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In this study, a biorefinery concept is presented to produce valuable platform chemicals such as γ-valerolactone (GVL), 2-methyltetrahydrofuran (2-MTHF) and 5-hydroxymethylfurfural (5-HMF) from lignocellulosic biomass via aqueous phase processing. Process simulation models are developed using Aspen Plus and a techno-economic assessment including cost estimation, energy integration, profitability study, sensitivity analysis and Monte Carlo simulation-based uncertainty analysis is carried out for evaluating the economic potential of the proposed process. The total investment for a plant with an annual production capacity of 35 kt of GVL, 17 kt of 2-MTHF and 5 kt of 5-HMF, is estimated as 257 M€. The minimum selling prices (MSPs) of GVL, 2-MTHF and 5-HMF are estimated to be 1.91 €/kg, 1.64 €/kg, and 1.93 €/kg, respectively. The profitability study revealed that the process generates an internal rate of return of 15.90%, making it viable and profitable. The sensitivity analysis indicated that the annual operational costs and fixed capital investment have the biggest influence on the minimum selling price of the products. Furthermore, based on the uncertainty analysis, the probability of loss is estimated as 17%. According to the market potential assessment, the most promising application of these platform chemicals is as biofuels and solvents. [ABSTRACT FROM AUTHOR]

The Brazilian territory is irradiated with solar energy ranging from 1500 to 2300 kWh/m 2 /year, compared to 900 to 1850 kWh/m 2 /year in Germany, France, Italy and Spain. Despite that, photovoltaic (PV) technology is only now starting to penetrate the Brazilian electricity mix. Until recently, the high costs of PV generation had prevented this technology from competing in Brazil. However, the consistent PV price reductions and the worldwide scale reached, has brought attention to the Brazilian planners and actions have been taken recently in Brazil to help PV start its progress. In this paper, two of the recent government actions are analyzed, namely the National Electrical Energy Agency ANEEL Resolution RN482/2012, and the announcement of support by the Brazilian Development Bank offering loans at low interest rates for solar PV projects. The effects of these actions for residential PV systems are positive where the conventional electricity tariff is high with respect to the average in the country, and less relevant elsewhere. We compare these tariffs with the calculated Levelized Cost of Energy of rooftop PV generation. The influence of these policies on the return on investment of residential rooftop PV generation is studied for different climatic zones in Brazil. [ABSTRACT FROM AUTHOR]