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The conventional Pb-Ag alloy possesses a high oxygen evolution reaction overpotential, poor stability, and short service life in acidic solutions, making it an unsuitable sort of anode material for the zinc electrowinning process. Therefore, a layered carbon-covered cobalt tetroxide (Co 3 O 4 @C)-reinforced PbO 2 -coated electrode is fabricated via a facile two-step pyrolysis-oxidation and subsequent electrodeposition process. As a result, the reinforced PbO 2 -coated electrode exhibits a low OER overpotential of 517 mV at 500 A m -2 and a Tafel slope of 0.152 V per decade in a zinc electrowinning simulation solution (0.3 M ZnSO 4 and 1.53 M H 2 SO 4 ). The reduced overpotential of 431 mV at 500 A m -2 compared to traditional Pb-0.76%Ag alloy leads to improved energy savings, which is attributable to the presence of Co 3 O 4 @C to refine the grain size and thus increase the effective contact area. Moreover, the reinforced PbO 2 -coated electrode has a prolonged service life of 93 h at 20 000 A m -2 in 1.53 M H 2 SO 4 . Therefore, an accessible and efficient strategy for preparing a coated electrode to improve OER performance for zinc electrowinning is presented in this research., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)