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Alcohol-based fuels are a viable alternative to fossil fuels for powering vehicles. As a drop-in fuel, an oxygenated fuel blend containing the C8 alcohol 2-ethylhexanol (isomer of octanol), hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) can reduce soot and NOx emissions whilst maintaining engine performance. However, fuel injection strategy significantly affects combustion and hence has been investigated with a view to reducing emissions whilst maintaining engine efficiency. In a single cylinder light-duty compression ignition research engine, the effect of different injection strategies (main, main/post, double pre/main, double pre/main/post injection) and EGR levels (0%, 19%) on specifically NOx, soot emissions and particle size distribution was investigated for three different fuels: fossil diesel fuel, HVO and the oxygenated blend. The blend was designed to have diesel-like combustion properties (cetane number of 52) and had an oxygen content of 5.4% by mass. The crank angle used when measuring MFB50, fuel consumption and IMEP was kept constant. The engine efficiencies were similar for all tested fuels and injection strategies. Heat release analysis revealed a strong influence of the cetane number on main and main/post injection strategy. However, when using double pre-injection, the start of combustion was similar for all fuels. Combustion characteristics, particle mass and number were more affected when using double pre-injection rather than post-injection. With 19% EGR and double pre-injection, soot mass increased as agglomerated particle mode increased in the PSD. Further, the in-cylinder temperature and pressure were lower compared to combustion without EGR, leading to a reduction of NOx emissions by a factor of 2.5 while soot emissions increased by a factor of 10. There were just minor differences in NOx emissions with variations in injection strategy. The PSD moved towards smaller particle diameters without EGR. In conclusion, the soot reduction potential of all fuels tested was coupled to the use of double pre-injection and EGR rather than post-injection.

Although waste animal fats such as chicken fat are promising alternative energy sources, biodiesels produced from these type of feedstocks hardly satisfies the EN14214 biodiesel standards. In this study, biomixtures were prepared by blending cottonseed biodiesel and chicken rendering fat biodiesel which were produced via transesterification method. Biodiesels were blended with each other at 60/40, 50/50 and 30/70 volume ratios to produce CO60CH40, CO50CH50 and CO30CH70 fuels. First, fuel properties of the neat biodiesels and novel biomixtures were measured and compared to European biodiesel standards and diesel. Then, the engine performance, combustion characteristics and exhaust emissions of these novel biomixture fuels were measured in a three-cylinder indirect injection diesel engine under various engine loads and at constant speed of 1500 rpm. The fuel characterisation showed that CO60CH40 and CO50CH50 biomixtures met the European standards. The Brake Specific Energy Consumption (BSEC) and Brake Thermal Efficiency (BTE) of all biomixtures were comparable with CO100, CH100 and diesel at the full engine load. The combustion results revealed that the maximum in-cylinder pressure and energy release values of the CO50CH50 were 4.2% and 4.4% higher than the diesel at full engine load because of optimised fuel properties of biomixture such as molecular structure, viscosity, cetane number and iodine value. CO50CH50 had 2.9% reduced CO 2 and comparable CO emission compared to diesel, which were also 5.6% and 13% lower than cottonseed biodiesel respectively. However, NO emission of CO50CH50 was found 3.8% and 5.8% higher than diesel and cottonseed biodiesel. A 6.5% reduction on NO emission was observed when CO60CH40 biomixture fuel was used instead of diesel. To conclude, this research showed that blending of cottonseed and chicken fat biodiesels is a promising approach to meet the EN14214 standards, improve in-cylinder pressure, optimise energy release and reduce exhaust emissions. Blending of different biodiesels will be tested as a future work.

Recently introduced sulfur caps on marine fuels in so-called sulfur emission control areas (SECAs) are forcing shipping companies to sail on more or less automotive grade diesel in lieu of the considerably less expensive, but sulfur-laden heavy fuel oil (HFO) to which they were accustomed. This development is an opportunity for a bio-based substitute, given that most biomass is sulfur free by default. Moreover, given that biomass is typically solid to start with, cracking it to an HFO grade, which is highly viscous in nature, will involve fewer and/or less harsh process steps than would be the case if an automotive grade fuel were to be targeted. In this study, a renewable low sulfur heavy fuel oil (LSHFO) has been produced by means of subcritical water assisted lignin depolymerization in the presence of a short length surfactant, ethylene glycol monobutyl ether (EGBE). The resulting oil contains a lignin derived content of 75 wt.-%, with the remainder consisting of EGBE and water (reusable). The derived LSHFO has a 20% higher heating value than the lignin feedstock. It is still roughly 20% and 30% lower when compared to the HFO and low sulfur marine gas oil (LSMGO) benchmarks, respectively. The lower heating value can be attributed to the fuel bond oxygen (10%) and water present in the LSHFO. Viscosity and sulfur levels, however, are within the HFO and LSMGO range and target respectively. Future work will examine what impact lignin particle size and surfactant type/concentration will have on the results.Graphical abstract

A set of additives was selected to improve the durability of the physical-chemical and biological characteristics of mineral diesel and its blend with biodiesel. Two biodiesels were used: soybean (SME) and rapeseed (RME). Both physical-chemical properties and fuel dispersion of fuel blends and their mixtures with additives were measured that could have effects on the combustion process in diesel engines. The dispersion of the fuel is affected by the injection nozzle integrity, influencing the capacity of the fuel to vaporize, while the modification of the fuel molecular structure can cause changes in combustion reaction. A 7 hole Common Rail (CR) 2nd generation injector, 136 ?m in diameter, was used at 80 MPa and 1.0 ms injection pressure and duration, respectively. The injection rate was determined using the Bosch's Method, while the fuel dispersion was measured by analyzing the images of spray evolving in an optical accessible quiescent vessel. The results showed that the additives have a great influence on the stability of the blends. Adding the biocide "P", antioxidant "AN" and pour point depressant "D", an increase of the oxidation stability of 390 % of the B20SME samples compared to B20 without additives. For B20SME containing "P", "AS" and "D", the oxidation stability increased of 810%. The injection rate data showed that a slight reduction in the rate of injections (9.91% for Diesel B5RME, 8.13% relative to B20RME and 12.84% relative to B20SME) was registered when additives were used. Finally, the inclusion of the additives did not produce particular variations on the fuel spray tip penetration.

Combusiton of pine pyrolysis oil droplets was studied at different pressures up to a maximum of 60 bar in a single-droplet combustion chamber. Oil droplets, with diameters between 400 \gmm and 120 \gmm were suspended to a thermocouple of to a quartz fiber. Their behavior was followed by means of high-speed digital imaging based on a shadowgraph scheme. About two thousands of frames were collected during every test with acquisition speed between 400 and 4000 frames/s. Droplets were easy to ignite at normal as well as at high pressure. Increasing the pressure the intensity of swelling phenomena, undergone by droplets, decreased and completely disappeared at pressures higher than 20 bar. However, bubbling and foaming were always observed. Liquid-phase pyrolysis and the formation of cenospheres as combustion residual were observed under all the pressure conditions.

A burning process in a combustion chamber of an internal combustion engine is very important to know the maximum temperature of the gases, the speed of combustion, the ignition delay time of fuel and air mixture exact moment at which ignition will occur. The automobilist industry has invested considerable amounts of resources in numerical modeling and simulations in order to obtain relevant information about the processes in the combustion chamber and then extract the maximum engine performance control the emission of pollutants and formulate new fuels. This study aimed to general construction and instrumentation of a shock tube for measuring shock wave. As specific objective was determined reaction rate and ignition delay time of diesel and ethanol doped with different levels of additive enhancer cetane number. The results are compared with the delays measured for the ignition diesel and biodiesel.

In the present study, ethanol was added in lower proportions to non-edible vegetable oil “Schleichera oleosa” or “Kusum”, to evaluate various performance and emission characteristics of a single cylinder; diesel engine. For engine's trial, four samples were prepared with 5%, 10%, 15% and 20% ethanol in kusum oil (v/v) and the blends were named as E5K95, E10K90, E15K85 and E20K80 respectively. Neat Kusum oil was named as K100. The results indicated that brake thermal efficiency (BTE) was found to increase with increase in volume fraction of ethanol in the kusum oil. E5K95, E10K90, E15K85 and E20K80 test fuels exhibited maximum BTE of 25.4%, 26.4%, 27.4% and 27.7% respectively as compared to 23.6% exhibited by the neat Kusum oil. Similarly, full load brake specific energy consumption (BSEC) decreased from 16.3MJ/kWh in case of neat Kusum oil to 15.1MJ/kWh for E20K80 with an almost linear reduction pattern with increased ethanol composition in the test fuel. Full load carbon monoxide emissions were found to be 0.18% volume for neat Kusum oil which was reduced to 0.1% for E20K80. Similarly, smoke emissions and unburnt hydrocarbons were also found to be reduced by a margin of 7-12% compared to the K100 operation. However, E5K95, E10K90, E15K85 and E20K80 test fuels exhibited 779, 890, 860 and 877 ppm each of NO x emissions as compared to 795 ppm exhibited by the neat Kusum oil.