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Abstract: Hyperspectral remote sensing provides great potential to monitor and study biodiversity of tropical forests through species identification and mapping. In this study, five species were selected to examine crown-level spectral variation within and between species using HYperspectral Digital Collection Experiment (HYDICE) data collected over La Selva, Costa Rica. Spectral angle was used to evaluate the spectral variation in reflectance, first derivative and wavelet-transformed spectral domains. Results indicated that intra-crown spectral variation does not always follow a normal distribution and can vary from crown to crown, therefore presenting challenges to statistically define the spectral variation within species using conventional classification approaches that assume normal distributions. Although derivative analysis has been used extensively in hyperspectral remote sensing of vegetation, our results suggest that it might not be optimal for species identification in tropical forestry using airborne hyperspectral data. The wavelet-transformed spectra, however, were useful for the identification of tree species. The wavelet coefficients at coarse spectral scales and the wavelet energy feature are more capable of reducing variation within crowns/species and capturing spectral differences between species. The implications of this examination of intra- and inter-specific variability at crown-level were: (1) the wavelet transform is a robust tool for the identification of tree species using hyperspectral data because it can provide a systematic view of the spectra at multiple scales; and (2) it may be impractical to identify every species using only hyperspectral data, given that spectral similarity may exist between species and that within-crown/species variability may be influenced by many factors. [Copyright &y& Elsevier]

Abstract: After leaves are clipped their reflectance properties change over time at variable rates. Spectral change can in part be attributed to the changing water content of the leaf, which affects absorption in the VIS, NIR and the SWIR. Maintaining water volume within samples has been the motivation behind many leaf handling techniques. This study has assessed the time constraints between leaf collection and spectral measurement. Specifically the relationship between leaf water content and foliar spectra (350–2500 nm) was examined over time for five tropical trees (common guava (Psidium guajava), purple guava (Psidium littorale), weeping fig (Ficus benjamina), floss silk (Chorisia speciosa), and coffee (Coffea arabica)). This investigation was carried for leaves wrapped with moist gauze around their petiole (treatment leaves) and leaves with no treatment. Spectral measurements and mass measurements were repeated for each leaf once every hour for the first 12 h, then every 4–6 h for 18 h, followed by one measurement after 12 h, and finally once a day until the control samples became air-dry. Foliar reflectance in the visible spectrum was not immediately responsive to water content changes and did not change until wilting of the leaf was observed. The NIR and SWIR wavelength regions were affected immediately by small changes in water content. Thus, by the time wilting was first observed the NIR and SWIR foliar reflectance differed considerably from corresponding fresh leaf reflectance. No common time limit could be observed for leaf clipping and reflectance measurement. Leaves have a variety of water contents and dehydration rates hence measurement time constraints are dependent on the properties of the leaf or species. Rather than using a time limit it is recommended that leaf handling techniques be based upon managing leaf water content and leaf structure. The results of this study indicate that leaves with petioles wrapped in moist paper towel and placed within plastic bags will maintain leaf reflectance longer than equivalent leaves without treatment; samples tested here lasted a minimum of 7 days. θ and D indices (“angle difference” and “root mean square difference”, respectively) revealed a stronger relationship between leaf water content and spectral shape than between leaf water and raw reflectance magnitude. The ratio of 1187/1096 nm, when compared with θ and D indices and individual reflectance bands, showed the highest coefficient of determination with leaf water content (r 2 =0.952). [Copyright &y& Elsevier]

Compact Airborne Spectrographic Imager (CASI) hyperspectral data is used to investigate the effects of topography on the selection of spectral end members, and to assess whether the topographic correction improves the discrimination of rock units for lithologic mapping. A publicly available Digital Elevation Model (DEM), at a scale of 1:50,000, is used to model the radiance variation of the scene as a function of topography, assuming a Lambertian surface. Skylight is estimated and removed from the airborne data using a dark object correction. The CASI data is corrected on a pixel-by-pixel basis to normalize the scene to a uniform solar illumination and viewing geometry. The results show that topography has the effect of expanding end member clusters at times resulting in the overlap of clusters and that the correction process can effectively reduce the variation in detected radiance due to changes in local illumination. When topographic effects are embedded in the hyperspectral data, methods typically used for the selection of end members, such as the convex hull method, can miss end members or result in the selection of nonrepresentative pixels as end members. Thus, end members selected by some conventional methods are very likely “incomplete” or “nonrepresentative” if the topographic effect is embedded in the data. As shown in this study, the topographic correction can reveal hidden end members and achieve a better representation of end members via the statistical center of isolated clusters. [Copyright &y& Elsevier]

The early identification of natural oil seepages or accidental leaks onshore is not a well explored theme in the literature. Location and mapping of contaminated areas can indicate the presence of a subsurface reservoir and guide direct exploration operations in the oil industry. Superficial occurrences of hydrocarbons (HCs) can also indicate damage to pipelines. Locating small leaks can guide containment, cleaning and repair operations. Remote sensing tools for such purposes usually focus on the effects that oil in the soil causes on the spectral signatures of vegetation. Studies investigating the spectral characteristics of soil and HC mixtures are not prevalent. This study comprises the conception and analysis of a spectral library of mixtures of several mineral substrates impregnated with various concentrations of light to heavy oils (API varying from 19.4 to 41.9), using data acquired with an automated hyperspectral imaging station and processed with wavelets. The wavelet transform allowed the extraction of key spectral features and the discard of secondary information (e.g. noise and continuum), resulting in hyperspectral imagery products that proved suitable to separate different phases in the soil-HC mixture, as well as to identify the type and concentration of HC in the soil. This comprehensive spectral library and the acquired information regarding spectral characteristics of soil-hydrocarbon mixtures, opens opportunities for the development of new processing methods for the direct mapping of onshore seeps and leaks using current and future orbital hyperspectral (Hyperion; EnMap; HyspIRI) and multispectral (WordView-3) sensors. [ABSTRACT FROM AUTHOR]