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We report the discovery of optical ghosts generated when using Volume Phase Holographic (VPH) gratings in spectrographs employing the Littrow configuration. The ghost is caused by light reflected off the detector surface, recollimated by the camera, recombined by, and reflected from, the grating and reimaged by the camera onto the detector. This recombination can occur in two different ways. We observe this ghost in two spectrographs being developed by the University of Wisconsin - Madison: the Robert Stobie Spectrograph for the Southern African Large Telescope and the Bench Spectrograph for the WIYN 3.5m telescope. The typical ratio of the brightness of the ghost relative to the integrated flux of the spectrum is of order 10^-4, implying a recombination efficiency of the VPH gratings of order 10^-3 or higher, consistent with the output of rigorous coupled wave analysis. Any spectrograph employing VPH gratings, including grisms, in Littrow configuration will suffer from this ghost, though the general effect is not intrinsic to VPH gratings themselves and has been observed in systems with conventional gratings in non-Littrow configurations. We explain the geometric configurations that can result in the ghost as well as a more general prescription for predicting its position and brightness on the detector. We make recommendations for mitigating the ghost effects for spectrographs and gratings currently built. We further suggest design modifications for future VPH gratings to eliminate the problem entirely, including tilted fringes and/or prismatic substrates. We discuss the resultant implications on the spectrograph performance metrics., Comment: 13 pages, 8 figures, emulateapj style, accepted for publication in PASP