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The aeronautical industry constantly strives for efficient technologies to facilitate hole-making in CFRP/Ti6Al4V structural components. The prime challenge in this direction is excessive tool wear because of the different engineering properties of both materials. Nanofluid minimum quantity lubrication (NF-MQL) is the latest technology to provide synergistic improvement in tool tribological properties and lubrication function during machining. In the current study, an MoS2-based NF-MQL system was applied during helical milling using a FIREX-coated tool. In-depth analysis of wear, a scanning electron microscope (SEM), and electron deposition spectroscopy (EDS) were used to evaluate workpiece elemental transfer and tool wear mechanisms. Experimental findings showed that 1% nanoparticles concentration in lubricant resulted in low tool wear of 13 µm after 10 holes. The SEM and EDS analyses depicted formation of tribo-film on the surface, resulting less severe wear and a reduced degree of adhesion. However, a low nanoparticle concentration of 0.5% resulted in 106 µm tool wear after 10 holes with slight evidence of tribo-film. Parametric analysis based on eccentricity, spindle speeds (individual for CFRP and Ti6Al4V), axial pitch, and tangential feed showed correlations with mechanical damage. An extended study of up to 200 holes showed diffusion of C element at a high rate as compared to metal elements such as W and Co. The lowest tool wear was observed using eccentricity level 1, spindle speed Ti6Al4V 1000 rpm, spindle speed CFRP 7500 rpm, tangential feed 0.01 mm/tooth, axial pitch 1.5 mm, and 1% of MoS2 nanoparticles. [ABSTRACT FROM AUTHOR]

Development of gas sensors displaying improved sensing characteristics including sensitivity, selectivity, and stability is now possible owing to tunable surface chemistry of the sensitive layers as well as favorable transport properties. Herein, zinc ferrite (ZnFe2O4) nanoparticles (NPs) were produced using a microwave-assisted hydrothermal method. ZnFe2O4 NP sensing layer films with different thicknesses deposited on interdigitated alumina substrates were fabricated at volumes of 1.0, 1.5, 2.0, and 2.5 µL using a simple and inexpensive drop-casting technique. Successful deposition of ZnFe2O4 NP-based active sensing layer films onto alumina substrates was confirmed by X-ray diffraction and atomic force microscope analysis. Top view and cross-section observations from the scanning electron microscope revealed inter-agglomerate pores within the sensing layers. The ZnFe2O4 NP sensing layer produced at a volume of 2 μL exhibited a high response of 33 towards 40 ppm of propanol, as well as rapid response and recovery times of 11 and 59 s, respectively, at an operating temperature of 120 °C. Furthermore, all sensors demonstrated a good response towards propanol and the highest response against ethanol, methanol, carbon dioxide, carbon monoxide, and methane. The results indicate that the developed fabrication strategy is an inexpensive way to enhance sensing response without sacrificing other sensing characteristics. The produced ZnFe2O4 NP-based active sensing layers can be used for the detection of volatile organic compounds in alcoholic beverages for quality check in the food sector. [ABSTRACT FROM AUTHOR]

Nanotechnology addresses numerous environmental problems such as wastewater treatment. Ground water, surface water and wastewater that is contaminated by toxic organic, inorganic solutes and pathogenic microorganisms can now be treated through the application of nanotechnology. The study reports iron@copper (Fe@Cu) nanoparticles, iron nanoparticles (FeNPs) and copper nanoparticles (CuNPs) synthesized using a bioflocculant in a green approach technique. Characterization of the as-synthesized materials was achieved using analytical techniques such as Fourier transform-Infrared spectroscopy (FT-IR), Thermogravimetric analysis (TGA), Scanning Electron Microscope (SEM), Transmission Electron Microscopy (TEM), UV-Vis spectroscopy (UV-Vis) and X-ray diffraction (XRD). The presence of hydroxyl (–OH) and amine (–NH2) groups was shown by FT-IR spectroscopy studies and the as-synthesized material was shown to be thermostable. Elements such as oxygen, carbon, iron and copper were found to be abundant in Wt%. Absorption peaks were found between 200 and 390 nm wavelength and diffraction peaks at 2θ –29°, 33° and 35° for FeNPs, CuNPs and Fe@Cu, respectively. In their application, the effect of various parameters on the flocculation activity were evaluated. Both the CuNPs and (Fe@Cu) nanoparticles have shown the best flocculation activity at a concentration of 0.2 mg/mL with over 90% activity, while the dosage size with a concentration of 0.4 mg/mL was optimal for FeNPs. The FeNPs were found to be cation dependent, while CuNPs and Fe@Cu nanoparticles flocculate in the absence of a cation and flocculate both in acidic and alkaline pH. All the synthesized nanoparticles are thermostable and maintain flocculation activity above 80% at 100 °C. Both the Fe@Cu and CuNPs were found to be effective in removing dyes with the removal efficiency above 89% and were found to be effective in removal of chemical oxygen demand (COD) and biochemical oxygen demand (BOD) in Mzingazi river water and coal mine wastewater with over 80% removal efficiency. Moreover, the synthesized nanoparticles showed some remarkable antimicrobial properties when evaluated against Gram-positive and Gram-negative bacteria. The as-synthesized material was found to be safe to use at low concentration when verified against human embryonic cells (HEK293) and breast cancer cells (MCF7) and biodegradable. [ABSTRACT FROM AUTHOR]