Search

The emission of volatile organic compounds (VOCs) from interior materials can significantly impact people's health and daily activities, necessitating effective management. In the construction of the interior built environment, plants serve as a suitable means to enhance air quality. They not only function as ecological living materials for air purification and VOCs removal but are also valued for their aesthetic appeal. However, often the emphasis in designing green infrastructure is placed more on the aesthetics of planting design rather than considering plants' ecological properties. This research examines the ability of 12 plant species used in the interior green wall design at Harvard University's Smith Center as a case study to decompose and absorb VOCs through experimental studies. By integrating ecological properties and key factors such as spatial and budget constraints into the design process, this research explores the potential of using an algorithmic model to select plant species capable of reducing interior VOC pollution in green wall design. The significance of this study lies in its contribution to indoor environmental health and environmental management practices through providing a potential plant selection model and suggesting a relevant workflow for interior planting design with the goal of controlling VOC emissions. By leveraging the knowledge gained from experiments on the VOC removal abilities of selected plant species, this study offers a valuable resource for practitioners seeking to create innovative indoor air cleaning and decontamination technologies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Various pharmaceuticals are essential for livestock farming, but some are highly toxic to aquatic life if they reach surface water bodies. Mediterranean Climate is characterized by dry summers followed by intense autumn storms. We studied the effect of these climatic conditions on the risk of pharmaceutical residues transfer to streams at the catchment-scale. Pharmaceutical products routinely used in the study area, as well as their application frequency and season, were identified through interviews with farmers. As a proof a concept, three veterinary pharmaceuticals (Fenbendazole (FBZ), Mebendazole (MBZ) and Ivermectin (IVM)) were chosen as model chemicals based on their relatively high usage, their specificity to represent different types of livestock (swine, sheep and cattle), and their ability to be analyzed using the same analytical method. Stream water was analyzed during low flow periods and at high frequency (up to 2 h -1 ) during flood events. The selected veterinary pharmaceuticals were not detected during low flow, but FBZ and MBZ reached high concentrations for short periods during floods. Due to the event-driven nature of their transfer, a significant load of veterinary pharmaceuticals can reach the river and cause temporary but significant degradation of water quality (e.g. for FBZ, the water concentration reached up to 355 times the predicted no effect concentration (PNEC)). This indicates that special care should be taken to avoid keeping freshly treated livestock on pastures that may become hydrologically connected under wet conditions. In addition, it suggests that low-frequency monitoring is not sufficient to detect those high concentration levels that exist during very short periods., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Government departments usually prepare and implement contingency plans to address frequent urban flooding caused by short-term heavy rainfall. Previous studies focused on the evaluation of the static impact of the policies on urban floods, while there is a lack of research on the effect of off-design conditions, real-time feedback and treatments of the flood events on urban flood mitigation, which is detrimental to the optimization of management strategies of the cities. To quantify the effects of real-time management on flood mitigation in Fuzhou City, China, this study proposed a framework (EAPF) for evaluation and risk prediction. First, we collected data on the locations, rainfall intensity, inundation time, and the triggers of the waterlogging events from 2017 to 2021. Second, based on the vigilance analyses, a structural equation model (SEM) was constructed to quantitatively evaluate the mitigation effects of management on waterlogging. Finally, a probability prediction model of dynamic drainage capacity was proposed for flood simulation caused by the rainwater grate blockage. The results indicate that the environmental factors were the decisive triggers affecting the severity of waterlogging, and increasing the frequency of management events effectively reduced the probability of blocking. The correlation between the number of management events and blocking flood events was -0.42, while a decrease in vigilance increased the possibility of flooding caused by overdue treatment. The proposed hydrological waterlogging model, which considered blockages, exhibited a Nash-Sutcliffe efficiency (NSE) coefficient exceeding 0.9 under deterministic conditions. The probability prediction model verified the mitigating effect of management on the blockages and urban flooding, and its results were consistent with those of the SEM. Our study contributes to improving the reliability of waterlogging prediction and optimizing the management flow in the developing cities., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

Pollution of surface waters is a global threat, with particular concern about pesticides due to their severe negative effects on ecosystem functioning and human health. The aims of this study were to identify the spatiotemporal patterns of water and sediment quality, and the key variables related to the variation in pesticide pollution (122 compounds), in headwater streams (surrounding land uses: crop or mixed crop-livestock systems) and floodplain streams (surrounding land uses: urban development or natural wetland) of the Paraná River basin in the central area of Argentina. We found significant differences in water and sediment quality related to local land uses among headwater streams, but not among floodplain streams. These differences were more noticeable during spring than during autumn. Pesticides were widespread in all the streams, independently of the surrounding land use, reflecting the combination of local inputs and the role of floodplain hydrological connectivity in transporting pollutants from upstream sources. The most frequently detected compound was atrazine (75 %), whereas the highest concentration of an individual compound was observed for the glyphosate metabolite aminomethylphosphonic acid (AMPA, up to 4 μg L -1 ). The significant explanatory variables for pesticide pollution were turbidity, chromophoric dissolved organic matter (CDOM), sub-basin area, side slope of streams (positive relations), wetland cover, and precipitations (negative relations). Our results can be useful for the design of monitoring programs that capture the spatial and temporal variability of pesticide pollution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Background: Physical activity is associated with health benefits and has been shown to reduce mortality risk. However, exposure to high levels of ambient fine particulate matter (PM 2.5 ) during exercise can potentially reduce the health benefits of physical activity. This study aims to assess and compare the PM 2.5 concentrations of different exercise venues in Singapore by their location attributes and time of day., Methods: Personal PM 2.5 exposures (μg/m 3 ) at 24 common outdoor exercise venues in Singapore over 49 sampling days were collected using real-time personal sensors from September 2017 to January 2020. Wilcoxon rank-sum test and Kruskal-Wallis test were used to compare PM 2.5 concentrations between different timings (peak (0700-0900; 1800-2000) vs. non-peak (0600-0700; 0900-1800; 2000-2300); weekend vs. weekday), and location attributes (near major roads (<50 m) vs. away from major roads (≥50 m)). Multivariable linear regression models were used to assess the associations between location attributes, timings and ambient PM 2.5 with personal PM 2.5 concentration, adjusting for potential confounders., Results: Compared with peak hours, exercising during non-peak hours was associated with a significantly lower PM 2.5 exposure (median, 17.8 μg/m 3 during peak vs. 14.5 μg/m 3 during non-peak; P = 0.006). Exercise venues away from major roads have significantly lower PM 2.5 concentrations as compared to those located next to major roads (median, 14.4 μg/m 3 away from major roads vs. 18.5 μg/m 3 next to major roads; P < 0.001). Individuals who exercised in parks experienced the highest PM 2.5 exposure (median, 55.0 μg/m 3 ) levels in the afternoon during 1400-1500. Furthermore, ambient PM 2.5 concentration was significantly and positively associated with personal PM 2.5 exposure (β = 0.85, P < 0.001)., Conclusions: Our findings suggest that exercising outdoors in the urban environment exposes individuals to differential levels of PM 2.5 at different times of the day. Further research should investigate a wider variety of outdoor exercise venues, explore different types of air pollutants, and consider the varying activity patterns of individuals., Competing Interests: Declaration of competing interest The authors declare no competing financial interests or personal relationship could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

A first characterization of greenhouse gases had been carried out to study their role and impact in a productive transitional coastal system of the southern Portugal - Ria Formosa lagoon. To this purpose, the partial pressure of CO 2 (pCO 2 ) and the concentration of dissolved CH 4 and N 2 O have been measured. Two surveys were carried out during 2020, at low tide under typical conditions of Spring (March) and end of Summer (October). The samplings sites were distributed along the costal lagoon covering: i) inner areas with strong human impact (influence of different flows of treated wastewater discharges); and ii) main channels in connection with the main inlets to study the exchanges with the ocean. In general, the highest values of the three greenhouse gases were found at the inner studied areas, especially affected by the disposal of treated effluents from wastewater treatment plans, in October. The mean water - atmosphere fluxes of the CO 2 , CH 4 and N 2 O are positive, showing that the study area acts as a source of these gases to the atmosphere. On the other hand, it was calculated a rough estimation of the three gases globally exported from Ria Formosa to the ocean, through the main six inlets to evaluate the magnitude of the supply of these gases from Ria Formosa to the adjacent ocean. The mean CO 2 , CH 4 and N 2 O horizontal water fluxes exported from all the inlets of Ria Formosa to the Gulf of Cadiz for both seasons, during low water, are 8.7 ± 3.9 mmol m -2  s -1 , 8.0 ± 3.5 μmol m -2  s -1 and 3.2 ± 1.5 μmol m -2  s -1 , which corresponds to a mass transport through the inlets section of 0.7 ± 0.7 kg s -1 , 0.2 ± 0.2 g s -1 and 0.2 ± 0.3 g s -1 respectively. From these estimates, as expected, the higher mass transport was found at the larger and deeper inlets (Faro-Olhão and Armona)., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

With the development of cities and population, the production of sludge is increasing annually. It has become an unavoidable challenge to achieve sludge dewatering and disposal by a cost-effective, efficient and safe process. In this work, firstly, the factors limiting sludge dewatering are reviewed in terms of moisture distribution, sludge concentration, organic matter content, electronegativity, floc strength, and extracellular polymers (EPS). Subsequently, focusing on the dewatering technology about the skeleton builder, the recent progress of it is detailed in terms of mechanism, evaluation indicators, influencing factors, and technology coupling. In addition, the impact of skeleton builders on the sludge disposal stage is concluded. Finally, the challenges faced by sludge dewatering and skeleton builders are prospected. This review will provide some theoretical basis and technical guidance for subsequent experiments and practices regarding skeleton builders., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Microplastic (MP) has been found to influence membrane fouling during microfiltration/ultrafiltration processes in direct and indirect ways by acting as fouling components and changing microbial activities, respectively. However, there is no relevant research about the contribution of MPs to nanofiltration membrane fouling. In this study, for the first time, the impacts of MPs on membrane fouling during the nanofiltration of secondary effluent (SE) were systematically investigated from the perspective of bacterial extracellular polymeric substances (EPS) secretion, their interaction with coexisting pollutants and also deposition. Membrane flux behaviors indicate that MPs simultaneously aggravated the short-term and long-term membrane fouling resistance of nanofiltration by 46 % and 27 %, respectively. ATR-FTIR, XPS and spectrophotometry spectra demonstrate that the deteriorated membrane fouling by MPs directly resulted from the increased accumulation of protein-like, polysaccharides-like and humic-like substances on membranes. EEM spectra further confirmed that MPs preferred to induce serious cake layers, which dominated membrane flux decline but hindered pore fouling. According to CLSM and SEM-EDS mappings, MPs in SE could stimulate microbial activities and then aggravate EPS secretion, after which their interaction with Ca 2+ was also enhanced in bulk solution. The cross-linker nets could promote the deposition of other unlinked pollutants on membranes. Besides, MPs could weaken the rejection of certain dissolved organic matters (from 57 % to 52 % on the 50th day of filtration) by aggravating cake-enhanced concentration polarization (CECP), but improved the average removal of inorganic salts from 58 % to 63 % by improving their back diffusion through cake layers. Based on these analyses, the mechanisms of MP-enhanced membrane fouling during the nanofiltration of SE can be thoroughly revealed., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Phosphorus (P) is an essential nutrient for all crops, yet its excess negatively affects public health, the environment, and the economy. At the same time, rock P is a critical raw material due to its importance for food production, the finite geological deposits, and its unequal regional distribution. As a consequence, nutrient management is addressed by numerous environmental policies. Process-based biogeochemical models are valuable instruments to monitor the P cycle and predict the effect of agricultural management policies. In this study, we upscale the calibrated DayCent model at European level using data-derived soil properties, advanced input data sets, and representative management practices. Our results depicted a P budget with an average P surplus (0.11 kg P ha -1  year -1 ), a total soil P (2240.0 kg P ha -1 ), and available P content (77.4 kg P ha -1 ) consistent with literature and national statistics. Through agricultural management scenarios, we revealed a range of potential changes in the P budget by 2030 and 2050, influenced by the interlink of P with biogeochemical carbon and nitrogen cycles. Thus, we developed a powerful assessment tool capable of i) identifying areas with P surplus or deficit at high spatial resolution of 1 km 2 , (ii) pinpointing areas where a change in agricultural management would be most urgent to reach policy goals in terms of environmental pollution, food security and resource efficiency of a critical raw material, and iii) assessing the response of the P cycle to modifications in agricultural management., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier B.V. All rights reserved.)