and Brunauer-Emmett-Teller (BET). Catalyst synthesis was used to efficiently activate persulfate for the removal of 2,4-dichlorophenol (2,4-DCP). A magnetic nanoparticle:GO mass ratio of 5 (MGO-5) exhibited a better catalytic efficiency and could be effectively reused four times. The influences of the pollutant, catalyst, and oxidant concentrations were investigated, and the intrinsic relationships among these factors and the degradation kinetic constant were evaluated by a fitting method. It was found that the catalytic degradation process in the MGO-5-persulfate-2,4-DCP system was most likely dominated by an interfacial catalytic reaction, with an activation energy of 13.88 kJ/mol. Radical quenching experiments and electron paramagnetic resonance (EPR) analysis indicated that both sulfate radicals (SO 4 - ) and hydroxyl radicals (OH) were responsible for 2,4-DCP removal, but surface-bounded SO 4 - played a greater role. Chloride ions at a concentration of 0-60 mg/L had no effect on 2,4-DCP removal. The proposed advanced oxidation technology has potential applications for the practical removal of aqueous organic pollutants., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Identifying and quantifying the major sources of atmospheric particulate matter (PM) is essential for the development of pollution mitigation strategies to protect public health. However, urban PM is affected by local primary emissions, transport, and secondary formation; therefore, advanced methods are needed to elucidate the complex sources and transport patterns. Here, an improved source apportionment method was developed by incorporating the receptor model, Lagrangian simulation, and emissions inventories to quantify PM 2.5 sources for an industrial city in China. PM 2.5 data including ions, metals, organic carbon, and elemental carbon were obtained by analyzing 1 year of sampling results at urban and rural sites. This method identified coal combustion (30.64%), fugitive dust (13.25%), and vehicles (12.51%) as major primary sources. Secondary sources, including sulfate, nitrate, and secondary organic aerosols also contributed strongly (25.28%-30.76% in total) over urban and rural areas. Hebei Province was the major regional source contributor (43.05%-57.51%) except for fugitive dust, on which Inner Mongolia had a greater impact (43.51%). The megacities of Beijing and Tianjin exerted strong regional impacts on the secondary nitrate and secondary organic aerosols factors, contributing 11.32% and 15.65%, respectively. Pollution events were driven largely by secondary inorganic aerosols, highlighting the importance of reducing precursor emissions at the regional scale, particularly in the Beijing-Tianjin-Hebei region. Overall, our results demonstrate that this novel method offers good flexibility and efficiency for quantifying PM 2.5 sources and regional contributions, and that it can be extended to other cities., (Copyright © 2018 Elsevier B.V. All rights reserved.)

With the rapid development of modern industry, heavy metals in the soil introduce the risk of serious pollution. To reduce this pollution risk, the following four research questions needed to be addressed: What are the main influencing factors of soil pollution? What is the degree of influence? Do factors operate independently or are they interconnected? Which regions have high pollution risk and should be paid more attention? The study area was in Huanjiang County, with 273 km 2 , and geographical detector proved to be a useful tool to solve these four problems. We found that mine activity and pH value were the primary influencing factors for total and water-soluble heavy metals. The interaction effects of mine activity and soil type, pH values, and normalized difference vegetation index (NDVI) for total heavy metals, as well as pH value and mine activity for water-soluble heavy metals, were greater than the sum effect of two factors. Zones with a high concentration of heavy metals were closer to the road and farther from the mine area, which had low NDVI, large slope, high terrain, and large pH values. Concentrations of total heavy metals were higher in calcareous soils and in dryland and forests. Zones with a higher concentration of water-soluble heavy metals were closer to the mine and river, which had lower DEM and pH values. The uncertainty of geographical detector was also analyzed on the basis of their interpolation accuracy and the stratification number of influencing factors, and we found that the existing sample numbers and the stratification number of influencing factors met the needs of geographical detector calculation. This study's conclusions are useful for soil pollution control and restoration., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Manganese oxides are naturally occurring powerful oxidants and scavengers, which can control the mobility and bioavailability of arsenic (As). However, the effect of synthetic nanostructured manganese oxides on the mobilization and transportation of As at actual paddy soils are poorly understood, especially in soils with low or medium background Mn concentration. In the present study, a novel nano manganese oxide with superior reactivity and surface area has been synthesized. A 90-d soil incubation experiment combined with pot and field rice cultivation trials were designed to evaluate the effectiveness of exogenous α-MnO 2 nanorods on the mobilization and transportation of As in soil-rice systems. Our results proved that the addition of α-MnO 2 nanorods can effectively control the soil-to-solution partitioning of As under anaerobic conditions. After treatment with different amounts of α-MnO 2 nanorods, the content of effective As decreased, offset by an increase in residual As and insoluble binding As (Ca-As and Fe-As). Enhancing the oxidation of As(III) into As(V), the α-MnO 2 nanorods increased the adsorption of As onto indigenous iron (hydr)oxides which greatly reduced the soil porewater As content. In addition, pot experiments and field applications revealed that the influx of As into the aerial parts of rice plants (stems, husk and leaves) was strictly prohibited after treatments with different amount of α-MnO 2 nanorods; more interestingly, significantly negative correlations have been observed between As and Mn in rice, which indicated that as Mn is increased in soil, As in brown rice decreases. Our results demonstrated that the use of α-MnO 2 nanorods in As polluted paddy soil containing low levels of background Mn oxides can be a promising remediation strategy., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Representative elementary volume (REV) is important to characterize dense nonaqueous phase liquids (DNAPLs) during surfactant-Enhanced aquifer remediation (SEAR) period. To investigate the REVs of DNAPL in remediation, a perchloroethylene (PCE) SEAR experiment is conducted in a two dimensional (2D) heterogeneous translucent porous media. Light transmission techniques are used to quantify PCE saturation (S oil ) and PCE-water interfacial area (A OW ). Afterward, corresponding REVs are estimated using a criterion of relative gradient error (ε g i ) to reveal the change of REVs of DNAPL over the entire remediation period. Results from this work suggest the presence of surface active agents strongly affect the REVs of DNAPL. At the beginning of the SEAR experiment, the frequency of minimum S oil -REV size closely follows a Gaussian distribution in 0.0mm-11.0mm. Simultaneously, the frequency of minimum A OW -REV size is close to a Gaussian distribution in 2.0mm-9.0mm and appears a peak value in 13.0mm-14.0mm. As SEAR experiment proceeds, both the shapes of frequency and cumulative frequency of REV sizes are changed. At the end of SEAR experiment, the frequency of minimum S oil -REV and minimum A OW -REV size tend to Gaussian distributions in 0.0mm-6.0mm and 0.0mm-9.0mm, respectively, which suggest both minimum S oil -REV size and minimum A OW -REV size show decreasing tendency. Continuous quantification of the REVs of DNAPL is realized in this study to reveal the change of REVs influenced by surface active agent. The finding has important significance on improving our understanding of the characteristics of DNAPL in SEAR process, simulating DNAPL remediation and designing appropriate remediation scheme with high-resolution., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Both humic acid and colloid particle size effectively regulate colloid transport. However, little is known about effect of particle size and configuration of humic acid colloid (HA colloid ) on enhanced-transport of ferrihydrite colloid (FH colloid ) in porous media. Co-transport of HA colloid and FH colloid at different pH was systematically investigated by monitoring breakthrough curves (BTCs) in saturated sand columns. The colloid transport model and the (X)DLVO theory were used to reveal the mechanism of HA colloid -enhanced FH colloid transport in the columns. Results showed that HA colloid enhanced FH colloid transport in neutral and alkaline conditions. In neutral conditions, small HA colloid (F-HA colloid ) with chain-shaped structure enhanced FH colloid transport more prominently than pristine granular HA colloid . The chain-shaped F-HA colloid caused osmotic repulsion and elastic-steric repulsion between colloids and sand, leading to enhanced transport. However, the granular HA colloid readily occurred as deposition due to attachment and straining, which decreased the enhanced transport of FH colloid . In alkaline conditions, both HA colloid and F-HA colloid were chain-shaped, with longer chains of HA colloid than F-HA colloid . Ferrihydrite colloid transport was enhanced by HA colloid more significantly than F-HA colloid due to stronger repulsion between mixed HA colloid -FH colloid and sand. It suggested that regulation of particle size and morphology of HA colloid would enhance FH colloid transport and further help in understanding FH colloid -facilitated contaminants transport in porous media., (Copyright © 2017 Elsevier B.V. All rights reserved.)

Leaf economics and hydraulic traits are simultaneously involved in the process of trading water for CO 2 , but the relationships between these two suites of traits remain ambiguous. Recently, Li et al. (2015) reported that leaf economics and hydraulic traits were decoupled in five tropical-subtropical forests in China. We tested the hypothesis that the relationships between economics and hydraulic traits may depend on water availability. We analysed five leaf economics traits, four hydraulic traits and anatomical structures of 47 woody species on the Loess Plateau with poor water availability and compared those data with Li et al. (2015) obtained in tropical-subtropical regions with adequate water. The results showed that plants on the Loess Plateau tend to have higher leaf tissue density (TD), leaf nitrogen concentrations and venation density (VD) and lower stomatal guard cell length (SL) and maximum stomatal conductance to water vapour (g wmax ). VD showed positive correlations with leaf nitrogen concentrations, palisade tissue thickness (PT) and ratio of palisade tissue thickness to spongy tissue thickness (PT/ST). Principal component analysis (PCA) showed a result opposite from those of tropical-subtropical regions: leaf economics and hydraulic traits were coupled on the Loess Plateau. A stable correlation between these two suites of traits may be more cost-effective on the Loess Plateau, where water availability is poor. The correlation of leaf economics and hydraulic traits may be a type of adaptation mechanism in arid conditions., (Copyright © 2017 Elsevier B.V. All rights reserved.)

Suspended substrate (SS) in natural waters controls the interaction, transportation, and biological effects of heavy metals in water bodies. The large amount of cadmium (Cd) carried by SS is an important source of Cd pollution in irrigation water. In this study, a novel procedure to remove trace Cd coexisting with SS from irrigation water by fertilizer flocculation was investigated. Four common fertilizers (K 2 HPO 4 , (NH 4 ) 2 HPO 4 , KH 2 PO 4 , and K 2 SO 4 ) were used as flocculants. Batch experiments with various fertilizers revealed that the removal efficiency followed the order: K 2 HPO 4 >(NH 4 ) 2 HPO 4 >KH 2 PO 4 >K 2 SO 4 . When levels of K 2 HPO 4 higher than 0.75g/L were applied, the total Cd decreased from 20 to 3.8μg/L after 12h of flocculation, i.e., the removal efficiency reached 80%. The mechanism analysis(Zeta potential, multi-element analysis) results demonstrated that the aggregation of SS and its sedimentation by K 2 HPO 4 were due to the combined effect of the oxidation of Fe 2+ to Fe 3+ and cation binding behavior towards SS, as a result of charge neutralization and electric double layer compression. This method of Cd removal from irrigation water is simple and has the potential to be applied in agricultural production., (Copyright © 2017. Published by Elsevier B.V.)

Heavy-metal-contaminated soil threatens human health and environmental safety. Complete remediation of contaminated soil is expensive; therefore, phytomanagement has emerged as a cost-effective alternative. The current study investigated mulberry tree (Morus alba) plantation, silkworm cultivation, and silk production as phytomanagement options. Results defined the safety of planting mulberry trees in soils with lead (Pb) and arsenic (As) concentrations lower than 369 and 180mgkg -1 , respectively. Silkworms fed with mulberry leaves collected from slightly contaminated soil exhibited productive growth and normal silk production. The silk, silkworm chrysalis, and silkworm fecal matter reached the national standards for textiles, feed, and agricultural sludge, respectively. Based on risk assessment, planting mulberry trees instead of rice significantly decreased the human health risk from contaminated soil. The total carcinogenic risk (Risk d ) and noncarcinogenic risk (HQ d ) derived from mulberry tree plantation and textile production were 2.4×10 -8 and 6.7×10 -5 , respectively, whereas those derived from rice plantation and ingestion were 0.44 and 18.4, respectively. Cost-benefit analysis showed that a mulberry tree plantation can yield $25,675 for every 1ha soil, whereas a rice plantation can yield $8409 for the same area. Moreover, phytoextraction requires $50,000-$150,000 to remediate 1ha of soil. Therefore, constructing a mulberry tree plantation with silkworm culture and silk production is a safe means to utilize slightly contaminated soil., (Copyright © 2017 Elsevier B.V. All rights reserved.)

Intercropping technology provides income for owners of contaminated soil without increasing environmental risk. Therefore, intercropping of arsenic (As) hyperaccumulator Pteris vittata L. with economic crops is now widely utilized in slightly or moderately As-contaminated farmlands. However, the mechanisms for As mobilization and absorption within the intercropping system are still unclear. To clarify As mobilization and absorption within an intercropping system, portable X-ray fluorescence spectrometry and sequential extraction were utilized to detect the spatial distribution and speciation of As in an intercropped system of P. vittata and cash crop mulberry (Morus alba L.). Compared with the P. vittata monoculture, P. vittata intercropping had higher As concentration, which may have been caused by the efficient exploitation of a greater As source in soil. Compared with the M. alba monoculture, M. alba intercropping had lower As concentration, which may have been caused by the As depletion by P. vittata roots. Spatial distribution of As in the soil indicated a "valley" around the P. vittata roots in both monocultured and intercropped systems, implying that As was depleted around the P. vittata roots. Continuous As extraction confirmed that both P. vittata monoculture and P. vittata and M. alba intercropping can efficiently control the risk of As soil contamination. Moreover, the properties of M. alba leaves were further studied. Mulberry leaves in the intercropping system satisfied the national feed standards. Therefore, intercropping presents a safe utilization mode for As-contaminated soil and can increase the income from silkworm-rearing M. alba leaves, without extra environmental risk., (Copyright © 2016. Published by Elsevier B.V.)

Disposal of plant biomass removed from heavy metal contaminated land via gasification achieves significant volume reduction and can recover energy. However, these biomass often contain high concentrations of heavy metals leading to hot-corrosion of gasification facilities and toxic gaseous emissions. Therefore, it is of significant interest to gain a further understanding of the solid-gas phase transition of metal(loid)s during gasification. Detailed elemental analyses (C, H, O, N and key metal/metalloid elements) were performed on five plant species collected from a contaminated site. Using multi-phase equilibria modelling software (MTDATA), the analytical data allows modelling of the solid/gas transformation of metal(loid)s during gasification. Thermodynamic modelling based on chemical equilibrium calculations was carried out in this study to predict the fate of metal(loid) elements during typical gasification conditions and to show how these are influenced by metal(loid) composition in the biomass and operational conditions. As, Cd, Zn and Pb tend to transform to their gaseous forms at relatively low temperatures (<1000°C). Ni, Cu, Mn and Co converts to gaseous forms within the typical gasification temperature range of 1000-1200°C. Whereas Cr, Al, Fe and Mg remain in solid phase at higher temperatures (>1200°C). Simulation of pressurised gasification conditions shows that higher pressures increase the temperature at which solid-to-gaseous phase transformations takes place., (Copyright © 2015 The Authors. Published by Elsevier B.V. All rights reserved.)

Heavy-metal pollution of soil is a serious issue worldwide, particularly in China. Soil remediation is one of the most difficult management issues for municipal and state agencies because of its high cost. A two-year phytoremediation project for soil contaminated with arsenic, cadmium, and lead was implemented to determine the essential parameters for soil remediation. Results showed highly efficient heavy metal removal. Costs and benefits of this project were calculated. The total cost of phytoremediation was US$75,375.2/hm(2) or US$37.7/m(3), with initial capital and operational costs accounting for 46.02% and 53.98%, respectively. The costs of infrastructures (i.e., roads, bridges, and culverts) and fertilizer were the highest, mainly because of slow economic development and serious contamination. The cost of phytoremediation was lower than the reported values of other remediation technologies. Improving the mechanization level of phytoremediation and accurately predicting or preventing unforeseen situations were suggested for further cost reduction. Considering the loss caused by environmental pollution, the benefits of phytoremediation will offset the project costs in less than seven years., (Copyright © 2015 Elsevier B.V. All rights reserved.)

Variations in arsenic (As) species in Panax notoginseng grown under field conditions remain understudied compared with those under greenhouse conditions. In the present study, soil and plant samples were collected from Wenshan Zhuang and Miao Autonomous Prefecture, Yunnan Province, which is the main production area of P. notoginseng in China, to identify As species in the soil and plant tissues and further assess effect of As toxic stress on As transformation and translocation in P. notoginseng. The results showed that arsenate (As(V)) was almost exclusively identified in the soil, while arsenite (As(III)) and monomethylarsonic acid (MMA) were detected in high proportions in plant tissues, suggesting that As(V) could be reduced and subsequently methylated in the plant body, mainly in the root. The reduction and methylation of As in the root of P. notoginseng were promoted by low As toxic stress, but were impeded by high As toxic stress. Arsenic(III) and MMA could rapidly translocate upwards in P. notoginseng. In addition, the translocation of total As, As(III), and MMA from the root to the rhizome was a response to As toxic stress, and the translocation rate increased with the increasing As concentration in the taproot. This study provides new insights into the detoxification mechanism of P. notoginseng grown in As-contaminated soils and the control of As during cultivation., (Copyright © 2016 Elsevier B.V. All rights reserved.)

Due to its high adsorption capacity, the use of biochar to capture excess nutrients from wastewater has become a central focus in environmental remediation studies. In this study, its potential use in adsorption and removal of ammonium in piggery manure anaerobic digestate slurry was investigated. The adsorbed amount of NH4(+)-N (mg·g(-1)) and removal percentage as a function of adsorbent mass in solution, adsorbent particle size, NH4(+)-N concentration in the effluent, contact time, pH and temperature were quantified in batch equilibrium and kinetics experiments. The maximum NH4(+)-N adsorption from slurry at 1400 mgN·L(-1) was 44.64 ± 0.602 mg·g(-1) and 39.8 ± 0.54 mg·g(-1) for wood and rice husk biochar, respectively. For both biochars, adsorption increased with increase in contact time, temperature, pH and NH4(+)-N concentration but it decreased with increase in biochar particle size. Furthermore, the sorption process was endothermic and followed Langmuir (R(2)=0.995 and 0.998) and Pseudo-second order kinetic models (R(2)=0.998 and 0.999). Based on the removal amounts, we concluded that rice husk and wood biochar have potential to adsorb NH4(+)-N from piggery manure anaerobic digestate slurry, and thus can be used as nutrient filters prior to discharge into water streams., (Copyright © 2014 Elsevier B.V. All rights reserved.)

Arsenic (As) contamination poses a high risk to human health. Phytoremediation based on As hyperaccumulator Pteris vittata has been utilized on large areas of contaminated farmland in southern China. However, the reason for the observed differences in As removal among P. vittata populations remains unclear. In this study, spores of four P. vittata populations were collected from four neighboring sites with varying soil As concentration (from 108 mg·kg(-1) to 7527 mg·kg(-1)) and then cultured in a controlled environment to analyze their differing abilities in terms of As accumulation and tolerance. The results indicate that populations from low-As habitats exhibited 80% greater shoot As concentrations compared with those from high-As habitats. On the other hand, populations from high-As habitats exhibited approximately five times greater biomass compared with those from low-As habitats when exposed to the same As stress. Thus, the As accumulation and tolerance of P. vittata were suggested to be two independent processes. Further investigations reveal that the As absorption and As species conversion occurring in roots are two essential activities that bridge the soil As concentration and the responses of P. vittata to As. Depending on the As concentration of the target soil, the selection of different P. vittata populations can result in approximately an eight-fold difference in terms of remediation efficiency., (Copyright © 2012 Elsevier B.V. All rights reserved.)