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• ∼1.4 Ga juvenile magmatism occurs in most microcontinents in the southern CAOB. • The microcontinents show distinct evolution compared to nearby cratons at ∼1.4 Ga. • Mesoproterozoic magmatism records geodynamic transition along the margin of Nuna. The southern Central Asian Orogenic Belt contains numerous microcontinents including the Kazakhstan-Yili block, Central Tianshan Arc and Junggar block in the west, the Erguna, Xing'an, Songliao and Jiamusi-Khanka blocks in the east, bridging by the Tuva-Mongolia block, Beishan Orogenic Belt and Alax block in the central region. New geochemical and geochronological data from the microcontinental blocks within the southern Beishan Orogenic Belt provide new insight into the Precambrian crustal evolution of this region. Five granitoids from the Jiujing region yielded igneous zircon 206Pb/238U ages of 1450–1401 Ma, and zircon xenocrysts from late Paleozoic plutons in the Jiujing, Qiaowan, and Shibandun regions have 206Pb/238U ages that also cluster at ∼1.4 Ga. Those data suggest that crust of this age is widespread beneath the southern Beishan Orogenic Belt. The ∼1.4 Ga zircons display depleted Hf isotopic signatures (ε Hf(t) = 2.0–11.1) and show relatively young two-stage Hf model ages (1.9–1.4 Ga), indicating rapid reworking of juvenile mantle-derived materials. Integrating these results with similar geochronological data from the Kyrgyz North Tianshan, Yili block, Central Tianshan Arc, northern Alxa block and Xilinhot block, we propose that the CAOB incorporates an extensive assemblage of Mesoproterozoic (1450–1360 Ma) magmatism that can be traced over ca. 3000-km long a west-east trending belt. These Mesoproterozoic granitoids display distinct geochemical signatures (e.g., Ga/Al*10,000 ranging from 1.46 to 3.88 and Zr + Nb + Ce + Y varying largely from 101 to 1066 ppm) and show a temporal progression from orogenic to anorogenic over a relatively short period. This suggests a tectonic setting that likely evolved from compressional to extensional environments during 1450–1360 Ma, perhaps resulting from slab roll back. We suggest that the 1450–1360 Ma magmatism along the southern CAOB corresponds with a transition from a compressional to extensional environment on the margin of the Nuna supercontinent. [ABSTRACT FROM AUTHOR]

An early extensive Neoproterozoic (ca. 900 Ma) continental magmatic arc system covering hundreds of kilometers has been reported to occur in the South Beishan Orogenic Belt (SBOB) and the Central Tianshan (CTA) in the southern Central Asian Orogenic Belt (CAOB). However, evidence for coeval high-grade metamorphism and thus the formation of an accretionary orogen in the framework of Rodinia is ambiguous or absent. This study provides new petrological, geochemical and geochronological data for garnet-bearing schists (quartz + garnet + biotite + plagioclase ± muscovite) from the SBOB in order to constrain its Neoproterozoic metamorphic history. The metamorphic zircon rims are either unzoned or display sector zoning in CL-images and reveal REE patterns with flat HREE patterns and negative Eu anomalies, which are interpreted to be in chemical equilibrium with garnet and plagioclase. The zircon U-Pb dating yields concordant U-Pb ages of 900 ± 3 Ma, 897 ± 2 Ma and 898 ± 4 Ma for the metamorphic zircon rims. The inherited detrital zircon cores of one sample display a concordant U-Pb age of 1397 ± 5 Ma that is consistent with the timing of formation for the extensive Mesoproterozoic continental arc in the SBOB and CTA. Based on phase equilibrium geothermobarometry and average P-T thermobarometric calculations, minimum amphibolite-facies P-T conditions are estimated to be >600 °C at pressure >0.6 GPa, which is thought to have been overprinted by subsequent Paleozoic metamorphism. However, the Ti-in-zircon thermometer still reveals temperatures of up to 840 °C using the composition of metamorphic zircon rims, suggesting former ca. 900 Ma granulite-facies peak metamorphic temperatures. The combined petrological and geochronological evidence in conjunction with the continental affinity of the regional metamorphic rocks suggests that the SBOB and the eastern CTA experienced an early Neoproterozoic accretionary orogenesis during the final assembly stage of Rodinia. [ABSTRACT FROM AUTHOR]

The South Beishan Orogenic Belt (SBOB) in the southwestern Central Asian Orogenic Belt (CAOB) is thought to be an eastern extension of the Eastern Tianshan Orogen. Up to now, it has been suggested to consist of a well-preserved Paleozoic magmatic and sedimentary sequence with a possible former Neoproterozoic microcontinent. We provide new geochemical and geochronological data for gneissic granites of the SBOB in order to constrain its tectonic evolution and setting. The gneissic granitoids belong to the high-K, calc-alkaline series and are characterized by an enrichment of light rare earth elements (LREE) and large ion lithophile elements (LILE), a depletion of Nb, Ta, Ti, Sr, and Ba and a positive Pb anomaly. The petrography and geochemical signatures reveal a possible I-type granite affinity and are in accordance with typical Andean Arc granites. Zircon grains, yielding 206 Pb/ 238 U magmatic crystallization ages of 933 ± 2 Ma and 900–890 Ma for the Shibanshan and Huaniushan arc granites, respectively, manifest the former presence of an early Neoproterozoic Precambrian microcontinent in the SBOB. Zircon ɛ Hf ( t ) values range from −16.1 to 10.2, indicating that juvenile material and reworked ancient crust were involved in the source of the gneissic granites. Furthermore, in conjunction with studies of the adjacent regions, the results of the present study suggest that the former Precambrian microcontinent in the SBOB neither belonged to the nearby Dunhuang Block nor the Tarim Craton, but has a common affinity with the Central Tianshan Arc Terrane. It is also suggested that the 900–890 Ma plutons originated from the mixing of juvenile material with older crust in an Andean-type active continental arc setting during the assembly of Rodinia. Thus the SBOB plays a key role in understanding the tectonic evolution of the CAOB. [ABSTRACT FROM AUTHOR]

Highlights: [•] TTG in the interior of the Dunhuang blocks was formed at ∼2.7–2.6Ga. [•] Tarim experienced two-stage (∼2.7–2.6 and ∼2.5Ga) intrusion of Archean TTG. [•] Tarim was characterized by episodic generation of juvenile continental crust. [•] Paleoproterozoic and Paleozoic tectonothermal events were prevail in the Tarim craton. [•] Paleoarchean continental crust as old as ∼3.4Ga may have existed in the Dunhuang block [Copyright &y& Elsevier]

• Negative Ce anomaly in the Gaoyuzhuang and Hongshuizhuang formations provides the evidence of transient oxygenation of the Mesoproterozoic ocean. • The proposed Ce anomaly depth model provide a quantitative constrain the surface environment of the Yanshan Basin. • Transient oxygenations could have provided vital niches for the evolution of eukaryotes. Predominantly anoxic conditions with a heterogeneous stratified water column are widely accepted for the Mesoproterozoic ocean. However, transient and episodic oxygenation during the Mesoproterozoic has been recently hypothesized, which may have been an important trigger for eukaryote evolution. In this study, we analyzed the Ce anomalies of the Gaoyuzhuang and Hongshuizhuang formations in North China, to investigate the Earth's surface environment during the Mesoproterozoic. Our data of negative Ce anomalies in the Gaoyuzhuang and Hongshuizhuang formations, reaching 0.73 and 0.84, respectively, suggest transient oxygenations of the surface environment. We applied a Ce N /Ce N * depth model to quantify these transient oxygenations and the results suggest that the atmospheric oxygen level would have increased by 0.01–0.03% present atmospheric level (PAL), 0.02–0.05% PAL, and 0.1–0.4% PAL, with the respective initial levels of 0.05% PAL, 0.1% PAL, and 1% PAL, in the Gaoyuzhuang and Hongshuizhuang formations. Our results suggest that although oxygen levels in the Mesoproterozoic were low, transient oxygenation may have occurred in the surface ocean, which would have provided vital niches for the evolution of eukaryotes. [ABSTRACT FROM AUTHOR]

• A link between mantle thermal, redox evolution and speciation of C-O-H magmatic volatiles is established, which is used to assess the contribution of mantle degassing on atmospheric oxidation. • We find that a rapid oxidization of Archean mantle related to recycling of oceanic crust, core-mantle material exchange, or evolution of primitive mantle redox heterogeneities can strongly reduce the fraction of reducing compositions (e.g., H 2 and CH 4) in volcanic gases, which then consumed less photosynthetic oxygen, leading to a net increase of atmospheric oxygen and triggering the Great Oxidation Event (GOE) at 2.4–2.3 Ga. • After the GOE, atmospheric oxidation events were likely triggered by plume and rifting degassing during supercontinent breakup. • Before the GOE, scattered oxygen oases can be produced above plume impingent regions. The C-O-H cycling of the early shallow Earth is suggested to be closely related to mantle degassing and speciation processes. These processes are influenced by the mantle's thermal and redox states, which have changed significantly in different mantle reservoirs during Earth's protracted history. However, the link between speciation of C-O-H magmatic volatiles and the temporal changes of the mantle's thermal and redox states in different mantle reservoirs remains elusive. We test this link through chemical equilibrium modeling of C-O-H magmatic volatiles to assess its influences on shallow C-O-H cycling and the oxidization history of the shallow Earth. We find that a rapid oxidization of Archean mantle related to recycling of oceanic crust, core-mantle material exchange, or evolution of primitive mantle redox heterogeneities can strongly reduce the fraction of reducing compositions (e.g., H 2 and CH 4) in volcanic gases, which then consumed less photosynthetic oxygen, leading to a net increase of atmospheric oxygen and triggering the Great Oxidation Event (GOE) at 2.4–2.3 Ga. After the GOE, mantle degassing at rifts, mid ocean ridges, and plumes became more oxidizing and thus triggered later atmospheric oxidation synchronous with supercontinent breakup. Our results support that the oxidation of the atmosphere in the Precambrian was influenced by mantle oxidation, upwelling and/or degassing, especially during the GOE. [ABSTRACT FROM AUTHOR]

• Granitoids of Singhbhum Craton. • Two generation of TTGs at 3.42 and 3.32 Ga formed by melting of juvenile mafic crust. • Later K-rich, silicic granites at 3.28 and 3.25 Ga formed by melting of tonalites. • Recurring crustal melting in a gradually thickening oceanic plateau. • Final cratonisation of the Singhbhum Craton at 3.25 Ga. A significant part of many Archean cratons formed during Paleoarchean. Yet, the mechanism and tectonic setting of formation of Paleoarchean continental crust remain highly debated. In this contribution, we present field, petrographic, geochemical, zircon U-Pb age and Hf isotope data on Paleoarchean granitoids from west-central part of the Singhbhum Craton (Champua-Hat Gamharia corridor), India. The whole process starting from nucleation of a juvenile continent to its evolution and final stabilization is documented. The core of the craton nucleated with formation of 3.45–3.40 Ga TTGs showing juvenile character (zircon ɛHf t = +0.6 to +7.1). These rocks show slightly depleted HREE and Y, negligible Eu-anomaly (Eu/Eu* = 0.90 to 1.00) and moderate Sr/Y (25–64), consistent with derivation from a low-K mafic crust at a pressure near the lower end of the garnet stability field, causing subordinate garnet retention in the residue and negligible role of plagioclase. A second generation of TTG formation took place at 3.32 Ga in the area by deeper melting of a juvenile mafic crust (zircon ɛHf t = +1.3 to +5.7) as suggested by strongly depleted HREE and Y, and high Sr/Y (52–155) implying significant amount of garnet retention in the residue. Subsequently, the area witnessed intracrustal melting at 3.28 and 3.25 Ga which tapped moderately old to juvenile (zircon ɛHf t = −1.9 to +4.5), mostly TTG sources at variable depths generating potassic, LILE-enriched, high-silica granites. Intrusion of these potassic granites marks the final cratonization of the Singhbhum Craton. The sequence of events is interpreted in terms of repeated crustal melting and granitoid generation in a gradually thickening oceanic plateau with a progressive change in granitoid source from mafic to felsic in composition. A synthesis of rock assemblage, regional geological setting and structural pattern also supports intraplate nature of the magmatism in Singhbhum Craton, which might have been a significant mechanism of crustal growth worldwide during Paleoarchean. Further, a comparison of juvenile crustal growth and crustal reworking events of the Singhbhum and other Indian cratons show that these cratons record distinct evolutionary histories and were probably nucleated at different sites. [ABSTRACT FROM AUTHOR]

Palaeoarchaean granitoids are exposed over wide area in the Singhbhum craton whose origin and role in crustal evolution are not well constrained. This study presents whole-rock and mineral chemical data coupled with zircon U-Pb dating and Hf isotope results on such granitoids from the central part of the craton to understand their petrogenesis, tectonic setting and role in continental crustal evolution. The first phase of granitoid magmatism in this area is represented by a 3.47 Ga Na-rich, gneissic tonalite belonging to the Archaean TTG (tonalite-trondhjemite-granodiorite) suite. This rock is characterized by high-HREE (heavy rare earth elements), negative Eu anomaly, low Sr/Y ratio and positive zircon Hf isotope signature (εHf t = +2.1 to +4.8). It is interpreted to be formed by shallow melting of a juvenile mafic source. At 3.35 Ga a silicic, ferroan porphyritic biotite granite formed. It shows variable K/Na, low Y and high Sr/Y, moderately fractionated HREE and positive zircon εHf t (+1.8 to +4.0), and is explained as a product of high-temperature melting of a heterogeneous, juvenile source consisting of tonalites and mafic rocks at lower crustal depth. The final phase of granitoid magmatism is marked by a 3.30 Ga non-porphyritic ferroan, silica-rich biotite granite. Geochemical characteristics like moderately high K, moderately fractionated HREE, low Ca and Sr/Y, and zircon εHf t (+0.8 to +3.7) suggest that the granite was formed by high-pressure melting of a tonalite-dominated source with short crustal residence. All the three granitoid phases display low Mg, Ni and Cr contents and magnesium number (Mg#) precluding direct involvement of mantle in their origin. Rather, crustal reworking caused by episodic plume-related mafic-ultramafic magma underplating and intraplating in an oceanic plateau setting is suggested as the possible mechanism for formation of the granitoids. Successive crustal reworking events involved progressively greater amount of previously formed felsic crust generating more evolved, K-rich granitoids. It appears to be a globally important process which led to effective crustal differentiation and maturing of the cratons during Palaeoarchaean. [ABSTRACT FROM AUTHOR]

U–Pb zircon dating for 10 rock samples collected from the Archean Jiaobei terrain of the eastern block of the North China craton (NCC) yield three groups of ages: ∼2.9 Ga, ∼2.7 Ga and ∼2.5 Ga. Thirteen rock samples studied can be classified into a low Mg# (molecular Mg/(Mg + Fe)) (Mg# = 34–52) and a high Mg# group (Mg# = 52–61), respectively. The low Mg# rocks are typical Archean TTGs with emplacement ages of ∼2.9 Ga, ∼2.7 Ga and ∼2.5 Ga whereas the high Mg# rocks are Archean sanukitoids with age of ∼2.5 Ga. Despite having different ages, all the Jiaobei TTGs have zircon δ 18 O values between 5.6‰ and 6.3‰, essentially identical to those of the ∼2.7 Ga TTGs from adjourning Taishan area and Archean TTGs from other parts of the world. Magmatic zircons from the Jiaobei sanukitoids have δ 18 O values between 6.4‰ and 7.5‰, significantly higher than the Archean TTGs. The whole-rock Nd and the zircon Hf isotopic compositions indicate that the ∼2.9 Ga and ∼2.5 Ga TTGs and ∼2.5 Ga sanukitoids represent crustal growth at ∼2.9 Ga and ∼2.5 Ga in the Jiaobei terrain. Unlike the ∼2.7 Ga TTGs in the adjourning Taishan area that are considered to reflect juvenile crust, the Jiaobei ∼2.7 Ga TTGs, however, are most likely resulted from the reworking of the pre-existing ∼3.0 Ga crust. This is in contrast to the previous suggestion that ∼2.7 Ga is the most significant crust-forming episode and ∼2.5 Ga a period of crustal reworking in the Jiaobei terrain. The high Mg# and high contents of Cr, Ni, LREE and LILE of the ∼2.5 Ga Jiaobei sanukitoids, require a metasomatized peridotitic mantle source for their origin. The significant negative Zr and Hf anomalies and the elevated δ 18 O values of the ∼2.5 Ga sanukitoids, are inconsistent with a mantle source metasomatized solely by the TTG melts. Instead, we suggest that the Jiaobei sanukitoids could have originated from a mantle wedge metasomatized by a high δ 18 O component, most likely the slab-derived fluids. The similarity of multi-element patterns and the zircon δ 18 O values between the Jiaobei and Superior Province sanukitoids may imply similar processes involved to form sanukitoids in both Jiaobei and Superior Province terrains. [ABSTRACT FROM AUTHOR]

Highlights: [•] Granitoid magmatism changed in composition with evolution of Kadiri greenstone belt. [•] Initial sanukitoid magmatism was followed by transitional TTG, leucogranite and A-type granite. [•] A convergent setting characterized by repeated slab break-off and crustal reworking. [•] Finally post-subduction anorogenic granite magmatism. [•] Reworking of Mesoarchaean crust in eastern Dharwar craton identified. [Copyright &y& Elsevier]

Abstract: A combined study of zircon U–Pb and Lu–Hf isotopes and whole rock major and trace elements and Sr–Nd isotopes has been conducted for 10 tonalitic–trondhjemitic–granodioritic (TTG) and granitic gneisses from the Kongling terrain, the only known Archean microcontinent in the Yangtze craton, South China. The results reveal a significant magmatic event at ∼2.6–2.7Ga, in addition to the previously reported ∼2.9Ga and ∼3.2–3.3Ga magmatism. The ∼2.6–2.7Ga rocks show relatively high REE (530–1074ppm), apparently negative Eu anomaly (Eu/Eu*=0.22–0.35), low #Mg (19.51–22.63) and low LaN/YbN (10.3–24.2). Besides, they have high K-feldspar proportion and relatively evaluated (K2O+Na2O)/CaO, TFeO/MgO, Zr, Nb, Ce and Y contents. Their 10,000×Ga/Al ratios range between 3.00 and 3.54. All these features suggest that the protoliths of these gneisses are A-type granites. Most of the ∼2.6–2.7Ga zircon grains have ɛ Hf(t) values >0 (up to 7.93, close to the depleted mantle value). This clearly indicates a considerably higher proportion of new crustal components in the ∼2.6–2.7Ga granitoids compared to the ∼3.2–3.3Ga and ∼2.9Ga TTGs. Our results support the conclusion of worldwide studies of igneous and detrital zircons that age peaks at 2.65–2.76Ga represent increases in the volume of juvenile continental crust. The present study also confirms the existence of the two older magmatic events in the Kongling terrain. Both whole rock ɛ Nd(t) values (−3.74 to 1.59) and the zircon ɛ Hf(t) values (−11.18 to 3.55) for the ∼2.9Ga TTG and the Hf isotopes of ∼3.2–3.3Ga igneous zircons (−7.37 to 3.12) are chondritic or subchondritic, suggesting that they were mainly generated by reworking of older rocks with a small amount of new crustal additions. [Copyright &y& Elsevier]

• Crustal xenoliths trapped by Guojialing granodiorites display rather low Au contents. • The Precambrian metamorphic outcrop rocks also show low Au contents. • The metal contents are consistent with the metamorphic devolatilization model. • The Precambrian basement was not the main Au source for Jiaodong giant gold deposits. The Jiaodong gold deposits, eastern China define a giant gold province in the Precambrian high-grade metamorphic crustal basement. Given the early metamorphism, the crustal basement would have been so depleted in gold that cannot be the main source for the later Mesozoic gold deposits. However, previously reported gold contents from crustal rocks were variably high (e.g., >5–10 ppb) and often interpreted to reflect the contribution of crustal basement. In this study, after careful field sampling, we obtained high-precision Au and S contents (with Cu and Ag for many samples) to solve the controversial issue. The Au contents were determined by internal standardization to platinum which was obtained from isotope dilution via high-sensitivity Element XR, and/or another independent method by GFAAS after polyurethane foam pretreatment. These methods achieved low procedural blanks (<0.02 ppb) and reliable analyses of low-Au samples. The analyzed metamorphic crustal rocks are from surface outcrops (n = 30) and crustal xenoliths (n = 10) in the Jiaobei terrane, where hosts the predominant Jiaodong gold resources (>85% of 5000 t). The Archean and Paleoproterozoic metamorphic outcrop rocks were sampled far from gold deposits and faults with the minimum effect of ore-forming fluids, and they display overall low Au contents (0.20 ± 0.18 ppb and 0.47 ± 0.29 ppb, respectively). More importantly, the crustal xenoliths trapped in pre-mineralization Guojialing granodiorites were not affected by hydrothermal overprint and better reflect the pristine features of the metamorphic basement. Although the crustal xenoliths contain variable sulfides with a wide range of Cu, Ag and S contents, they show rather low Au contents (0.18 ± 0.15 ppb). These results indicate the strong depletion of Au contents in the Precambrian crustal basement, consistent with the metamorphic devolatilization model. The Precambrian metamorphic crustal basement thus was rather difficult as the main gold source for the Jiaodong gold deposits, suggesting alternative sources. [ABSTRACT FROM AUTHOR]

• The Fe speciation data help bridge the global data gap of Fe species gap during 1500–1400 Ma. • The global Fe speciation data suggest underestimated oxic depositional conditions during the Mesoproterozoic. • Oxic environment could have provided suitable habitats for complex eukaryotes and their subsequent evolution. The Mesoproterozoic (1600–1000 million years ago, Ma) is thought to have experienced important changes in ocean chemistry and eukaryote evolution. Our understanding of global redox conditions remains in its infancy, and redox data derived from the Mesoproterozoic thus far indicate heterogeneity and complexity in the realm of ocean redox, which hampers our understanding of the potential significance of variations in ocean redox on eukaryote evolution. In this study, we report analyses of Fe species and redox-sensitive trace metals of U and Mo from the Jixian Group, including the Wumishan, Hongshuizhuang and Tieling formations, as well as the Xiamaling Formation, in the Yanshan Basin in North China. The Fe speciation data from the Wumishan, Hongshuizhuang, and Tieling formations first reported in this study help bridge the global data gap of Fe species data during 1500–1400 Ma. Our data suggest likely oxic bottom water conditions for the Wumishan Formation and ferruginous bottom water conditions for the Tieling Formation. The Fe species data can distinguish ferruginous conditions for the upper Hongshuizhuang from sulfidic depositional conditions for the lower-middle Hongshuizhuang Formation. Based on Fe species and trace metal data, redox conditions likely varied from anoxic conditions with transient euxinia in the lower-middle Xiamaling Formation to oxic conditions in the upper Xiamaling Formation. The new Fe speciation data from the Yanshan Basin, when combined with previously published data, show a surprisingly high proportion of middle Proterozoic samples with very low highly reactive to total iron ratios. This suggests either a relatively large extent of oxic seafloor, or non-uniformitarian iron cycling. Resolving this discrepancy will be key to understanding the extent of suitable habitats for complex eukaryotes. [ABSTRACT FROM AUTHOR]

• Rutile xenocrysts were captured from the basement by the Yangyuan carbonatites. • The Zr-in-rutile thermometer records formation of the rutiles at 743–932 °C. • Cr and Nb contents and Hf isotopes in rutiles support pelitic granulite protoliths. • U-Pb rutile cooling ages peak at 1810 ± 4 Ma, 1735 ± 5 Ma, and 1673 ± 8 Ma. • In combination with dating results from other systems yields episodic cooling path. The amalgamation of the North China Craton along the Trans-North China Orogen at ~1.85 Ga has been widely discussed, but its thermal evolution after amalgamation is relatively poorly constrained. This study presents U-Pb ages, trace element compositions, and Hf isotopes of rutile xenocrysts carried by the Yangyuan Cenozoic carbonatites, revealing an episodic cooling history of the Trans-North China Orogen. The Zr-in-rutile thermometer records formation of the rutiles under granulite facies at 743–932 °C. Cr and Nb concentrations in rutiles support a pelitic protolith, which is consistent with 176Hf/177Hf ratios that are close to zircons from pelitic granulites in the orogen. U-Pb ages of the rutiles are cooling ages, for which three populations can be clearly delineated. In combination with dating results from other systems, three episodes of cooling can be identified: [1] active cooling after the ~1.85 Ga peak metamorphism, with a cooling rate increasing from 7.9 °C/Ma in the period 1850–1810 Ma to 15.3 °C/Ma at 1810–1792 Ma; [2] active cooling after mantle upwelling at ~1.78 Ga, with cooling rate increasing from 8.7 °C/Ma at 1780–1735 Ma to 17.2 °C/Ma between 1735 and 1719 Ma; [3] passive cooling after a rifting event at ~1.68 Ga, with cooling rate decreasing from 20.6 °C/Ma at 1680–1673 Ma to 6.9 °C/Ma in the period 1673–1633 Ma. The first two episodes correspond to exhumation-related cooling, while the last episode resulted from the rift-to-drift transition of the North China Craton due to increasing distance from the heat source during break-up of the Columbia supercontinent. [ABSTRACT FROM AUTHOR]