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Light availability in lakes or reservoirs is affected by optically active components (OACs) in the water. Light plays a key role in the distribution of phytoplankton and hydrophytes, thus, is a good indicator of the trophic state of an aquatic system. Diffuse attenuation of photosynthetic active radiation (PAR) (Kd(PAR)) is commonly used to quantitatively assess the light availability. The PAR and the concentration of OACs were measured at 206 sites, which covered 26 lakes and reservoirs in Northeast China. The spatial distribution of Kd(PAR) was depicted and its association with the OACs was assessed by grey incidences(GIs) and linear regression analysis. Kd(PAR) varied from 0.45 to 15.04 m-1. This investigation revealed that reservoirs in the east part of Northeast China were clear with small Kd(PAR) values, while lakes located in plain areas, where the source of total suspended matter (TSM) varied, displayed high Kd(PAR) values. The GIs and linear regression analysis indicated that the TSM was the dominant factor in determining Kd(PAR) values and best correlated with Kd(PAR) (R2 = 0.906, RMSE = 0.709). Most importantly, we have demonstrated that the TSM concentration is a reliable measurement for the estimation of the Kd(PAR) as 74% of the data produced a relative error (RE) of less than 0.4 in a leave-one-out cross validation (LOO-CV) analysis. Spatial transferability assessment of the model also revealed that TSM performed well as a determining factor of the Kd(PAR) for the majority of the lakes. However, a few exceptions were identified where the optically regulating dominant factors were chlorophyll-a (Chl-a) and/or the chromophroic dissolved organic matter (CDOM). These extreme cases represent lakes with exceptionally clear waters. [ABSTRACT FROM AUTHOR]

Sun induced chlorophyll fluorescence (SICF) emitted by phytoplankton provides considerable insights into the vital role of the carbon productivity of the earth's aquatic ecosystems. However, the SICF signal leaving a water body is highly affected by the high spectral variability of its optically active constituents. To disentangle the SICF emission from the water-leaving radiance, a new high spectral resolution retrieval algorithm is presented, which significantly improves the fluorescence line height (FLH) method commonly used so far. The proposed algorithm retrieves the reflectance without SICF contribution by the extrapolation of the reflectance from the adjacent regions. Then, the SICF emission curve is obtained as the difference of the reflectance with SICF, the one actually obtained by any remote sensor (apparent reflectance), and the reflectance without SICF, the one estimated by the algorithm (true reflectance). The algorithm first normalizes the reflectance spectrum at 780 nm, following the similarity index approximation, to minimize the variability due to other optically active constituents different from chlorophyll. Then, the true reflectance is estimated empirically from the normalized reflectance at three wavelengths using a machine learning regression algorithm (MLRA) and a cubic spline fitting adjustment. Two large reflectance databases, representing a wide range of coastal and ocean water components and scattering conditions, were independently simulated with the radiative transfer model HydroLight and used for training and validation of the MLRA fitting strategy. The best results for the high spectral resolution SICF retrieval were obtained using support vector regression, with relative errors lower than 2% for the SICF peak value in 81% of the samples. This represents a significant improvement with respect to the classic FLH algorithm, applied for OLCI bands, for which the relative errors were higher than 40% in 59% of the samples. [ABSTRACT FROM AUTHOR]