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Ethylene is one of the most important products in the emissions-intensive petrochemical industry. Decarbonizing the ethylene industry is thus important for achieving global carbon neutrality. This study is the first to explore future long-term zero-emissions production pathways for the ethylene industry in China, the world's biggest ethylene producer. An optimization model was built in the context of China's carbon neutrality target of 2060. Four scenarios were developed where the policy ambitions for climate mitigation and for plastic management including waste were varied. Based on this, authors assessed the cumulative total emissions, technology options, future geographical location of ethylene production, and policy challenges associated with each scenario. This is also the first time that scope 3 emissions from waste incineration are included, motivated by the short lifetime of most ethylene products. Results show the cumulative CO 2 emissions for the scenarios differ considerably, ranging from 4.3 to 7.8 Gt, even if carbon neutrality by 2060 is achieved in all scenarios. The results suggest that ambitious plastic focused policies can result in lower costs and less cumulative emissions compared to ambitious climate focused policies. The results demonstrate the importance of adopting CCS for waste incineration. This reduces cumulative CO 2 emissions by up to 2 Gt. However, reduced overall demand and increased recycling rates should be priority options due to CCS challenges. Results suggest Chinese ethylene industry should adopt a mixed portfolio of production technologies, where the share of emission-intensive coal-based methanol-to-olefins is limited. These findings on decarbonization pathways can contribute to achieving the Paris agreement. [Display omitted] • Ambitious plastic policies lead to 1.3 Gt less cumulative CO 2 than climate policies. • Cumulative CO 2 until 2060 can be reduced by 3.5 Gt compared to reference scenario. • Adopting CCS in incineration can reduce cumulative CO 2 emissions by 2 Gt. • Ethylene industry should adopt a mixed production portfolio due to uncertainties. • Coal-based MTO with CCS does not appear to be a cost-competitive option. [ABSTRACT FROM AUTHOR]

CO 2 concentration in the atmosphere has crossed an unprecedented level of 420 ppm, causing catastrophic events like climate change. Climate change mitigation via carbon capture is crucial for reducing CO 2 emissions. Among various CO 2 capture technologies, adsorption is considered one of the most efficient and promising techniques. In recent times, substantial research has been conducted on producing cost-effective and efficient adsorbents for CO 2 capture via the thermal and chemical treatments of biomass. In this review, we discuss key scientific results to give broad insight into the recent progress in biomass conversion to activated porous carbon (APC). The effects of various chemical and thermal treatments on the textural properties and CO 2 adsorption capacity of APC are comprehensively discussed. CO 2 adsorption mechanism based on interaction with the surface functionality is thoroughly explained. The economic aspects of APC synthesis and post-combustion CO 2 capture using APC are systematically reviewed. [Display omitted] • Use of biomass based activate porous carbon (APC) for CO 2 capture is reviewed. • CO 2 adsorption mechanism on APC surface is thoroughly explained. • APC surface functionalization via metal doping and heteroatom doping is discussed. • Economics of APC synthesis & large-scale CO 2 capture on APC is critically reviewed. [ABSTRACT FROM AUTHOR]

Cities represent unique spaces for climate mitigation where wide-ranging action to reduce emissions meets ambition and collaboration. This research work distils climate neutrality narratives for 362 cities that expressed interest in the European Mission on 100 Climate-Neutral and Smart Cities and focuses on the 112 cities selected to spearhead the process of reaching climate neutrality by 2030 (representing a mitigation potential of 318.3 megatonnes of carbon dioxide equivalent emissions). The method involves steps that profile the characteristics of these cities, enunciate cross-cutting patterns in cities' visions by thematic groupings, and compare 14 contextual factors with 77 possible main barriers. There are both similarities and differences among the results as a basis for learning together and certain barriers can be relatively more dominant in some thematic groupings, such as fragmentation of responsibilities. As a synthesis of the main findings, the original analyses are used to derive and prioritise nine high-level recommendations based on the cities' visions, contextual factors, and expected main barriers. Opportunities for mobilising transformative change relate to transforming siloed into integrated approaches, inclusive climate governance and collaborations, innovative financing, welfare and just transition as well as planning, implementation, and policy coherence. The advances provide pioneering steps for stimulating co-learning processes among Mission Cities and beyond to support the transition to climate neutrality and open up opportunities to progress together in climate action while producing impact with global reach. [Display omitted] • Visions and narratives for achieving climate neutrality by 2030 are enunciated across cities. • The 112 Mission Cities represent an emissions reduction potential of 318.3 MtCO 2 eq. • Thematic groupings are formed by cross-comparing degree of ambition and collaboration. • Recommendations are prioritised based on enablers and barriers in the thematic groupings. • Cross-cutting patterns in cities' visions provide opportunities to stimulate co-learning. [ABSTRACT FROM AUTHOR]

Animal production faces challenges related to thermal comfort, air quality, and carbon dioxide (CO 2) emissions, thereby the need for more efficient and sustainable systems due to climate change. This study examines green roofs and their potential to absorb atmospheric CO 2 and reduce heat load through photosynthesis and evapotranspiration, resulting in decreased energy consumption and increased CO 2 emissions. The maximum CO 2 concentration limit in animal production facilities is 3000 ppm. Depending on the ventilation system used in broiler production facilities, the CO 2 concentration can exceed 2000 ppm. Dark House poultry facilities tend to have higher concentrations reaching up to 777 ppm. In pig farming, the nursery sector has higher concentrations of CO 2 , exceeding 1200 ppm. In dairy farming, the number of milkings, the type of ventilation system and local climatic conditions can affect the CO 2 concentration, reaching values of up to 1401 ppm. C3 plants have a CO 2 saturation point at 800 ppm and C4 plants at 200 ppm. The CO 2 balance in animal production facilities that use a green roof can be done considering the CO 2 produced and the CO 2 absorbed. Green roofs are therefore considered a sustainable solution for animal production. Its implementation enhances air quality in the facilities, supporting the reduction of environmental impacts and mitigation of climate change effects caused by the agroindustry. This investigation underscores the significance of green roofs, emphasizing their environmental, social, and economic benefits, as well as their applicability in animal production. • It is possible to estimate the CO 2 balance in animal production facilities with a green roof. • Green roof can improve air quality in animal production. • Green roof can reduce the thermal stress of the animals in the premises. • Green roof can contribute to the sustainability of animal production. [ABSTRACT FROM AUTHOR]