1. Effect of heterogeneous hydrophobic coating on floating of insoluble particles.
- Author
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Bozon, Annabel, Fries, Lennart, Kammerhofer, Jana, Forny, Laurent, Niederreiter, Gerhard, Palzer, Stefan, and Salman, Agba D.
- Subjects
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HYDROPHOBIC interactions , *SURFACE coatings , *HYDROPHOBIC surfaces , *CONTACT angle , *SURFACE defects , *POWDERS , *COCOA butter - Abstract
Food powders often exhibit hydrophobic surface areas. To understand the effect of corresponding wettability variations on particle floating, which critically influences powder reconstitution, we studied floating of glass beads after creating surface heterogeneity by spraying cocoa butter. Force-position curves were recorded to characterise contact line pinning. Floating of particles with surface heterogeneities comprised a dynamic phase, which to our knowledge has not been reported previously. Measured forces varied due to contact line pinning/depinning. The results indicate that the dynamic floating phase is caused by gradual depinning. Steady-state floating is reached once pinning is sufficiently pronounced. We also demonstrate that surface heterogeneities complicate theoretical predictions of particle floating. The use of sessile drop contact angles for modelling was identified as an important source of error, as weak pinning points can affect contact angles but are oftentimes overcome during floating. Moreover, local pinning effects are not necessarily represented by a sessile drop. [Display omitted] • Distributed hydrophobic defects significantly affect particle floating. • Floating of particles with surface heterogeneities comprises a dynamic phase. • The height of the wettability contrast affects floating position and kinetics. • Force-position curves show contact line pinning at surface defects. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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