1. The guiding role of pre-coking on the coke deposition over ZSM-5 in methanol to propylene
- Author
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Lin Wang, Jing Qi, Hongqiao Jiao, Liangcheng An, Chong Guan, Xiaojing Yong, Zhengwei Jin, Angui Zhang, and Dianhua Liu
- Subjects
pre-coking ,zsm-5 zeolites ,methanol to propylene ,catalyst ,Science - Abstract
Deposition of carbonaceous compounds was used to improve the propylene selectivity of ZSM-5 by deactivating some acid sites meanwhile maintaining the high activity for methanol conversion. The carbonaceous species of pre-coked samples before and after MTP reactions were investigated by elementary analysis and thermogravimetric analysis (TGA). The results showed that pre-coke formed at low temperature (250°C) was unstable and easy to transform into polyaromatics species at the high reacting temperature, while combining 5% pre-coking process with 95% steam treatment at high temperature (480°C) was effective in inhibiting the formation of coke deposits and presented a significant improvement in the propylene selectivity.
- Published
- 2019
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