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The determination of 18 metals and metalloids was realized in 4 tissues of 62 Stenella coeruleoalba specimens stranded along the French Mediterranean coastline from 2010 to 2016. While most concentrations were comparable to mean worldwide levels, Hg levels were alarming (1190 μg g -1 dw, in average). The results were discussed together with previous measurements in the same area, from 2002 to 2009. The elements Ni and Pb (-81 % and -88 % in liver in 2010-16 compared to 2002-09), and Cd (-40 % in kidney in 2010-16 compared to 2002-09) as well as V (-79 % in liver in 2013-16 compared to 2010-12), showed promising decreasing trends, and the decrease of Zn and Cu levels below baseline values could indicate a global decreasing burden of metal contaminants. In contrary, Hg dramatically increased in dolphins since 2007 (+135 % in liver in 2010-16 compared to 2002-09), regardless of total length. On the other hand, Se levels increased only slightly since 2012, potentially not offering anymore an efficient protection against Hg, with mean Se-to-Hg molar ratios below unity in most tissues (0.26, 0.56, 1.81, and 0.57 in liver, kidney, lung and muscle, respectively)., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The extensive use of pesticides combined with their persistence in the environment requires new methodologies to assess more effectively the population exposure to pesticides via air pollution. Biomonitoring pesticides with lichens has been poorly documented, although it represents a complementary approach to the usual active samplings, with an exposure to pesticides accumulated and integrated over several months. An optimized extraction procedure from the lichen Xanthoria parietina followed by a gas chromatographic-tandem mass spectrometric analysis is proposed here to quantify simultaneously 48 pesticides considered in France as priority active substances to monitor in the air. This method has been applied to lichen samples collected in 24 sites in southern France covering urban, industrial, and agricultural areas in order to identify potential contrasts related to anthropogenic activities. Fifteen pesticides (six fungicides, five insecticides, and four herbicides), including four active compounds currently banned by EU legislation, were detected in at least one site. Lindane, diflufenican, difenoconazole, and boscalid were the most common pesticides found in all sites. Urban sites appeared generally less contaminated compared to industrial and rural ones, but a strong heterogeneity was noticed between locations. The biomonitoring with lichens revealed unexpected contaminated areas, partly due to the use of herbicides for vegetation control in industrial and railway installations. The spatial distribution also suggests an input of pesticides by atmospheric transport at the local and regional scales., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier B.V. All rights reserved.)