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The large (26-fold over the past 25 years) increase in the on-road vehicle fleet in China has raised sustainability concerns regarding air pollution prevention, energy conservation, and climate change mitigation. China has established integrated emission control policies and measures since the 1990s, including implementation of emission standards for new vehicles, inspection and maintenance programs for in-use vehicles, improvement in fuel quality, promotion of sustainable transportation and alternative fuel vehicles, and traffic management programs. As a result, emissions of major air pollutants from on-road vehicles in China have peaked and are now declining despite increasing vehicle population. As might be expected, progress in addressing vehicle emissions has not always been smooth and challenges such as the lack of low sulfur fuels, frauds over production conformity and in-use inspection tests, and unreliable retrofit programs have been encountered. Considering the high emission density from vehicles in East China, enhanced vehicle, fuel and transportation strategies will be required to address vehicle emissions in China. We project the total vehicle population in China to reach 400–500 million by 2030. Serious air pollution problems in many cities of China, in particular high ambient PM 2.5 concentration, have led to pressure to accelerate the progress on vehicle emission reduction. A notable example is the draft China 6 emission standard released in May 2016, which contains more stringent emission limits than those in the Euro 6 regulations, and adds a real world emission testing protocol and a 48-h evaporation testing procedure including diurnal and hot soak emissions. A scenario ( PC[1] ) considered in this study suggests that increasingly stringent standards for vehicle emissions could mitigate total vehicle emissions of HC, CO, NO X and PM 2.5 in 2030 by approximately 39%, 57%, 59% and 79%, respectively, compared with 2013 levels. With additional actions to control the future light-duty passenger vehicle population growth and use, and introduce alternative fuels and new energy vehicles, the China total vehicle emissions of HC, CO, NO X and PM 2.5 in 2030 could be reduced by approximately 57%, 71%, 67% and 84%, respectively, (the PC[2] scenario) relative to 2013. This paper provides detailed policy roadmaps and technical options related to these future emission reductions for governmental stakeholders. [ABSTRACT FROM AUTHOR]

Landfills are the most widely used method for municipal solid waste (MSW) disposal method in China. However, these facilities have caused serious groundwater contamination due to the leakage of leachate. This study, analyzed 32 scientific papers, a field survey and an environmental assessment report related to groundwater contamination caused by landfills in China. The groundwater quality in the vicinity of landfills was assessed as “very bad” by a comprehensive score (FI) of 7.85 by the Grading Method in China. Variety of pollutants consisting of 96 groundwater pollutants, 3 organic matter indicators, 2 visual pollutants and 6 aggregative pollutants had been detected in the various studies. Twenty-two kinds of pollutants were considered to be dominant. According to the Kruskal-Wallis test and the median test, groundwater contamination differed significantly between regions in China, but there were no significant differences between dry season and wet season measurements, except for some pollutants in a few landfill sites. Generally, the groundwater contamination appeared in the initial landfill stage after five years and peaked some years afterward. In this stage, the Nemerow Index ( PI ) of groundwater increased exponentially as landfill age increased at some sites, but afterwards decreased exponentially with increasing age at others. After 25 years, the groundwater contamination was very low at selected landfills. The PI values of landfills decreased exponentially as the pollutant migration distance increased. Therefore, the groundwater contamination mainly appeared within 1000 m of a landfill and most of serious groundwater contamination occurred within 200 m. The results not only indicate that the groundwater contamination near MSW landfills should be a concern, but also are valuable to remediate the groundwater contamination near MSW landfills and to prevent the MSW landfill from secondary pollutions, especially for developing countries considering the similar situation of MSW disposal. [ABSTRACT FROM AUTHOR]

Light rapid transit (LRT) has been widely used in a number of Chinese cities in recent years. Different from plain cities, the urban areas in mountainous cities are featured with dense road networks and high density of buildings. The noise impact of urban LRT could be more complex and significant due to the special morphological conditions in mountainous cities. This paper aims to investigate the noise exposure of residential areas along LRT lines in a typical mountainous city, namely Chongqing in Southwest China, through a series of field measurements and questionnaire surveys. Eight typical spatial configurations were classified to represent the relationships between LRT lines and urban mountainous environment. Both the outdoor and indoor acoustic environment of residential areas along LRT lines largely exceeded the national standards by up to 15 dBA, with dominant at low frequencies. The LRT noises tend to be more dominant on the ‘below track’ and ‘passing through’ rather than ‘above track’ areas or ‘facing towards’ locations. Good agreements were achieved between acoustic measurements and subjective evaluations from the local residents. Residents in the noisier areas tend to be more annoyed and influenced by the LRT noise, and 63.2% of interviewed residents once were awakened by the LRT noise. Among various urban noise sources, LRT noise resulted in the largest percentages of highly annoyed residents (30.9%), and acoustic environment was identified by 42.2% of the participants as the most urgent environmental factor to be improved. The preferred control strategies for LRT noise are possible but limited in practice. Moreover, noise sensitivity and age might significantly affect LRT noise annoyance and impact, whereas window glazing and residence time have no significant influence. [ABSTRACT FROM AUTHOR]

Intra-urban assessment of air pollution exposure has become a priority study while international attention was attracted to PM 2.5 pollution in China in recent years. Land Use Regression (LUR), which has previously been proved to be a feasible way to describe the relationship between land use and air pollution level in European and American cities, was employed in this paper to explain the correlations and spatial variations in Shanghai, China. PM 2.5 and NO 2 concentrations at 35–45 monitoring locations were selected as dependent variables, and a total of 44 built environmental factors were extracted as independent variables. Only five factors showed significant explanatory value for both PM 2.5 and NO 2 models: longitude, distance from monitors to the ocean, highway intensity, waterbody area, and industrial land area for PM 2.5 model; residential area, distance to the coast, industrial area, urban district, and highway intensity for NO 2 model. Respectively, both PM 2.5 and NO 2 showed anti-correlation with coastal proximity (an indicator of clean air dilution) and correlation with highway and industrial intensity (source indicators). NO 2 also showed significant correlation with local indicators of population density (residential intensity and urban classification), while PM 2.5 showed significant correlation with regional dilution (longitude as a indicator of distance from polluted neighbors and local water features). Both adjusted R squared values were strong with PM 2.5 (0.88) being higher than NO 2 (0.62). The LUR was then used to produce continuous concentration fields for NO 2 and PM 2.5 to illustrate the features and, potentially, for use by future studies. Comparison to PM 2.5 studies in New York and Beijing show that Shanghai PM 2.5 pollutant distribution was more sensitive to geographic location and proximity to neighboring regions. [ABSTRACT FROM AUTHOR]

With the rapid development of the economy and population, water scarcity and poor water quality caused by water pollution have become increasingly severe in China. Virtual water trade is a useful tool to alleviate water shortage. This paper focuses on a comprehensive study of China's international virtual water flows from agricultural products trade and completes a diachronic analysis from 2001 to 2013. The results show that China was in trade surplus in relation to the virtual water trade of agricultural products. The exported virtual water amounted to 29.94 billion m 3 /yr. while 155.55 billion m 3 /yr. was embedded in imported products. The trend that China exported virtual water per year was on the decline while the imported was on a rising trend. Virtual water trade of China was highly concentrated. Not all of the exported products had comparative advantages in virtual water content. Imported products were excessively concentrated on water intensive agricultural products such as soya beans, cotton, and palm oil. The exported virtual water mainly flowed to the Republic of Korea, Hong Kong of China and Japan, while the imported mainly flowed from the United States of America, Brazil and Argentina. From the ethical point of view, the trade partners were classified into four types in terms of “net import” and “water abundance”: mutual benefit countries, such as Australia and Canada; unilateral benefit countries, such as Mongolia and Norway; supported countries, such as Egypt and Singapore; and double pressure countries, such as India and Pakistan. Virtual water strategy refers to water resources, agricultural products and human beings. The findings are beneficial for innovating water resources management system, adjusting trade structure, ensuring food security in China, and promoting the construction of national ecological security system. [ABSTRACT FROM AUTHOR]

Source water areas are facing many potential water pollution risks. Risk assessment is an effective method to evaluate such risks. In this paper an integrated model based on k -means clustering analysis and set pair analysis was established aiming at evaluating the risks associated with water pollution in source water areas, in which the weights of indicators were determined through the entropy weight method. Then the proposed model was applied to assess water pollution risks in the region of Shiyan in which China's key source water area Danjiangkou Reservoir for the water source of the middle route of South-to-North Water Diversion Project is located. The results showed that eleven sources with relative high risk value were identified. At the regional scale, Shiyan City and Danjiangkou City would have a high risk value in term of the industrial discharge. Comparatively, Danjiangkou City and Yunxian County would have a high risk value in terms of agricultural pollution. Overall, the risk values of north regions close to the main stream and reservoir of the region of Shiyan were higher than that in the south. The results of risk level indicated that five sources were in lower risk level (i.e., level II), two in moderate risk level (i.e., level III), one in higher risk level (i.e., level IV) and three in highest risk level (i.e., level V). Also risks of industrial discharge are higher than that of the agricultural sector. It is thus essential to manage the pillar industry of the region of Shiyan and certain agricultural companies in the vicinity of the reservoir to reduce water pollution risks of source water areas. [ABSTRACT FROM AUTHOR]

Water resources are one of the important factors that influence regional crop production and the food security of humans. Most traditional models of crop water demand analysis are built on the basis of a certain crop or macroscopic analysis, which neglect regional crop allocation and the difference of water demand in different crop growing periods. In this paper, a new assessing model, the satisfied degree of crop water requirement, is developed to assess the impacts of water resources on production of six main food crops in China. The six main food crops are spring wheat, winter wheat, corn, early season rice, middle-season rice and late rice. The results show that: (1) there are serious risks of water shortage in China, even in south China with its abundant precipitation; (2) the satisfied degree of crop water demand represents great temporal–spatial changes. On spatial distribution the risks are high in major bases of food production due to influences of cropping system and crop-combinations. Northwest China is a special interesting case. In seasonal fluctuation water shortage is severe in March and September. These risks seriously restrict food production in China. The results also show that the strategic measures of water resources management must be chosen carefully to deal with food security and regional sustainable development in China. [ABSTRACT FROM AUTHOR]

The fluorine content of coal has been well documented, while such data of coal spoil are limited. In the present paper, fluorine in coal spoils and its releasing behavior were studied via leaching and combustion tests, as well as field investigation. Fluoride pollution in groundwater and soil occurred in the air depositing areas of coal spoils. The average content of fluorine in coal spoils was 525 mg/kg with the highest value of 1885 mg/kg. The only XRD detectable inorganic fluorine phase was fluorphlogopite. The absence of major fluorine bearing minerals in coal spoils suggested that bulk fluorine, rather than trace phases, resided in the mineral matrix. The major extracted species were water soluble fluorine and exchangeable fluorine in the coal spoils. Batch leaching tests illustrated that the leachable fluoride in coal spoils was widely distributed, ranging from 2.0 to 108.4 mg/kg. Column leaching tests showed a clear pH-dependent leaching behavior of fluorine: lower pH situation led to fluorine release from the mineral matrix; the loosely bound or easily exchangeable fluorine was also flushed out of the column. The higher ion strength or alkaline bicarbonate/carbonate rich leaching solution tended to free more fluorine into the acidic aqueous solution. The leachable fluorine in coal spoils was estimated as ca. 6%, based on the results of leaching tests. Also, our research found that over 90% of fluorine in coal spoils could be released into the atmosphere as a result of spontaneous combustion, accounting for over 40% of the total atmospheric fluorine emissions in northern China. Our investigation suggests that it is urgent to conduct comprehensive studies to assist the management and control of fluorine pollution at coal spoil banks. [ABSTRACT FROM AUTHOR]

Developing a more accurate greenhouse gas (GHG) emissions inventory draws too much attention. Because of its resource endowment and technical status, China has made coal-related GHG emissions a big part of its inventory. Lacking a stoichiometric carbon conversion coefficient and influenced by geological conditions and mining technologies, previous efforts to estimate fugitive methane emissions from coal mining in China has led to disagreeing results. This paper proposes a new calculation methodology to determine fugitive methane emissions from coal mining based on the domestic analysis of gas geology, gas emission features, and the merits and demerits of existing estimation methods. This new approach involves four main parameters: in-situ original gas content, gas remaining post-desorption, raw coal production, and mining influence coefficient. The case studies in Huaibei–Huainan Coalfield and Jincheng Coalfield show that the new method obtains the smallest error, + 9.59% and 7.01% respectively compared with other methods, Tier 1 and Tier 2 (with two samples) in this study, which resulted in + 140.34%, + 138.90%, and − 18.67%, in Huaibei–Huainan Coalfield, while + 64.36%, + 47.07%, and − 14.91% in Jincheng Coalfield. Compared with the predominantly used methods, this new one possesses the characteristics of not only being a comparably more simple process and lower uncertainty than the “emission factor method” (IPCC recommended Tier 1 and Tier 2), but also having easier data accessibility, similar uncertainty, and additional post-mining emissions compared to the “absolute gas emission method” (IPCC recommended Tier 3). Therefore, methane emissions dissipated from most of the producing coal mines worldwide could be more accurately and more easily estimated. [ABSTRACT FROM AUTHOR]

Following several decades of rapid economic growth, China has become the largest energy consumer and the greatest emitter of CO 2 in the world. Given the complex development situation faced by contemporary China, Chinese policymakers now confront the dual challenge of reducing energy use while continuing to foster economic growth. This study posits that a better understanding of the relationship between economic growth, energy consumption, and CO 2 emissions is necessary, in order for the Chinese government to develop the energy saving and emission reduction strategies for addressing the impacts of climate change. This paper investigates the cointegrating, temporally dynamic, and casual relationships that exist between economic growth, energy consumption, and CO 2 emissions in China, using data for the period 1990–2012. The study develops a comprehensive conceptual framework in order to perform this analysis. The results of cointegration tests suggest the existence of long-run cointegrating relationship among the variables, albeit with short dynamic adjustment mechanisms, indicating that the proportion of disequilibrium errors that can be adjusted in the next period will account for only a fraction of the changes. Further, impulse response analysis (which describes the reaction of any variable as a function of time in response to external shocks) found that the impact of a shock in CO 2 emissions on economic growth or energy consumption was only marginally significant. Finally, Granger casual relationships were found to exist between economic growth, energy consumption, and CO 2 emissions; specifically, a bi-directional causal relationship between economic growth and energy consumption was identified, and a unidirectional causal relationship was found to exist from energy consumption to CO 2 emissions. The findings have significant implications for both academics and practitioners, warning of the need to develop and implement long-term energy and economic policies in order to effectively address greenhouse effects in China, thereby setting the nation on a low-carbon growth path. [ABSTRACT FROM AUTHOR]

Urban dust pollution has been becoming an outstanding environmental problem due to rapid urbanization in China. However, it is very difficult to construct an urban dust inventory, owing to its small horizontal scale and strong temporal/spatial variability. With the analysis of visual interpretation, maximum likelihood classification, extrapolation and spatial overlaying, we quantified dust source distributions of urban constructions, barrens and croplands in the Guanzhong Basin using various satellite data, including VHR (0.5 m), Lansat-8 OLI (30 m) and MCD12Q1 (500 m). The croplands were the dominant dust sources, accounting for 40% (17,913 km 2 ) of the study area in summer and 36% (17,913 km 2 ) in winter, followed by barrens, accounting for 5% in summer and 10% in winter. Moreover, the total constructions were 126 km 2 , including 84% of active and 16% inactive. In addition, 59% of the constructions aggregated on the only megacity of the study area, Xi'an. With high accuracy exceeding 88%, the proposed satellite-data based method is feasible and valuable to quantify distributions of dust sources. This study provides a new perspective to evaluate regional urban dust, which is seldom quantified and reported. In a companied paper (Part-2 of the study), the detailed distribution of the urban dust sources is applied in a dynamical/aerosol model (WRF-Dust) to assess the effect of dust sources on aerosol pollution. [ABSTRACT FROM AUTHOR]

This paper analyses the reduction potential, shadow prices, and pollution costs of agricultural pollutants in China based on provincial panel data for 2001–2010. Using a parameterized quadratic form for the directional output distance function, we find that if agricultural sectors in all provinces were to produce on the production frontier, China could potentially reduce agricultural emissions of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) by 16.0%, 16.2%, and 20.4%, respectively. Additionally, our results show that the shadow price of TN increased rapidly and continuously, while that of COD and TP fluctuated for the whole period. For the whole country, the average shadow price of COD, TN, and TP are 8266 Yuan/tonne, 25,560 Yuan/tonne, and 10,160 Yuan/tonne, respectively. The regional shadow prices of agricultural pollutants are unbalanced. Furthermore, we show that the pollution costs from emissions of COD, TN, and TP are 6.09% of the annual gross output value of the agricultural sector and are highest in the Western and lowest in the Eastern provinces. Our estimates suggest that there is scope for further pollution abatement and simultaneous output expansion for China's agriculture if farmers promote greater efficiency in their production process. Policymakers are required to dynamically adjust the pollution tax rates and ascertain the initial permit price in an emission trading system. Policymakers should also consider the different pollution costs for each province when making the reduction allocations within the agricultural sector. [ABSTRACT FROM AUTHOR]

In this paper, the Mann–Kendall test and F-test were combined to analyze the annual and seasonal streamflow variations and aberrance points for the twin rivers from 1963 to 2011. The Tennant method was subsequently used to evaluate the ecological flow assurance and deficit. Finally, the Double Mass Curve method was applied to identifying the human activities affecting the streamflow variations. The results were as follows: (1) Three similar stages of the streamflow variations were found for the twin rivers: fluctuations before 1980, the tiny downward trends from the 1980s to the 1990s, and the notably downward trends in the 2000s. (2) The seasonal streamflow also decreased continuously and dramatically, especially in summer, by 80.9% for the Chaohe River and 86.0% for the Baihe River. (3) During the spawning season, 83.3% and 73.1% of streamflow was not at the appropriate level for the Chaohe and Baihe Rivers, respectively, which indicated that the ecological environment was not optimal for the reproduction and breeding of aquatic organisms. While in other periods, the ecological flow assurance was better than that in spawning seasons for the Chaohe and Baihe Rivers, respectively. This indicated that the streamflow regimes of the twin rivers were not always optimal and conducive to the development of the aquatic ecosystem. (4) The streamflow variations of the twin rivers were influenced by increasingly intensive human activities such as changes of land use and land cover, and excessive exploitation and utilization of water resources. These influences were cumulative and showed a gradually increasing tendency. This research is helpful for understanding the streamflow regime and for forecasting of the regional extreme climate, such as drought and floods, and can provide a basis for decision making and formulating adaptive ecological security countermeasures in response to climate changes and human activities. [ABSTRACT FROM AUTHOR]

Irrigation plays a major role in Chinese agricultural production, as China is experiencing water and food scarcity. Assessing water use (WU) and water productivity (WP) will contribute to regional water management and grain production improvement. This paper quantifies the water use and productivity in grain production for 31 Chinese provinces, autonomous regions and municipalities (PAMs) by distinguishing between irrigated and rain-fed farmland. An indicator of marginal productivity of blue water (MWP b ) is established and calculated to evaluate irrigation profits. National water use (WU t ) for grain cultivation from 1998 to 2010 was approximately 689.04 Gm 3 (42.26% blue water and 57.74% green water). The productive water proportions for irrigated and total croplands were 65.57% and 76.85%, respectively. Water use compositions from both blue–green and productive–unproductive perspectives changed slightly over time. The water use productivity (WPU) and water consumption productivity (WPC) for integrated grain products of China during the study period were 0.747 and 0.972 kg/m 3 , respectively. The spatial distribution patterns of irrigated WPs (WPU I, WPC I ) were consistent with those for total cropland. China has achieved sufficient food supply without increasing water use. The national MWP b was estimated to be 0.673 kg/m 3 , revealing a higher increase in crop yield on irrigated land compared to rain-fed land. The northeast provinces urgently need to improve irrigation efficiency, and the North China Plain PAMs should promote rain-fed crop yield to increase grain production and control water use in the future. [ABSTRACT FROM AUTHOR]

Fire activity in boreal forests will substantially increase with prolonged growing seasons under a warming climate. This trend poses challenges to managing fires in boreal forest landscapes. A fire environment zone map offers a basis for evaluating these fire-related problems and designing more effective fire management plans to improve the allocation of management resources across a landscape. Toward that goal, we identified three fire environment zones across boreal forest landscapes in northeastern China using analytical methods to identify spatial clustering of the environmental variables of climate, vegetation, topography, and human activity. The three fire environment zones were found to be in strong agreement with the spatial distributions of the historical fire data (occurrence, size, and frequency) for 1966–2005. This paper discusses how the resulting fire environment zone map can be used to guide forest fire management and fire regime prediction. [ABSTRACT FROM AUTHOR]

As a typical experimental Soil and Water Conservation District, Yanhe watershed has long been plagued by soil erosion due to severe human disturbances. Exerting remote sensing (RS) and geographic information system (GIS) technology, this paper firstly analyzed and simulated ecological hydrological process in Yanhe watershed based on SWAT model, constructed a comprehensive landscape indices which was closely related to soil erosion, and reflected the coupling relationship between regional landscape pattern change and soil erosion. The results are as follows: (1) Areas of different land use types remained relatively stable from 1990 to 2000 and then changed drastically from 2000 to 2010, which was characterized by lawn expansion and cultivated land shrinkage. (2) In terms of the spatial heterogeneity of hydrological response unit (HRUs), the correlation coefficient of seven selected landscape indices and runoff was very small, and cannot pass all significant testing. But correlation between the indices and sediment yield except for Total Core Area (TCA) and Interspersion and Juxtaposition Index (IJI) was remarkable. (3) According to ‘the source–sink’ theory of soil erosion, new landscape index—slope-HRU landscape index (SHLI) was built, and reflected the relationship between landscape pattern and soil erosion processes to a certain extent. (4) Coupling relationship between SHLI in 2010 and annual sediment was very prominent. In the sub-basin scale, SHLI has obvious regional differentiation from annual sediment. [ABSTRACT FROM AUTHOR]

With rapid economic development in China, water crisis is becoming serious and may impede future sustainable development. The uneven distribution of water resources further aggravates such a problem. Under such a circumstance, the concepts of water footprint and virtual water have been proposed in order to respond water scarcity problems. This paper focuses on studying provincial disparity of China's water footprints and inter-provincial virtual water trade flows by adopting inter-regional input–output (IRIO) method. The results show that fast developing areas with larger economic scales such as Guangdong, Jiangsu, Shandong, Zhejiang, Shanghai and Xinjiang had the largest water footprints. The most developed and water scarce areas such as Shanghai, Beijing, Tianjin and Shandong intended to import virtual water, a rational choice for mitigating their water crisis. Xinjiang, Jiangsu, Heilongjiang, Inner Mongolia, Guangxi and Hunan, had the largest per GDP water intensities and were the main water import regions. Another key finding is that agriculture water footprint was the main part in water footprint composition and water export trade. On the basis of these findings, policy implications on agriculture geographical dispersion, consumption behavior changes, trade structure adjustment and water use efficiency improvement are further discussed. [ABSTRACT FROM AUTHOR]

Abstract: Vegetation recolonization has often been used to control roadside slope erosion, and in this paper, four restoration models – Natural Restoration, Grass, Grass & Shrub, Sodded Strip – were chosen to recolonize the plants on a newly built unpaved roadside slope in the Three Gorges Reservoir Area. After eight months growth, eight rainfall simulations (intensity of 90mmh−1 for 60min) and in-situ soil shear strength test were then carried out to identify the impacts of vegetation on roadside slope erosion and soil shear strength. The erosion on cutslopes was higher than that on fillslopes. The runoff coefficient and soil detachment rate were significantly lower on the Grass & Shrub model (4.3% and 1.99gm−2 min−1, respectively) compared with the other three, which had the highest surface cover (91.4%), aboveground biomass (1.44kgm−2) and root weight density (3.94kgm−3). The runoff coefficient and soil detachment rate on roadside slopes showed a logarithmic decrease with the root weight density, root length density and aboveground biomass. The soil shear strength measured before and after the rainfall was higher on Grass & Shrub (59.29 and 53.73kPa) and decreased on Grass (46.93 and 40.48kPa), Sodded Strip (31.20 and 18.87kPa) and Natural Restoration (25.31 and 9.36kPa). Negative linear correlations were found between the soil shear strength reduction and aboveground biomass, root weight density and root length density. The variation of soil shear strength reduction was closely related to the roadside slope erosion, a positive linear correlation was found between runoff coefficient and soil shear strength reduction, and a power function was shown between soil detachment rate and soil shear strength reduction. This study demonstrated that Grass and Grass & Shrub were more suitable and highly cost-effective in controlling initial period erosion of newly built low-volume unpaved road. [Copyright &y& Elsevier]

Abstract: By applying substance flow analysis (SFA), the paper attempts to illustrate how copper utilization pattern has changed in the anthroposphere of China from 1975 to 2010. An analytical framework is firstly established and the detailed copper cycles of the specific years 1975, 1985, 1995, 2005 and 2010 are then characterized. Major conclusions include the following: (1) Chinese copper industry has made significant progress driven by large domestic copper demand since 1970s, especially after 1990s. Also the structure of copper industry has shifted from a basic industry to a processing industry. The share of secondary copper production in total refined copper has risen from 20% in 1975 to 38% in 2010; (2) the Chinese society has experienced a rapid copper accumulation since 1990s. The annual input flow to use stage jumped from only 334Gg (that is 0.36kg per capita copper consumption) in 1975 to 7916Gg (5.90kg per capita) in 2010; (3) a large amount of copper has to be imported to meet the huge demand, mainly involving in copper concentrate, refined copper and copper scrap. And the NIR (Net Import Ratio) of the three was 53.0%, 38.7% and 63.0% in 2010, respectively; (4) domestically produced copper scrap increased from 74.5Gg in 1975 to 711.2Gg in 2010. Comparing it with import scrap and domestic new scrap we found that at current stage the in-use stock is still too small to generate high quantities of copper scrap for domestic secondary copper production. (5) Major copper losses occurred through copper Mining, Refining and WM&R, with the Mining exhibited the lowest copper utilization efficiency (CUE) among the three processes, and may have the great potential for increasing copper utilization rate in China. [Copyright &y& Elsevier]

Abstract: The risk assessment of trace elements of different environmental media in conventional and organic greenhouse vegetable production systems (CGVPS and OGVPS) can reveal the influence of different farming philosophy on the trace element accumulations and their effects on human health. These provide important basic data for the environmental protection and human health. This paper presents trace element accumulation characteristics of different land uses; reveals the difference of soil trace element accumulation both with and without consideration of background levels; compares the trace element uptake by main vegetables; and assesses the trace element risks of soils, vegetables, waters and agricultural inputs, using two selected greenhouse vegetable systems in Nanjing, China as examples. Results showed that greenhouse vegetable fields contained significant accumulations of Zn in CGVPS relative to rice–wheat rotation fields, open vegetable fields, and geochemical background levels, and this was the case for organic matter in OGVPS. The comparative analysis of the soil medium in two systems with consideration of geochemical background levels and evaluation of the geo-accumulation pollution index achieved a more reasonable comparison and accurate assessment relative to the direct comparison analysis and the evaluation of the Nemerow pollution index, respectively. According to the Chinese food safety standards and the value of the target hazard quotient or hazard index, trace element contents of vegetables were safe for local residents in both systems. However, the spatial distribution of the estimated hazard index for producers still presented certain specific hotspots which may cause potential risk for human health in CGVPS. The water was mainly influenced by nitrogen, especially for CGVPS, while the potential risk of Cd and Cu pollution came from sediments in OGVPS. The main inputs for trace elements were fertilizers which were relatively safe based on relevant standards; but excess application caused trace element accumulations in the environmental media. [Copyright &y& Elsevier]

Abstract: Rapid urbanization has greatly altered the urban metabolism of material and energy. As a significant part of the infrastructure, urban roads are being rapidly developed worldwide. Quantitative analysis of metabolic processes on urban road systems, especially the scale, composition and spatial distribution of their stocks, could help to assess the resource appropriation and potential environmental impacts, as well as improve urban metabolism models. In this paper, an integrated model, which covered all types of roads, intersection structures and ancillary facilities, was built for calculating the material stocks of urban road systems. Based on a bottom-up method, the total stocks were disassembled into a number of stock parts rather than obtained by input–output data, which provided an approach promoting data availability and inner structure understanding. The combination with GIS enabled the model to tackle the complex structures of road networks and avoid double counting. In the case study of Beijing, the following results are shown: 1) The total stocks for the entire road system reached 159million tons, of which nearly 80% was stored in roads, and 20% in ancillary facilities. 2) Macadam was the largest stock (111million tons), while stone mastic asphalt, polyurethane plastics, and atactic polypropylene accounted for smaller components of the overall system. 3) The stock per unit area of pedestrian overcrossing was higher than that of the other stock units in the entire system, and its steel stocks reached 0.49t/m2, which was 10 times as high as that in interchanges. 4) The high stock areas were mainly distributed in ring-shaped and radial expressways, as well as in major interchanges. 5) Expressways and arterials were excessively emphasized, while minor roads were relatively ignored. However, the variation of cross-sectional thickness in branches and neighborhood roads will have a significant impact on the scale of material stocks in the entire road system. [Copyright &y& Elsevier]

Abstract: Heavy metal pollution has pervaded many parts of the world, especially developing countries such as China. This review summarizes available data in the literature (2005–2012) on heavy metal polluted soils originating from mining areas in China. Based on these obtained data, this paper then evaluates the soil pollution levels of these collected mines and quantifies the risks these pollutants pose to human health. To assess these potential threat levels, the geoaccumulation index was applied, along with the US Environmental Protection Agency (USEPA) recommended method for health risk assessment. The results demonstrate not only the severity of heavy metal pollution from the examined mines, but also the high carcinogenic and non-carcinogenic risks that soil heavy metal pollution poses to the public, especially to children and those living in the vicinity of heavily polluted mining areas. In order to provide key management targets for relevant government agencies, based on the results of the pollution and health risk assessments, Cd, Pb, Cu, Zn, Hg, As, and Ni are selected as the priority control heavy metals; tungsten, manganese, lead–zinc, and antimony mines are selected as the priority control mine categories; and southern provinces and Liaoning province are selected as the priority control provinces. This review, therefore, provides a comprehensive assessment of soil heavy metal pollution derived from mines in China, while identifying policy recommendations for pollution mitigation and environmental management of these mines. [Copyright &y& Elsevier]

Abstract: This paper presents an intensive field measurement campaign carried out at the rural mountainous site of Xinglong (960ma.s.l.) in Northern China during Sep. 3–20 2008. Size-segregated samples were collected daily and analyzed for 25 trace elements (TEs). The majority of the TEs showed comparable concentrations in fine (<2.1μm) and coarse particles (2.1–9μm). In addition, elements like K, Mn, Cu, Se, Mo, Ag, Cd, Tl and Pb were accumulated in fine mode whereas Al, Co and Sb were concentrated in a coarse mode. For most of the TEs, their enrichment factor (EF) increased with decreasing particle size from large (>9μm) to coarse, and to fine, signifying influences by anthropogenic emissions. The observed concentrations of heavy metals in fine particles, with EF values higher than 100, were significantly higher than the historical data recorded in the 1980s and 1990s, reflecting the increasing emissions in the target area. One pronounced event occurred on Sep. 14 when all of the TEs showed a peak, which was associated with regional emissions from both southeast (SE) and southwest (SW) indicated by backward trajectory analysis. This is further supported by the measurements in upwind sites where the concentrations of TEs were several times higher than those in Xinglong, suggesting potential source regions. Episodes of heavy metals were generally characterized by significant enhancements of fine mode and air mass trajectories from SE or SW alone. Taking this finding and factor analysis results together, the metallic episodes were attributable to the long-range transport of regional plumes from coal consumption and nonferrous metal smelting. With the rapid urbanization and industrialization in Northern China, the increasing emissions of TEs will place a great strain on human health and the environment in the downwind regions, thus long-term and multi-site observation with high time resolution are necessary. [Copyright &y& Elsevier]

Abstract: Estimations of air pollutant emissions from vehicles in China under different energy and emission abatement policy scenarios are presented in this paper. Three scenarios are designed: (i) “business as usual” (BAU); (ii) “advanced fuel economy” (AFE); and (iii) “alternative energy replacement” (AER). The CO, VOCs, NOx, PM10, and CO2 emissions are predicted to reach 105.8, 5.9, 7.5, 1.1, and 3522.6milliontons, respectively, in the BAU scenario by 2030. In the AFE scenario, the CO, VOCs, NOx, PM10, and CO2 emissions in 2030 will be abated by 23.8%, 18.6%, 25.3%, 18.2%, and 24.5% respectively compared with the BAU scenario. In the AER scenario, the CO and VOCs in 2030 will be further reduced by 15.9% and 6.1% respectively, while NOx, PM10, and CO2 will be increased by 10.7%, 33.3%, and 2.0% compared with AFE. In conclusion, our models indicate that the emission abatement policies introduced by governmental institutions are potentially viable, as long as they are effectively implemented. [Copyright &y& Elsevier]

Abstract: This paper evaluated the excretion masses and environmental occurrence of 11 classes of 50 antibiotics in six typical swine and dairy cattle farms in southern China. Animal feeds, wastewater and solid manure samples as well as environmental samples (soil, stream and well water) were collected in December 2010 from these farms. Twenty eight antibiotics, including tetracyclines, bacitracin, lincomycin, sulfonamides, fluoroquinolones, ceftiofur, trimethoprim, macrolides, and florfenicol, were detected in the feeds, animal wastes and receiving environments. The normalized daily excretion masses per swine and cattle were estimated to be 18.2mg/day/swine and 4.24mg/day/cattle. Chlortetracycline (11.6mg/day/swine), bacitracin (3.81mg/day/swine), lincomycin (1.19mg/day/swine) and tetracycline (1.04mg/day/swine) were the main contributors to the normalized daily excretion masses of antibiotics per swine, while chlortetracycline (3.66mg/day/cattle) contributed 86% of the normalized daily excretion masses of antibiotics per cattle. Based on the survey of feeds and animal wastes from the swine farms and interview with the farmers, antibiotics excreted by swine were mainly originated from the feeds, while antibiotics excreted by dairy cattle were mainly from the injection route. If we assume that the swine and cattle in China excrete the same masses of antibiotics as the selected livestock farms, the total excretion mass by swine and cattle per annum in China could reach 3,080,000kg/year and 164,000kg/year. Various antibiotics such as sulfonamides, tetracyclines, fluroquinolones, macrolides, trimethoprim, lincomycin and florfenicol were detected in well water, stream and field soil, suggesting that livestock farms could be an important pollution source of various antibiotics to the receiving environments. [Copyright &y& Elsevier]

Abstract: Receptor models are useful tools to identify sources of a specific pollutant and to estimate the quantitative contributions of each source based on environmental data. This paper reports on similarities and differences in results achieved when testing three receptor models for estimating the sources of polycyclic aromatic hydrocarbons (PAHs) in soils from Huanghuai Plain, China. The three tested models are Principal Component Analysis with Multiple Linear Regression (PCA-MLR), Positive Matrix Factorization (PMF) and Unmix. Overall source contributions as well as modeled ∑PAHs concentrations compared well among models. All three models apportioned three common PAH sources: wood/biomass burning, fossil fuel combustion and traffic emission, which contributed on average 27.7%, 53.0% and 19.3% by PCA-MLR, 36.9%, 27.2% and 16.3% by PMF, and 47.8%, 21.1% and 18.3% by Unmix to the total sum of PAHs (∑PAHs), respectively. Moreover, the spatial evolution of the common sources were well correlated among models (r=0.83–0.99, p <0.001). In addition, the PMF and Unmix models allowed segregating an additional source from the fossil fuel combustion source, with 19.6% and 11.8% contributions to ∑PAHs, respectively. The current findings further validate that different receptor models provide divergent source profiles, which are mainly attributed to both the model itself and/or the underlying dataset. It is therefore generally recommended to apply multiple techniques to determine the source apportionment in order to minimize individual-method weaknesses and thereby to strengthen the conclusion. [Copyright &y& Elsevier]

Abstract: Irrespective of which side is taken in the densification-sprawl debate, insights into the relationship between urban green space coverage and urbanization have been recognized as essential for guiding sustainable urban development. However, knowledge of the relationships between socio-economic variables of urbanization and long-term green space change is still limited. In this paper, using simple regression, hierarchical partitioning and multi-regression, the temporal trend in green space coverage and its relationship with urbanization were investigated using data from 286 cities between 1989 and 2009, covering all provinces in mainland China with the exception of Tibet. We found that: [1] average green space coverage of cities investigated increased steadily from 17.0% in 1989 to 37.3% in 2009; [2] cities with higher recent green space coverage also had relatively higher green space coverage historically; [3] cities in the same region exhibited similar long-term trends in green space coverage; [4] eight of the nine variables characterizing urbanization showed a significant positive linear relationship with green space coverage, with ‘per capita GDP’ having the highest independent contribution (24.2%); [5] among the climatic and geographic factors investigated, only mean elevation showed a significant effect; and [6] using the seven largest contributing individual factors, a linear model to predict variance in green space coverage was constructed. Here, we demonstrated that green space coverage in built-up areas tended to reflect the effects of urbanization rather than those of climatic or geographic factors. Quantification of the urbanization effects and the characteristics of green space development in China may provide a valuable reference for research into the processes of urban sprawl and its relationship with green space change. [Copyright &y& Elsevier]

Abstract: Soil erosion is a major global environmental problem that has caused many issues involving land degradation, sedimentation of waterways, ecological degradation, and nonpoint source pollution. Therefore, it is significant to understand the processes of soil erosion and sediment transport along rivers, and this can help identify the erosion prone areas and find potential measures to alleviate the environmental effects. In this study, we investigated soil erosion and identified the most seriously eroded areas in the East River Basin in southern China using a physically-based model, Soil and Water Assessment Tool (SWAT). We also introduced a classical sediment transport method (Zhang) into SWAT and compared it with the built-in Bagnold method in simulating sediment transport process along the river. The derived spatial soil erosion map and land use based erosion levels can explicitly illustrate the identification and prioritization of the critical soil erosion areas in this basin. Our results also indicate that erosion is quite sensitive to soil properties and slope. Comparison of Bagnold and Zhang methods shows that the latter can give an overall better performance especially in tracking the peak and low sediment concentrations along the river. We also found that the East River is mainly characterized by sediment deposition in most of the segments and at most times of a year. Overall, the results presented in this paper can provide decision support for watershed managers about where the best management practices (conservation measures) can be implemented effectively and at low cost. The methods we used in this study can also be of interest in sediment modeling for other basins worldwide. [Copyright &y& Elsevier]

Abstract: Using GIS software and based on exposure-response functions, this paper estimated the health-related economic losses that China suffered in 2009 due to the presence of particulate matter (PM10). The results show that China suffered a health-related economic loss due to PM10 of US$ 106.5billion, or 2.1% of China''s GDP, for the year 2009. Some urban areas, including Beijing, Tianjin, Shanghai, Guangzhou, Chongqing, and Changsha, reported large health-related economic losses due to PM10, with a value of US$ 1.5million per square kilometre or greater. Some parts of Beijing, Ji''nan, and Chongqing reported health-related economic losses due to PM10 as being greater than 4% of the 2009 GDP. [Copyright &y& Elsevier]

Abstract: The contamination of urban soils can affect the health of people living in urban areas, and the surrounding ecosystems. Urbanization in China has taken place at an unprecedented pace in the last three decades. This paper provides an overview of studies on the quality of urban soils in China with special reference to trace metal contamination. It summarizes the characteristics of accumulation, spatial and temporal distribution, and major sources of various toxic or potentially toxic trace metals in urban soils as reported in recent literature. Levels of pollution in urban soil and road dust were discussed using the concentrations, enrichment factors, pollution indexes, and chemical fractionation of trace metals in major cities of China, and compared with other countries. In future studies, more pollutants in urban environments need to be included in multi-compartmental environmental surveillance for potential risk assessments. In addition to routine urban soil surveys by a harmonized methodology, a comprehensive assessment of soil quality is needed for the control and management of many urban brownfield sites. Taking into consideration pathways of exposure and site characteristics, risk assessment frameworks for major pollutants in urban soils, which integrate land use type and environmental availability, may be developed in the future. [Copyright &y& Elsevier]

Abstract: It is well known that thallium (Tl) is a non-essential and toxic metal to human health, but less is known about the geo-environmentally-induced Tl pollution and its associated health impacts. High concentrations of Tl that are primarily associated with the epithermal metallogenesis of sulfide minerals have the potential of producing Tl pollution in the environment, which has been recognized as an emerging pollutant in China. This paper aims to review the research progress in China on Tl pollution in terms of the source, mobility, transportation pathway, and health exposure of Tl and to address the environmental concerns on Tl pollution in a geo-environmental perspective. Tl associated with the epithermal metallogenesis of sulfide minerals has been documented to disperse readily and accumulate through the geo-environmental processes of soil enrichment, water transportation and food crop growth beyond a mineralized zone. The enrichments of Tl in local soil, water, and crops may result in Tl pollution and consequent adverse health effects, e.g. chronic Tl poisoning. Investigation of the baseline Tl in the geo-environment, proper land use and health-related environmental planning and regulation are critical to prevent the Tl pollution. Examination of the human urinary Tl concentration is a quick approach to identify exposure of Tl pollution to humans. The experiences of Tl pollution in China can provide important lessons for many other regions in the world with similar geo-environmental contexts because of the high mobility and toxicity of Tl. [Copyright &y& Elsevier]

Abstract: Arsenic (As), selenium (Se) and thallium (Tl) are three trace metals (metalloids) of high concern in China because deficiency or excess expose can cause a range of endemic diseases, such as endemic arsenism, selenosis, Keshan disease (KD), Kashin–Beck disease (KBD) and thallotoxicosis. These specific endemic diseases were attributable for overabundance or deficiency (mainly referring to selenium) of these three elements in the local environment as a result of natural geochemical processes and/or anthropologic activities. The geochemistry and human health impacts of these three trace elements have been intensively studied since the 1970s in China, in terms of geochemical sources, distribution, transportation, health impact pathways, and prevention/remediation measures. Endemic arsenism in China are induced from the exposures of high As in either drinking water or domestic combustion of As-rich coals. Both endemic selenium deficiency and selenosis occurred in China. The KD and KBD were related to the deficiency of Se in the low-Se geological belt with Se contents in soil less than 0.125mg/kg stretching from northeast to southwest of China. Endemic selenosis occurred in areas with high Se concentrations in soils derived from the Se-enriched black carbonaceous siliceous rocks, carbonaceous shale and slate. Endemic Tl poisoning occurred in southwestern China due to Tl contamination in local drinking water and vegetables surrounding the Tl-rich sulfide mineralized areas. Some measures have been taken to control and remedy the endemic diseases with significant effects in reducing health risk and damage of As, Se and Tl. However, the states of the endemic diseases of As, Se and Tl in China are still serious in some areas, and substantial research efforts regarding the health impacts of these elements are further required. This paper reviews the progress of medical geology of As, Se and Tl in China, and provides with some outlooks for future research directions. [Copyright &y& Elsevier]

Abstract: Due to the fast developing economy, mercury (Hg) emissions to the atmosphere from Chinese mainland have increased rapidly in recent years. Consequently, this issue has received a considerable attention internationally. This paper reviews the current understanding of and knowledge on atmospheric Hg emissions, distribution and transport in China. The magnitude of Hg emissions to the atmosphere from Chinese anthropogenic sources has been estimated to be in the range of 500–700 tons per year, whereby comprising a significant proportion of the globe total anthropogenic emissions. Emissions of Hg from natural surfaces including bare soil, water, and vegetation covered soil tend in a comparison to be higher in China than in Europe and North America, indicating the importance of this source category. Atmospheric Hg exhibits a significant concentration variability among urban, semi-remote, and remote areas. Total Gaseous Mercury (TGM) concentrations in urban areas of China were often 1.5 – 5 folds higher compared to the corresponding settings in North America and Europe. In turn, particulate mercury (PHg) concentrations in urban areas of China were up to two orders of magnitude higher compared to North America and Europe. Atmospheric observations made at strictly remote sites in China also include the presence of occasional high concentrations of TGM, and the more short-lived fractions PHg and Reactive Gaseous Mercury (RGM). Accordingly, Hg deposition fluxes tended to be higher in China, with remote areas and urban areas being 1–2 times and 1–2 magnitude higher than those in North America and Europe, respectively. [Copyright &y& Elsevier]

Abstract: Soil heavy metal contamination is a major environmental concern, and the ecological risk associated with heavy metals is increasing. In this paper, we investigated heavy metal contamination near Dabaoshan Mine by: using sequential indicator simulation to delineate the spatial patterns of soil data; fitting multiple linear regression models for heavy metal uptake by crops; interpreting land uses from remote sensing images and integrating the spatial patterns, uptake models and land uses into a dose–response model for human health risks from heavy metals. The areas with elevated soil heavy metal concentrations are mainly located at the Dabaoshan Mine site and in the watershed basins of the Hengshi, Tielong and Chuandu rivers. The average concentrations of Cu, Zn, Cd and Pb in soil in the study area are all above the natural soil background levels, but Cd is the major contributor to human health risk in the area. Areas of low soil pH are also found throughout the watershed basins of the Hengshi, Tielong and Chuandu rivers. Of the different land use types in the study area, agricultural and residential land uses have the highest human health risk because ingestion is the dominant exposure pathway for heavy metals. The spatial patterns of the heavy metal concentrations and soil pH indicate that the areas with the highest human health risk regions do not directly coincide with the areas of highest heavy metal concentrations, but do coincide with the areas of lower soil pH. The contamination with high concentrations of heavy metals provides the risk source, but the combination of high heavy metal concentrations, low pH and agricultural or residential land use is required for human health risks to be present. The spatial pattern of the hazard quotients indicates that Cd is the most important pollutant contributing to the human health risk. [Copyright &y& Elsevier]

Abstract: Near surface disposal of low- and intermediate-level radioactive wastes (LILW) requires evaluating the field conditions of the candidate site. However, assessment of the site conditions may be challenging due to the limited prior knowledge of some remote sites, and various multi-disciplinary data requirements at any given site. These situations arise in China as in the rest of the industrialized world, particularly since a regional strategy for LILW disposal has been implemented to protect humans and the environment. This paper presents a demonstration of the site assessment process through a case study focusing mainly on the geologic, hydrogeologic and geochemical characteristics of the candidate site. A joint on-site and laboratory investigation, supplemented by numerical modeling, was implemented in this assessment. Results indicate that no fault is present in the site area, although there are some minor joints and fractures, primarily showing a north–south trend. Most of the joints are filled with quartz deposits and would thus function hydraulically as impervious barriers. Investigation of local hydrologic boundaries has shown that the candidate site represents an essentially isolated hydrogeologic unit, and that little or no groundwater flow occurs across its boundaries on the north or east, or across the hilly areas to the south. Groundwater in the site area is recharged by precipitation and discharges primarily by evapo-transpiration and surface flow through a narrow outlet to the west. Groundwater flows slowly from the hilly area to the foot of the hills and discharges mainly into the inner brooks and marshes. Some groundwater circulates in deeper granite in a slower manner. The vadose zone in the site was investigated specially for their significant capability for restraining the transport of radionuclides. Results indicate that the vadose zone is up to 38m in thickness and is made up of alluvial clay soils and very highly weathered granite. The vadose zone has low saturated hydraulic conductivities on the order of 10-5 cm/s and in this respect is well-suited for the disposal of LILW. The saturated formations are primarily made up of silt and moderately-to-slightly weathered granite, which exhibit even lower hydraulic conductivities, on the order of 10−6 cm/s, also favorable for restraining the transport of radionuclides. Chemical analyses indicate that the groundwaters at the site are of the HCO3–Na·Ca and HCO3·SO4–Na·Ca types and are weakly corrosive to concrete and steel. Geochemical analyses indicate that the rock and soil materials (particularly weathered granite) at the site contain very small fractions of colloidal particles and exhibit low Cation Exchange Capacities (CEC), and would therefore have limited capacity for sorption of radionuclides. Groundwater flow and solute transport models of the candidate site have been developed using MODFLOW and MT3DMS, incorporating the data obtained during the assessment program. Calibration was based on the available measured groundwater level fluctuations and tracer concentrations from in situ dispersion tests. The longitudinal dispersion coefficient as determined in calibration is equal to 5.0×10−3 m2/d. Numerical sensitivity analyses indicate that the hydraulic conductivity and the longitudinal dispersion coefficient are the key parameters controlling the transport of radionuclides, while the numerical model is not sensitive to changes in the effective porosity and the specific yield. Preliminary predictions have been performed with the calibrated model both for the natural setting of the site and the graded site in which the valleys of the site are backfilled with low permeable materials. Results indicate that the proposed site grading increases the safety of the site for disposal of LILW by reducing both the groundwater level and the hydraulic gradient and that radionuclide transport would not likely be a problem or cause groundwater contamination. Although there are some problems remaining to be addressed in future work, the conclusion of the assessment is that the conditions at this site are appropriate for LILW disposal. This study provides an example of the procedures necessary in an assessment of site conditions relevant to the safe disposal of LILW. Such an assessment is crucial to the site selection process and to subsequent environmental impact assessment. [Copyright &y& Elsevier]

Abstract: Eutrophication due to non-point source (NPS) of nitrogen (N) and phosphorus (P) has become a serious pollution problem in many Chinese rivers. In this paper, the export coefficient model (ECM) was used to assess the influence of NPS on N and P loading to the Three Gorges Reservoir Area (TGRA) of Hubei Province, People''s Republic of China. Data from the main non-point sources were analyzed from 1995 to 2007, including rural domestic wastes, distributed livestock farms, fertilizers and soil erosion. Additionally, the potential N and P loading from NPS originated from a variety of sources were estimated and analyzed from 1995 to 2007, including runoff from rural domestic waste, livestock farms, land use, and atmospheric deposition, using the ECM. These gave the temporal distributions of the potential NPS loads within the reservoir area. The results indicated that the potential total nitrogen (TN) load was much higher than the potential total phosphorus (TP) load. The calculated TN load was 2.83×104 tonnes, while the TP load was 2.14×103 tonnes in 2007, with a ratio of TN/TP of 13.23. Record shows that “algae blooms” occurred 8 times in TGRA that year. Therefore, there may be a correlation between the eutrophication potential in the inlet water of TGRA and the TN/TP ratio of potential NPS loads. These findings demonstrate that the export coefficient model could provide a simple and reliable approach to evaluate the potential N and P loading to the Three Gorges Reservoir Area of Hubei Province in the People''s Republic of China and may be useful for the planning and management of the local agricultural watersheds. [Copyright &y& Elsevier]

Abstract: This paper investigates the characteristics of dissolved organic nitrogen (DON) in raw water from the Huangpu River and also in water undergoing treatment in the full-scale Yangshupu drinking water treatment plant (YDWTP) in Shanghai, China. The average DON concentration of the raw water was 0.34mg/L, which comprised a relatively small portion (~5%) of the mass of total dissolved nitrogen (TDN). The molecular weight (MW) distribution of dissolved organic matter (DOM) was divided into five groups: >30, 10–30, 3–10, 1–3 and <1kDa using a series of ultrafiltration membranes. Dissolved organic carbon (DOC), UV absorbance at wavelength of 254nm (UV254) and DON of each MW fraction were analyzed. DON showed a similar fraction distribution as DOC and UV254. The <1kDa fraction dominated the composition of DON, DOC and UV254 as well as the major N-nitrosodimethylamine formation potential (NDMAFP) in the raw water. However, this DON fraction cannot be effectively removed in the treatment line at the YDWTP including pre-ozonation, clarification and sand filtration processes. The results from linear regression analysis showed that DON is moderately correlated to DOC, UV254 and trihalomethane formation potential (FP), and strongly correlated to haloacetic acids FP and NDMAFP. Therefore, DON could serve as a surrogate parameter to evaluate the reactivity of DOM and disinfection by-products FP. [ABSTRACT FROM AUTHOR]

Abstract: Member enterprises have a vital effect on the stability and system efficiency of an eco-industrial park (EIP), and a selection and control for them is an important part. This paper proposes a new method which is an establishment of both an access indicator system and an extendable optimal degree evaluation model. The indicator system comprises seven primary indicators and twenty-seven secondary indicators. The first three primary indicators, matching the existing industrial chains or not, park capacity and park environmental performance improvement, are proposed from the perspective of an EIP. The others including eco-design, economic benefit, utilization of resources, and pollution control, are suggested from the point of view of enterprises. This new access indicator system provides a basis for evaluating candidate enterprises. The extendable optimal degree evaluation which was proposed by Prof. Caiwen is a method to assess the satisfactoriness of all the indicators and to assign an optimal degree order to each candidate enterprise accordingly. There are four steps to conduct the evaluation after establishing the access indicator system: (1) selecting correlation function; (2) calculating correlations; (3) assigning weights and current values of indicators; and (4) calculating the optimal degree of all the candidate enterprises. The enterprises can be ranked based on optimal degree results. The highest-ranked enterprise should have the highest priority of entering the EIP. This study provides the specifics of applying the method by examining the case of Yantai Economy Technology Development Zone EIP (YTEIP) in Shandong province. The method provides a practical tool for controling enterprise access to an EIP. However, the reasonability and validity of indicators and effectiveness of the established method of extendable optimal degree evaluation merit further studies. [ABSTRACT FROM AUTHOR]

Abstract: Traditional measurements of suspended sediment concentrations (SSC) through in-situ sampling in rivers are expensive and time-consuming to perform. Thus, these methods cannot provide continuous SSC records. Although remote sensing has been used for SSC estimation, little research has been undertaken on inland rivers, especially for highly turbid rivers like the Yangtze. Previous studies have proposed Landsat TM/ETM+ Band 4 as a spectral SSC indicator for the Yangtze, but its limitation on temporal resolution is insufficient for the study of dynamic changes of sediment. This paper presents a method of estimating SSC of the Yangtze at Jiujiang using time-series satellite data of high temporal resolution Terra MODIS. It was found that differences in water reflectance between Band 2 and Band 5 could provide relatively accurate SSC estimation even when in-situ atmospheric conditions were unknown. After cross-validation, mean absolute relative error (ARE) and relative root mean square error (RRMSE) were relatively low (i.e., 25.5% and 36.5%, respectively). This empirical relationship was successfully applied to the estimation of SSC at Datong in the Lower Yangtze River, although the SSC values were generally underestimated. This study suggests that Terra MODIS could be used to estimate SSC in large turbid rivers, although some influencing factors require further study to improve the accuracy of SSC estimation. [Copyright &y& Elsevier]

Abstract: Generic Assessment Criteria (GAC) are derived using widely applicable assumptions about the characteristics and behaviour of contaminant sources, pathways and receptors. GAC provide nationally consistent guidance, thereby saving money and time. Currently, there are no human health based Generic Assessment Criteria (GAC) for contaminated sites in China. Protection of human health is therefore difficult to ensure and demonstrate; and the lack of GAC makes it difficult to tell if there is potential significant risk to human health unless site-specific criteria are derived. This paper derived Chinese GAC (GAC) for five inorganic and eight organic substances for three regions in China for three land uses: urban residential without plant uptake, Chinese cultivated land, and commercial/industrial using the SNIFFER model. The SNIFFER model has been further implemented with a dermal absorption algorithm and the model default input values have been changed to reflect the Chinese exposure scenarios. It is envisaged that the modified SNIFFER model could be used to derive GAC for more contaminants, more Regions, and more land uses. Further research to enhance the reliability and acceptability of the GAC is needed in regional/national surveys in diet and working patterns. [Copyright &y& Elsevier]

Abstract: The Tibetan Plateau covers an area of about one fourth of Europe, has an average elevation over 4000m above sea level, and is the water sources for about 40% of world''s population. In order to foresee future changes in water quality, it is important to understand what pressures are governing the spatial variation in water chemistry. In this paper the chemistry including major ions and trace elements in the headwaters of four major Asian rivers (i.e. the Salween, Mekong, Yangtze River and Yarlung Tsangpo) in the Tibetan Plateau was studied. The results showed that the content of dissolved salts in these Tibetan rivers was relatively high compared to waters from other parts of the world. The chemical composition of the four rivers were rather similar, with Ca2+ and HCO3 − being the dominating ions. The exception was the Yangtze River on the Plateau, which was enriched in Na+, Cl−, SO4 2− and Li due to silicate weathering followed by strong evaporation caused by a negative water balance, dissolution of evaporites in the catchment and some drainage from saline lakes. The concentrations of heavy metals (Cu, Co, Cr, Ni, Cd, Pb, and Hg) and As, NH4 + were generally low in all the rivers. Anthropogenic impacts on the quality of the rivers were identified at a few locations in the Mekong River and Yarlung Tsangpo basins. Generally, the main spatial variation in chemical compositions of these under studied rivers was found to be governed mainly by difference in geological variation and regional climatic-environment. Climate change is, therefore, one of main determining factors on the water chemical characteristics of these headwaters of Asian major rivers in the Tibetan Plateau. [Copyright &y& Elsevier]

Abstract: The vertical distribution of polycyclic aromatic hydrocarbons (PAHs) at different sediment depths, namely 0–2cm, 2–4cm, 4–6cm, 6–10cm, 10–15cm and 15–20cm, in one of the most contaminated mangrove swamps, Ma Wan, Hong Kong was investigated. It was the first time to study the intrinsic potential of deep sediment to biodegrade PAHs under anaerobic conditions and the abundance of electron acceptors in sediment for anaerobic degradation. Results showed that the total PAHs concentrations (summation of 16 US EPA priority PAHs) increased with sediment depth. The lowest concentration (about 1300ng g−1 freeze-dried sediment) and the highest value (around 5000ng g−1 freeze-dried sediment) were found in the surface layer (0–2cm) and deeper layer (10–15cm), respectively. The percentage of high molecular weight (HMW) PAHs (4 to 6 rings) to total PAHs was more than 89% at all sediment depths. The ratio of phenanthrene to anthracene was less than 10 while fluoranthene to pyrene was around 1. Negative redox potentials (Eh) were recorded in all of the sediment samples, ranging from −170 to −200mv, with a sharp decrease at a depth of 6cm then declined slowly to 20cm. The results suggested that HMW PAHs originated from diesel-powered fishing vessels and were mainly accumulated in deep anaerobic sediments. Among the electron acceptors commonly used by anaerobic bacteria, sulfate was the most dominant, followed by iron(III), nitrate and manganese(IV) was the least. Their concentrations also decreased with sediment depth. The population size of total anaerobic heterotrophic bacteria increased with sediment depth, reaching the peak number in the middle layer (4–6cm). In contrast, the aerobic heterotrophic bacterial count decreased with sediment depth. It was the first time to apply a modified electron transport system (ETS) method to evaluate the bacterial activities in the fresh sediment under PAH stress. The vertical drop of the ETS activity suggested that the indigenous bacteria were still active in the anaerobic sediment layer contaminated with PAHs. The biodegradation experiment further proved that the sediment collected at a depth of 10–15cm harbored anaerobic PAH-degrading bacterial strains (two Sphingomonas, one Microbacterium, one Rhodococcus and two unknown species) with some intrinsic potential to degrade mixed PAHs consisting of fluorene, phenanthrene, fluoranthene and pyrene under low oxygen (2% O2) and non-oxygen (0% O2) conditions. This is the first paper to report the anaerobic PAH-degrading bacteria isolated from subsurface mangrove sediment. [Copyright &y& Elsevier]

Harmful algal blooms (HABs) have drawn great attention in coastal areas worldwide in the past decades because of their multiple effects on marine ecosystems as well as public health. This study utilized geographic information system (GIS) techniques to analyze the primary data on HABs, as well as shellfish toxins data, in the East China Sea from 2000 to 2006. The frequency of HABs was mapped by kernel density estimation, and the relative risk posed by HABs was assessed based on their physical–chemical characteristics. In addition, the spatial patterns and the trend of HAB events were examined by nearest neighbor analysis and time series analysis, respectively. The results revealed that HAB events not only had an increasing trend and significant seasonality, but also were clustered in space and time. HAB events displayed a higher frequency and a higher risk in Zhejiang coastal waters, particularly in the Zhoushan Archipelago, the largest marine fishery in China. Shellfish toxins were detected in areas with high HAB risk, but were not correlated with the risk. This paper provides a novel method to assess the relative risk caused by HABs and some useful information for HAB monitoring and management and aquaculture development. [Copyright &y& Elsevier]

Abstract: The emission of N2O from China is globally significant, but relatively few direct observations have been made in many of the fresh water environments most likely to be important sites of N2O production. In this paper, N2O saturations were examined in the ecologically heterogeneous, eutrophied, Lake Taihu, as well as in surrounding rivers in eastern China. The emissions of N2O were estimated and compared with those from other landscapes within the Lake Taihu drainage basin. We found that anthropogenically-enhanced inorganic N inputs act as a limited primary control on the spatial distribution of N2O saturations in heavily eutrophied parts of the lake only and that overall, lake N2O production and emission are not raised as significantly as expected due to high N inputs. In comparison, the heavily eutrophied river network is an important fraction of the local N2O budget, and when considered together with emissions of N2O from the lake, constitute a major (10–50% depending on season) fraction of total N2O emissions from the Lake Taihu drainage basin. [Copyright &y& Elsevier]

Vehicle exhaust emissions have posed a serious threat in recent years to the urban air quality of Beijing. It is necessary to accurately estimate the magnitude and distribution of these emissions in order to reduce the uncertainty of local scale air quality modeling assessment. This paper provides a bottom-up approach by combining vehicle emission factors and vehicle activity data from a travel demand model estimated at the grid level to generate vehicle emissions data for the Beijing urban area in 2005. In that year, vehicular emissions of HC, CO and NOx were respectively 13.33×104, 100.02×104 and 7.55×104 tons. The grid-based emissions were also compared with the vehicular emission inventory developed by macro-scale approach. It shows this bottom-up approach can result in better estimates of the levels and spatial distribution of vehicle emissions than the macro-scale method that relies on more average and aggregated information. [Copyright &y& Elsevier]

The transfer of nutrients from agricultural land to waters attracts the attention of policy makers as well as scientists as it plays an increasingly significant role in affecting the water environment. It is therefore essential to first understand the nutrient flow in agricultural systems and then correspondingly formulate a series of cost-effective policies and best management practices (BMPs). On the basis of an emission inventory analysis (EIA) and a nutrient full balance (NFB) calculation, this paper presents a partial substance flow analysis (SFA) method, as well as an Agricultural Phosphorus Flow Analysis (AgiPhosFA) model, to describe the phosphorus (P) flow in the agricultural systems in China and assess the impact of human activities on waters driven by agriculture and rural life. It is estimated that average P input and output were 28.9 kg ha−1 a−1 and 14.2 kg ha−1 a−1 respectively in China in 2004, while the total P utilization efficiency (Plant uptake P/P input) in agriculture was 45.7% leading to an average P surplus of 14.7 kg ha−1 a−1. Excessive P application through mineral fertilizer in the arable farming system has led to the accumulation of soil P and constituted a risk to the recipient water quality, whereas the grassland grazing system is confronted with a severe P deficit problem which has resulted in widespread grass degradation. Therefore it may be an efficient way to mitigate the problems simultaneously by regulating and balancing the P flows between the two systems. Uncertainties of the method and model are also discussed in terms of model conceptualization, data and parameters, and spatial and temporal variability. [Copyright &y& Elsevier]

In this paper, we apply the method of Granger causality which is more accurate than classical correlation analysis method to determine whether the main air pollutants — Nitrogen oxides (NO x ), SO2 (Sulfur Dioxide), CO (carbon monoxide), TSP (total suspended particulates), PM10 (particulate matter smaller than 10 microns) and the mortality of respiratory diseases of the residents in Beijing have causal relationship. After ensuring NO x , SO2 and CO as the responsible substances, we use the time series method to construct the autoregressive integrated moving average model (ARIMA) of the pollutants, so that we could predict the amount of the pollutants from 2005 to 2008. Then we use the predicted value of pollutants as the input of the neural network model and obtain the output as the change of the death rate of respiratory diseases from 2005 to 2008. In the end, reducing the amount of pollutants by 10% and inputting the data in the neural network model, we make the prediction to evaluate the level of the pollutants and concluded that NO x is the most important pollutant to control. [Copyright &y& Elsevier]

Abstract: Organic matter in source water has presented many challenges in the field of water purification, especially for conventional treatment. A two-year-long pilot test comparing water treatment processes was conducted to enhance organic matter removal. The tested process combinations included the conventional process, conventional plus advanced treatment, pre-oxidation plus conventional process and pre-oxidation plus conventional plus advanced treatment. The efficiency of each kind of process was assayed with the comprehensive indices of CODMn, TOC, UV254, AOC, BDOC, THMs, and HAAs and their formation potential. The results showed that the combination of the conventional process and O3-BAC provides integrated removal of organic matter and meets the required standards. It is the best performing treatment tested in this investigation for treating polluted source water in China. Moreover, much attention should be paid to organic removal before disinfection to control DBP formation and preserve biostability. This paper also reports the range of efficiency of each unit process to calculate the total efficiency of different process combinations in order to help choose the appropriate water treatment process. [Copyright &y& Elsevier]

Abstract: In this paper, field measurements were performed to determine SO2 concentration gradients from a highway in Shanghai using passive samplers. It was demonstrated that passive sampling method is a cost-effective and convenient way to monitor specific gaseous pollutants at small scales over long sampling periods in air quality studies. Using function fit analysis for the measured results, a shifted power–law relationship had been found between SO2 concentration and the distance from a highway. Accordingly, an empirical shifted power–law model was developed for describing and predicting the SO2 gradients near a highway, in which k is the only parameter and named as diffusion attenuation coefficient. There was a surprisingly significant negative correlation between known SO2 concentration at reference point (C 0) and diffusion attenuation coefficient (k). By the correlation equation of C 0 and k, appropriate value of k could be calculated with measured C 0. Therefore, the empirical shifted power–law model developed in this study could be practically and conveniently applied for predicting the SO2 distributions near a highway with known C 0. [Copyright &y& Elsevier]

Particulate air pollution is a serious problem in Beijing. The annual concentration of particulate matter with aerodynamic diameter less than 10 μm (PM10), ranging from 141 to 166 μg m−3 in 2000–2004, could be very harmful to human health. In this paper, we presented the mortality and morbidity effects of PM10 pollution based on statistical data and the epidemiological exposure–response function. The economic costs to health during the 5 years were estimated to lie between US$1670 and $3655 million annually, accounting for about 6. 55% of Beijing''s gross domestic product each year. The total costs were apportioned into two parts caused by: the local emissions and long-range transported pollution. The contribution from local emissions dominated the total costs, accounting on average for 3. 60% of GDP. However, the contributions from transported pollution cannot be neglected, and the relative percentage to the total costs from the other regions could account for about 45%. An energy policy and effective measures should be proposed to reduce particulate matter, especially PM2. 5 pollution in Beijing to protect public health. The Beijing government also needs to cooperate with the other local governments to reduce high background level of particulate air pollution. [Copyright &y& Elsevier]