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Enhancing the degradability of polyethylene plastics could provide a potential solution to the overwhelming crisis of plastic waste. Conventional studies have focused on the degradation of polyethylene thin films. This study investigated UV-induced photo-degradation according to ASTM D5208-14 in polyethylene sheets with thicknesses ranging from 0.4 to 1.2 mm. The impacts of sample thickness, metal pro-oxidants, polyethylene resin types and foaming were explored through the characterization of the carbonyl index, molecular weight, tensile properties and crystallinity. As pro-oxidants, single iron or manganese stearate demonstrated a concentration-dependent trend in accelerating the photo-degradation of polyethylene sheets. The thickness, foaming and resin type—such as low-density polyethylene (LDPE) and high-density polyethylene (HDPE)—significantly impacted the rate of photo-oxidation. Thick polyethylene sheets (1.2 mm) exhibited a heterogenous and depth-dependent degradation profile. As the photo-degradation progressed, the enhanced crystallinity, reduced UV transmittance and formation of crosslinks were able to prevent further oxidative cleavage of the polyethylene chain. This study investigated the time course and factors affecting the photo-degradation of polyethylene sheets, which could provide insights into the formulation design of photo-degradable polyethylene plastics. [ABSTRACT FROM AUTHOR]

In this research, a new computational method was proposed for describing the mechanical behavior of super-elastic-plastic foams under inhomogeneous compressive impacts. The method regarded the foam material as composed of two typical mechanical properties superimposed multiple times: one was the hyper-elastic layer, and the other was the elastoplastic layer. The hyper-elastic layer and the elastoplastic layer were interwoven and overlapped, divided into double-layer, four-layer, and six-layer configurations to characterize the foam material. After the equivalent layering of the foam, by comparing the results of the four-layer and six-layer divisions, it was found that when the layering reached four layers, the foam performance curve had already converged. The study utilized the HYPERFOAM model and Mullins effect in the ABAQUS software to establish the constitutive relationship of the hyper-elastic layer. It adopted the Crushable foam model to develop the constitutive relationship of the elastoplastic layer. Under uniaxial compression conditions, quasi-static and intermediate strain rate compression tests were performed on polyethylene (PE) foam materials with three different densities. Based on the experimental results, the parameter values of the hyper-elastic-plastic foam model in the ABAQUS code were determined. By comparing the computational results and the experimental results, the established finite element (FE) model was validated using the mechanical behavior of indentation and compression tests. The results showed that this method could effectively describe the complex mechanical behavior and residual deformation of hyper-elastic-plastic foam packaging materials under non-uniform compression, and the experimental and simulation results agreed well, proving the reliability of this method. [ABSTRACT FROM AUTHOR]

Elastic peak electron spectroscopy (EPES) analyzes the line shape of the elastic peak. The reduction in energy of the elastic peak electrons is the result of energy transfer to the target atoms, a phenomenon known as recoil energy. EPES differs from other electron spectroscopies in its unique ability to identify hydrogen in polymers and hydrogenated carbon-based materials. This feature is particularly noteworthy as lighter elements exhibit stronger energy shifts. The energy difference between the positions of the elastic peak of carbon and the elastic peak of hydrogen tends to increase as the kinetic energy of the incident electrons increases. During electron irradiation of an insulating polymer, if the number of secondary electrons emitted from the surface is less than the number of electrons absorbed in the sample, the surface floats energetically until it stabilizes at a potential energy e V s . As a result, the interaction energy changes and modifies the energy difference between the elastic peaks of hydrogen and carbon. In this study, the charge effects are evaluated using the Monte Carlo method to simulate the EPES spectra of electrons interacting with polystyrene and polyethylene. [ABSTRACT FROM AUTHOR]

Polymer blends of poly(L-lactide)-b-poly(ethylene glycol)-b-poly(L-lactide) (PLLA-PEG-PLLA) and high-density polyethylene (HDPE) with different blend ratios were prepared by a melt blending method. The thermal, morphological, mechanical, opacity, and biodegradation properties of the PLLA-PEG-PLLA/HDPE blends were investigated and compared to the PLLA/HDPE blends. The blending of HDPE improved the crystallization ability and thermal stability of the PLLA-PEG-PLLA; however, these properties were not improved for the PLLA. The morphology of the blended films showed that the PLLA-PEG-PLLA/HDPE blends had smaller dispersed phases compared to the PLLA/HDPE blends. The PLLA-PEG-PLLA/HDPE blends exhibited higher flexibility, lower opacity, and faster biodegradation and bioerosion in soil than the PLLA/HDPE blends. Therefore, these PLLA-PEG-PLLA/HDPE blends have a good potential for use as flexible and partially biodegradable materials. [ABSTRACT FROM AUTHOR]

Additives, such as antioxidants (AOs), carbon black (CB) and compatibilizers (COs), are used in recycled polymer blends for different reasons. AOs slow thermal degradation, CB gives blends a black color and protect them against ultraviolet (UV) light, and compatibilizers improve compatibility between the different phases of the mixture and consequently enhance the mechanical properties of the final blend. In this paper, the three additives were added to recycled polyethylene (PE) blends to study their effect on the final properties and to determine the best formulations that help improve the mechanical properties of recycled PE blends. Stress Crack Resistance (SCR) was accessed by performing Notched Crack Ligament Stress (NCLS) and Un-notched Crack Ligament Stress (UCLS). On the other hand, Oxidative Induction Time (OIT) was used to determine the oxidation time of the blends and the effect of each additive on this property. Based on the results of this study, it was proven that adding carbon black and antioxidants delay the thermal degradation of recycled PE blends and consequently improve the OIT. Otherwise, resistance to stress cracking is improved only by adding a compatibilizer to the reference blend. [ABSTRACT FROM AUTHOR]

Plastic production has risen steadily, but recycling rates lag. Researchers are increasingly investigating the use of plastics in road construction, especially in terms of modifying asphalt with waste plastics. The dry process, which involves incorporating plastics into hot aggregates, is increasingly gaining traction as an alternative to the wet process, where plastics are added to hot bitumen. Past studies indicate enhanced asphalt mixture properties with the dry process, but there is debate about the role of waste plastics—whether they should be used as aggregates, fillers, or binder modifiers. This study explores the extent to which dry-added waste plastic modified the binder of the asphalt mixtures. Fluorescent microscopy and scanning electron microscopy revealed the impact of plastic on the binder, while image analysis quantified polymer swelling and dispersion in the binder matrix. It was concluded that when plastics are added to hot aggregates, they will act as binder modifiers. Lower plastic content and reduced polymer crystallinity led to increased polymer swelling and better dispersion in the mixture. This study recommends plastic inclusion of less than 2.5% (by volume) in the dry-added method since high plastic content leads to polymer agglomeration, especially for highly crystalline polymers. Additionally, mixes modified with amorphous plastics exhibited superior workability and performance compared to those modified with crystalline plastics. This study also suggests that using plastics to replace both bitumen and filler can improve cost efficiency, reduce the carbon footprint, and enhance the overall performance of the asphalt mixture. [ABSTRACT FROM AUTHOR]

Ultra-high molecular weight polyethylenes (UHMWPEs) are significant engineering plastics for their unique properties, such as high impact resistance, abrasion resistance, weatherability, lubricity, and chemical resistance. Consequently, developing a suitable catalyst is vital in facilitating the preparation of UHMWPE. The late transition metal catalysts have emerged as effective catalysts in producing UHMWPE due to their availability, enhanced tolerance to heteroatom groups, active polymerization characteristics, and good copolymerization ability with polar monomers. In this review, we mainly focus on the late transition metal catalysts, summarizing advancements in their application over the past decade. Four key metals (Ni, Pd, Fe, Co) for generating linear or branched UHMWPE will be primarily explored in this manuscript. [ABSTRACT FROM AUTHOR]

The direct copolymerization of ethylene with polar monomers to produce functional polyolefins continues to be highly appealing due to its simple operation process and controllable product microstructure. Low-cost nickel catalysts have been extensively utilized in academia for the synthesis of polar polyethylenes. However, the development of high-temperature copolymerization catalysts suitable for industrial production conditions remains a significant challenge. Classified by the resultant copolymers, this review provides a comprehensive summary of the research progress in nickel complex catalyzed ethylene-polar monomer copolymerization at elevated temperatures in the past five years. The polymerization results of ethylene–methyl acrylate copolymers, ethylene-tert–butyl acrylate copolymers, ethylene–other fundamental polar monomer copolymers, and ethylene–special polar monomer copolymers are thoroughly summarized. The involved nickel catalysts include the phosphine-phenolate type, bisphosphine-monoxide type, phosphine-carbonyl type, phosphine-benzenamine type, and the phosphine-enolate type. The effective modulation of catalytic activity, molecular weight, molecular weight distribution, melting point, and polar monomer incorporation ratio by these catalysts is concluded and discussed. It reveals that the optimization of the catalyst system is mainly achieved through the methods of catalyst structure rational design, extra additive introduction, and single-site catalyst heterogenization. As a result, some outstanding catalysts are capable of producing polar polyethylenes that closely resemble commercial products. To achieve industrialization, it is essential to further emphasize the fundamental science of high-temperature copolymerization systems and the application performance of resultant polar polyethylenes. [ABSTRACT FROM AUTHOR]

This study examines the applicability of an unknown composition waste plastic bag sample as bitumen modifier. The waste components were initially characterized to identify the type of plastics and the level of impurity. Asphalt binder performance was examined for rutting, thermal, and age resistance. The results revealed that the waste plastic bags, predominantly consisted of Low-Density Polyethylene (LDPE) and Linear Low-Density Polyethylene (LLDPE) and contained 6.1% impurities. The binder tests indicated that the waste plastic bags enhanced the rutting resistance of bitumen by one grade, with its modification more similar to LLDPE, rather than LDPE. The thermal degradation and aging properties of the modified binders demonstrated that the bitumen modified by the waste plastic bags exhibited slightly lower resistance to temperature and aging compared to virgin LDPE and LLDPE. This was attributed to the impurities contained in the waste plastic. In conclusion, the analyzed waste plastic bags proved to be suitable for use in binder modification, presenting a viable alternative to virgin LLDPE. [ABSTRACT FROM AUTHOR]

This research studies natural rubber (NR) composite blends prepared with recycled polyethylene (PE), polyurethane waste (PU), silica (SiO2), and aluminum trihydroxide (ATH) under the proper mixing conditions using an internal mixer and a two-roll mill. The mechanical, impact, dynamic mechanical, and thermal properties, together with flammability, were investigated. NR/PU composites filled with a specific SiO2/ATH concentration resulted in excellent flame-retardant properties without using PE. Adding PE causes poor flammability, while using PU and SiO2 prevents flame extensibility of the composites. In addition, SiO2 and ATH synergistically improved both mechanical and dynamical mechanical properties. This is attributed to the reinforcement of SiO2 particles inside the matrix, whereas the ATH releases water as a flame retardant. The V-0 composites tested with UL-94 showed acceptable heat resistance, strength, and durability, making them suitable for interior and exterior applications in buildings without the lightweight requirement. [ABSTRACT FROM AUTHOR]

To overcome the degradation of insulating properties caused by the water tree aging of cross-linked polyethylene (XLPE), a self-repairing material for XLPE based on a microcapsule system is proposed. Three-layer shell nucleus microcapsules/XLPE composites with different microcapsule doping content are prepared. The water tree aging experiments are carried out using the water-needle electrode method to analyze the ability of microcapsules to repair the damaged areas of water trees. The results show that, compared with the XLPE material without microcapsules, the electrical properties of composites decline significantly when the doping concentration of three-layer shell nucleus microcapsules is large. When the doping concentration is 1.0 wt%, the microcapsule/XLPE composite breakdown strength has no noticeable change, and the dielectric loss factor does not change significantly, the space charge density decreases, and the space charge properties have been improved considerably. When the water tree branch develops to the position where the microcapsules are located, the microcapsules will rupture and release their internal repair materials and catalysts and react with water to produce an organic silicone resin to fill the water tree cavity, which can achieve an excellent self-healing effect. In addition, the nano-SiO2 on the surface microcapsules can make the microcapsules and matrix better integrated, which avoids the microcapsule accumulation that tends to occur when incorporating microcapsules, thus improving the repair rate. [ABSTRACT FROM AUTHOR]

Acute pneumonia (AP), triggered primarily by pathogens like bacteria and viruses, is a leading cause of human mortality. Ribavirin, a broad-spectrum antiviral agent, plays a pivotal role in the treatment of AP. However, its therapeutic use is hindered by the need for high dosages and the associated cardiac and hepatic toxicities. In this study, we synthesized polyethylene glycol-modified cationic liposomes to encapsulate ribavirin (RBV-PCL) and formulated it into a spray, aiming to enhance the effectiveness of RBV through respiratory administration. Lipopolysaccharide (LPS), a compound known to induce AP models in animals, was utilized in our research. Successfully, we established an acute pneumonia model in mice using aerosol inhalation. Through animal experiments, we investigated the therapeutic effects of RBV-PCL on mice with AP. In vivo studies revealed promising results. RBV-PCL effectively prolonged the survival of mice with AP, significantly reduced the levels of inflammatory markers such as interleukin-6 (IL-6) and tumor necrosis factor-α (TNF-α), and inhibited the infiltration of neutrophils in the lungs and spleens of mice. These findings suggest that RBV-PCL can effectively suppress the inflammatory response in mice with AP, thus holding significant potential as a novel therapeutic approach for the treatment of acute pneumonia. [ABSTRACT FROM AUTHOR]

The goal of the study was to compare the surface characteristics of typical implant materials used in orthopedic surgery and traumatology, as these determine their successful biointegration. The morphological and chemical structure of Vortex plate anodized titanium from commercially pure (CP) Grade 2 Titanium (Ti2) is generally used in the following; non-cemented total hip replacement (THR) stem and cup Ti alloy (Ti6Al4V) with titanium plasma spray (TPS) coating; cemented THR stem Stainless steel (SS); total knee replacement (TKR) femoral component CoCrMo alloy (CoCr); cemented acetabular component from highly cross-linked ultrahigh molecular weight polyethylene (HXL); and cementless acetabular liner from ultrahigh molecular weight polyethylene (UHMWPE) (Sanatmetal, Ltd., Eger, Hungary) discs, all of which were examined. Visualization and elemental analysis were carried out by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). Surface roughness was determined by atomic force microscopy (AFM) and profilometry. TPS Ti presented the highest Ra value (25 ± 2 μm), followed by CoCr (535 ± 19 nm), Ti2 (227 ± 15 nm) and SS (170 ± 11 nm). The roughness measured in the HXL and UHMWPE surfaces was in the same range, 147 ± 13 nm and 144 ± 15 nm, respectively. EDS confirmed typical elements regarding the investigated prosthesis materials. XPS results supported the EDS results and revealed a high % of Ti4+ on Ti2 and TPS surfaces. The results indicate that the surfaces of prosthesis materials have significantly different features, and a detailed characterization is needed to successfully apply them in orthopedic surgery and traumatology. [ABSTRACT FROM AUTHOR]

Polymer/polymer nanocomposites based on high-density polyethylene (HDPE) and biocompatible polyvinyl alcohol (PVA) were prepared by tensile drawing of HDPE in the PVA solutions via environmental crazing. The mechanism of this phenomenon was described. The HDPE/PVA nanocomposites were studied by the methods of scanning electron microscopy, atomic force microscopy, gravimetry, tensile tests, and their composition, properties, and performance were characterized. The content of PVA in the HDPE/PVA nanocomposites (up to 22 wt.%) was controlled by the tensile strain of HDPE and concentration of PVA in the solution. Depending on the content of PVA, the wettability of the HDPE/PVA nanocomposite (hydrophilic-lipophilic balance) could be varied in a broad interval from 45 to 98°. The modification of HDPE by the biocompatible PVA offers a beneficial avenue for practical applications of the HDPE/PVA composites as biomedical materials, packaging and protective materials, modern textile articles, breathable materials, membranes and sorbents, etc. [ABSTRACT FROM AUTHOR]

The blending of polyolefins (POs), such as polyethylene (PE) and polypropylene (PP), is a growing area of research, particularly for recycling mixed polyolefin (MPO) waste through flotation sorting techniques. However, understanding the thermomechanical behavior of these recycled blends is challenging due to limitations in the existing characterization methods. This paper introduces a combined experimental and numerical method to accurately assess the complex mechanical behavior of high-density PE, PP, and their blends. We conducted detailed thermomechanical analyses using a high-speed stereo digital image correlation (DIC) system paired with an infrared camera to capture temperature variations alongside mechanical stress and strain. This approach allowed us to correct for distortions caused by necking and to derive accurate stress–strain relationships. We also applied a cutting-edge unified semi-crystalline polymer (USCP) model to simplify the analysis, focusing on the effects of strain rate and temperature, including self-heating and thermal softening phenomena. Our results, which closely match experimental observations of stress–strain behavior and temperature changes, offer new insights into the thermomechanical properties of PO blends, which are essential for advancing their practical applications in various fields. [ABSTRACT FROM AUTHOR]

Due to the increasing demands for improved radiation safety and the growing concerns regarding the excessive use of plastics, this work aimed to develop effective and eco-friendly thermal-neutron-shielding materials based on recycled high-density polyethylene (r-HDPE) composites containing varying surface-treated gadolinium oxide (Gd2O3) contents (0, 5, 10, 15, and 20 wt%). The results indicate that the overall thermal-neutron-shielding properties of the r-HDPE composites were enhanced with the addition of Gd2O3, as evidenced by large reductions in I/I0, HVL, and TVL, as well as the substantial increases in ∑t and ∑t/ρ of the composites. Furthermore, the results reveal that the values for tensile properties initially increased up to 5–15 wt% of Gd2O3 and then gradually decreased at higher contents. In addition, the results show that the addition of Gd2O3 particles generally increased the density (ρ), the remaining ash at 600 °C, and the degree of crystallinity (%XC) of the composites. This work also determined the effects of gamma irradiation on relevant properties of the composites. The findings indicate that following gamma aging, the tensile modulus slightly increased, while the tensile strength, elongation at break, and hardness (Shore D) showed no significant (p < 0.05) differences, except for the sample containing 5 wt% of Gd2O3, which exhibited a noticeable reduction in elongation at break. Furthermore, by comparing the neutron-shielding and mechanical properties of the developed r-HDPE composites with common borated polyethylene (PE) containing 5 wt% and 15 wt% of boron, the results clearly indicate the superior shielding and tensile properties in the r-HDPE composites, implying the great potential of r-HDPE composites to replace virgin plastics as effective and more eco-friendly shielding materials. [ABSTRACT FROM AUTHOR]

A non-pneumatic tire (NPT) overcomes the shortcomings of a traditional pneumatic tire such as wear, punctures and blowouts. In this respect, it shows great potential in improving driving safety, and has received great attention in recent years. In this paper, a carbon fiber-reinforced polyethylene terephthalate (PET/CF) honeycomb is proposed as a support structure for NPTs, which can be easily prepared using 3D printing technology. The experimental results showed that the PET/CF has high strength and modulus and provides excellent mechanical properties. Then, a finite element (FE) model was established to predict the compression performance of auxetic honeycombs. Good agreement was achieved between the experimental data and FE analysis. The influence of the cell parameters on the compressive performance of the support structure were further analyzed. Both the wall thickness and the vertically inclined angle could modulate the mechanical performance of the NPT. Finally, the application of vertical force is used to analyze the static load of the structure. The PET/CF honeycomb as the support structure of the NPT showed outstanding bearing capacity and stiffness in contrast with elastomer counterparts. Consequently, this study broadens the material selection for NPTs and proposes a strategy for manufacturing a prototype, which provides a reference for the design and development of non-pneumatic tires. [ABSTRACT FROM AUTHOR]

Polymers generally form incompatible mixtures that make the process of recycling difficult, especially the mechanical recycling of mixed plastic waste. One of the most commonly used films in the packaging industry is multilayer films, mainly composed of polyethylene (PE) and polyamide (PA). Recycling these materials with such different molecular structures requires the use of compatibilizers to minimize phase separation and obtain more useful recycled materials. In this work, commercial polyisoprene–graft–maleic anhydride (PI-g-MA) was tested as a compatibilizer for a blend of PE and PA derived from the mechanical recycling of PE/PA multilayer films. Different amounts of PI-g-MA were tested, and the films made with 1.5% PI-g-MA showed the best results in terms of mechanical properties and dart impact. The films were also characterized thermally via thermogravimetric analysis (TG) and differential scanning calorimetry (DSC), using Fourier-transform infrared spectroscopy (FTIR), and morphologically using a scanning electron microscope (SEM). Other parameters, such as tearing and perforation, were analyzed. [ABSTRACT FROM AUTHOR]

Understanding and characterizing semi-crystalline models with crystalline and amorphous segments is crucial for industrial applications. A coarse-grained molecular dynamics (CGMD) simulations study probed the crystal network formation in high-density polyethylene (HDPE) from melt, and shed light on tensile properties for microstructure analysis. Modified Paul–Yoon–Smith (PYS/R) forcefield parameters are used to compute the interatomic forces among the PE chains. The isothermal crystallization at 300 K and 1 atm predicts the multi-nucleus crystal growth; moreover, the lamellar crystal stems and amorphous region are alternatively oriented. A one-dimensional density distribution along the alternative lamellar stems further confirms the ordering of the lamellar-stack orientation. Using this plastic model preparation approach, the semi-crystalline model density ( ρ c r ) of ca. 0.913 g·cm−3 and amorphous model density ( ρ a m ) of ca. 0.856 g·cm−3 are obtained. Furthermore, the ratio of ρ c r / ρ a m ≈ 1.06 is in good agreement with computational (≈1.096) and experimental (≈1.14) data, ensuring the reliability of the simulations. The degree of crystallinity ( χ c ) of the model is ca. 52% at 300 K. Nevertheless, there is a gradual increase in crystallinity over the specified time, indicating the alignment of the lamellar stems during crystallization. The characteristic stress–strain curve mimicking tensile tests along the z-axis orientation exhibits a reversible sharp elastic regime, tensile strength at yield ca. 100 MPa, and a non-reversible tensile strength at break of 350%. The cavitation mechanism embraces the alignment of lamellar stems along the deformation axis. The study highlights an explanatory model of crystal network formation for the PE model using a PYS/R forcefield, and it produces a microstructure with ordered lamellar and amorphous segments with robust mechanical properties, which aids in predicting the microstructure–mechanical property relationships in plastics under applied forces. [ABSTRACT FROM AUTHOR]

Though paper is an environmentally friendly alternative to plastic as a packaging material, it lacks antibacterial properties, and some papers have a low resistance to oil or water. In this study, a multifunctional paper-coating material was developed to reduce the use of plastic packaging and enhance paper performance. Natural cellulose nanocrystals (CNCs) with excellent properties were used as the base material for the coating. The CNCs were functionalized into dialdehyde CNCs (DACNCs) through periodate oxidation. The DACNCs were subsequently complexed using erythrosine as a photosensitizer to form an erythrosine–CNC composite (Ery-DACNCs) with photodynamic inactivation. The Ery-DACNCs achieved inactivations above 90% after 30 min of green light irradiation and above 85% after 60 min of white light irradiation (to simulate real-world lighting conditions), indicating photodynamic inactivation effects. The optimal parameters for a layer-by-layer dip coating of kraft paper with Ery-DACNCs were 4.5-wt% Ery-DACNCs and 15 coating layers. Compared to non-coated kraft paper and polyethylene-coated paper, the Ery-DACNC-coated paper exhibited enhanced mechanical properties (an increase of 28% in bursting strength). More than 90% of the bacteria were inactivated after 40 min of green light irradiation, and more than 80% were inactivated after 60 min of white light irradiation. [ABSTRACT FROM AUTHOR]

In accordance with the Circular Economy Package of the European directive, the Spanish government compels manufacturers of plastic bags to include into their products a minimum of 70% of polyethylene (PE) waste. Following this mandate can be challenging and requires a deep knowledge of the alterations produced by the recycling in the main components of a plastic bag film: lineal low-density polyethylene (LLDPE), the LLDPE recycled post-industry, generated as waste from an industrial process (rLLDPE) and the PE recycled from post-consumer use (rPE), that has been picked up, cleaned, and reprocessed. This study provides insight in the macro and microstructural changes produced by several cycles of recycling in these materials. Specimens in the form of film for supermarket bags formed with these polymers have been subjected to several recycling sequences. The process closely mimics industrial processes. Four cycles have been applied to the samples. The evolution of mechanical properties, including tensile strength, elongation at break, and tear and impact tests, shows an obvious decrease due to degradation that is not an impediment for practical use after the four cycles of recycling according to the main specifications defined by the producer. Colorimetric measurements reveal no significant variations in the color of the films. The results of the FTIR and TGA analysis show degradation phenomena and changes in crystallinity in branching and the apparition of crosslinking that are in consonance with the mechanical data. There is also a difference between both types of recycled PE. In general, rLLDPE is more affected by the recycling than rPE. According to our findings, the limiting property would be the tearing. By comparing these values with bags available in the market, manufactured from 70–80% recycled material, we can infer that while two reprocessing cycles can lead to good results, a maximum of four cycles of recycling is advisable. [ABSTRACT FROM AUTHOR]

Silica-supported chromium oxide catalysts, also named Phillips chromium catalysts (PCCs), provide more than half of the world's production of high- and medium-density polyethylenes. PCCs are usually prepared in the Cr(VI)/SiO2 form, which is subjected to reductive activation. It has been explicitly proven that CO reduces Cr(VI) to Cr(II) species that initiate ethylene polymerization; ethylene activates Cr(VI) sites as well, but the nature of the catalytic species is complicated by the presence of the ethylene oxidation products. It is widely accepted that the catalytic species are of a Cr(III)–alkyl nature, but this common assumption faces the challenge of "extra" hydrogen: the formation of similar species under the action of even-electron reducing agents requires an additional H atom. Relatively recently, it was found that saturated hydrocarbons can also activate CrOx/SiO2, and alkyl fragments turn out to be bonded with a polyethylene chain. In recent years, there have been numerous experimental and theoretical studies of the structure and chemistry of PCCs at the different stages of preparation and activation. The use of modern spectral methods (such as extended X-ray absorption fine structure (EXAFS), X-ray absorption near-edge structure (XANES), and others); operando IR, UV–vis, EPR, and XAS spectroscopies; and theoretical approaches (DFT modeling, machine learning) clarified many essential aspects of the mechanisms of CrOx/SiO2 activation and catalytic behavior. Overall, the Cosse–Arlman mechanism of polymerization on Cr(III)–alkyl centers is confirmed in many works, but its theoretical support required the development of nontrivial and contentious mechanistic concepts of Cr(VI)/SiO2 or Cr(II)/SiO2 activation. On the other hand, conflicting experimental data continue to be obtained, and certain mechanistic concepts are being developed with the use of outdated models. Strictly speaking, the main question of what type of catalytic species, Cr(II), Cr(III), or Cr(IV), comes into polymerization still has not received an unambiguous answer. The role of the chemical nature of the support—through the prism of the nature, geometry, and distribution of the active sites—is also not clear in depth. In the present review, we endeavored to summarize and discuss the recent studies in the field of the preparation, activation, and action of PCCs, with a focus on existing contradictions in the interpretation of the experimental and theoretical results. [ABSTRACT FROM AUTHOR]

To investigate the influence of the crosslinked polyethylene (XLPE) structure on electrical performance, various analytical methods were employed to study polyethylene structures with different degrees of crosslinking. Dynamic rheological analysis was conducted to determine material shear viscosity, dynamic viscosity, storage modulus (G′), loss modulus (G″), and other rheological parameters. Additionally, the electrical performance of the material was analyzed by studying the phenomenon of space charge accumulation under direct current voltage. The results indicate that with an increasing mass fraction of the crosslinking agent, the crosslink density of crosslinked polyethylene initially increases and then decreases. When the dicumyl peroxide (DCP) content exceeds 1.0 wt.%, there is an accumulation of like-polarity space charges. The best rheological processing performance of crosslinked polyethylene is observed when the DCP content is in the range of 1.0–1.5 wt.%. [ABSTRACT FROM AUTHOR]

This study provides insight into the causes of inferior long-term stability of nanocomposites based on organic layered silicates (OLSs) used for cable mantles. A hierarchy was established by analyzing bentonite products and their respective polyolefin nanocomposites. Thermogravimetric analysis (TGA), X-ray diffraction (XRD), gas adsorption, energy-dispersive spectroscopy (SEM-EDX), and infrared spectroscopy (IR) provided evidence for the adsorption of stabilizers onto the filler surface and thus their reduction in activity, promoting polymer oxidation. This behavior corresponds to the specific surface area of the incorporated OLS. Therefore, it can be stated that gas adsorption and XRD are especially useful for the evaluation of long-term photostability. It was revealed that photocatalytically active iron is of secondary importance since iron-rich bentonites still formed the most stable nanocomposite. This also applies to the Hofmann elimination products of the modifying agent, where higher contents do not accelerate the degradation process. No elimination products could be traced within the composites. Due to the polymer-filler interface being essential for long-term photostability, prior analysis of the filler surface properties can be used to estimate the stability of the respective nanocomposite as a rationale for product selection in the early stages of development. The reasons identified in this work for decreasing the long-term photostability of OLS nanocomposites compared with unfilled formulations is an important step toward increasing their stability. [ABSTRACT FROM AUTHOR]

The main objective of this study was to discover new packaging materials that could integrate one of the most expected properties, such as UV protection, with a self-cleaning ability defined as photocatalytic performance. Accordingly, new hybrid additives were used to transform LDPE films into materials with complex performance properties. In this study, titanium dioxide–lignin (TL) hybrid systems with a weight ratio of inorganic to organic precursors of 5-1, 1-1, and 1-5 were prepared using a mechanical method. The obtained materials and pristine components were characterized using measurement techniques and research methods, such as Fourier-transform infrared spectroscopy (FTIR), thermal stability analysis (TGA/DTG), measurement of the electrokinetic potential as a function of pH, scanning electron microscopy (SEM), and particle size distribution measurement. It was found that hydrogen bonds were formed between the organic and inorganic components, based on which the obtained systems were classified as class I hybrid materials. In the next step, inorganic–organic hybrid systems and pristine components were used as fillers for a low-density polyethylene (LDPE) composite, 5 and 10% by weight, in order to determine their impact on parameters such as tensile elongation at break. Polymer composites containing titanium dioxide in their matrix were then subjected to a test of photocatalytic properties, based on which it was found that all materials with TiO2 in their structure exhibit photocatalytic properties, whereby the best results were obtained for samples containing the TiO2–lignin hybrid system (1-1). The mechanical tests showed that the thin sheet films had a strong anisotropy due to chill-roll extrusion, ranging from 1.98 to 3.32. UV–Vis spectroscopy revealed four times higher light absorption for composites in which lignin was present than for pure LDPE, in the 250–450 nm range. On the other hand, the temperature at 5% and 30% weight loss revealed by TGA testing increased the highest performance for LDPE/TiO2 materials (by 20.4 °C and 8.7 °C, respectively). [ABSTRACT FROM AUTHOR]

In order to withstand high-temperature environments, ultra-high molecular weight polyethylene (UHMWPE) fibers with cooling properties are being increasingly used in personal thermal management textiles during the summer. However, there is relatively little research on its combination with knitting. In this paper, we combine UHMWPE fiber and knitting structure to investigate the impact of varying UHMWPE fiber content and different knitting structures on the heat and humidity comfort as well as the cooling properties of fabrics. For this purpose, five kinds of different proportions of UHMWPE and polyamide yarn preparation, as well as five kinds of knitted tissue structures based on woven tissue were designed to weave 25 knitted fabrics. The air permeability, moisture permeability, moisture absorption and humidity conduction, thermal property, and contact cool feeling property of the fabrics were tested. Then, orthogonal analysis and correlation analysis were used to statistically evaluate the properties of the fabrics statistically. The results show that as the UHMWPE content increases, the air permeability, heat conductivity, and contact cool feeling property of the fabrics improve. The moisture permeability, moisture absorption and humidity conductivity of fabrics containing UHMWPE are superior to those containing only polyamide. The air permeability, moisture permeability, and thermal conductivity of the fabrics formed by the tuck plating organization are superior to those of the flat needle plating and float wire plating organization. The fabric formed by 2 separate 2 float wire organization has the best moisture absorption, humidity conduction, contact cool feeling property. [ABSTRACT FROM AUTHOR]

The alteration of an ultraviolet light absorber (UVA: UV-326) in polymers (PP, HDPE, LDPE, PLA, and PS) over time during degradation was studied using an enhanced degradation method (EDM) involving sulfate ion radicals in seawater. The EDM was employed to homogeneously degrade the entire polymer samples containing the UVA. The PP and PS samples containing 5-phr (phr: per hundred resin) UVA films underwent rapid whitening, characterized by the formation of numerous grooves or crushed particles. Notably, the UVA loss rate in PS, with the higher glass transition temperature (Tg), was considerably slower. The behavior of crystalline polymers, with the exception of PS, was analogous in terms of the change in UVA loss rate over the course of degradation. The significant increase in the initial loss rate observed during EDM degradation was due to microplasticization. A similar increase in microplasticization rate occurred with PS; however, the intermolecular interaction between UVA and PS did not result in as pronounced an increase in loss rate as observed in other polymers. Importantly, the chemical structure of UVA remained unaltered during EDM degradation. These findings revealed that the primary cause of UVA loss was leaching from the polymer matrix. [ABSTRACT FROM AUTHOR]

With the increasing demand for high-end materials, trimodal polyethylene (PE) has become a research hotspot in recent years due to its superior performance compared with bimodal PE. By means of molecular dynamics (MD) simulations, we aim to expound the effect of the molecular weight distribution (MWD) on the mechanism of nucleation and crystallization of trimodal PE. The crystallization rate is faster when short-chain branching is distributed on a single backbone compared to that on two backbones. In addition, as the content of high molecular weight backbone decreases, the time required for nucleation decreases, but the crystallization rate slows down. This is because low molecular weight backbones undergo intra-chain nucleation and crystallize earlier due to the high diffusion capacity, which leads to entanglement that prevents the movement of medium or high molecular weight backbones. Furthermore, crystallized short backbones hinder the movement and crystallization of other backbones. What is more, a small increase in the high molecular weight branched backbone of trimodal PE can make the crystallinity greater than that of bimodal PE, but when the content of high molecular weight backbone is too high, the crystallinity decreases instead, because the contribution of short and medium backbones to high crystallinity is greater than that of long backbones. [ABSTRACT FROM AUTHOR]

Considering the sustainability of material development, coordination polymerization catalysts effective for 1,1-disubstituted olefins are receiving a great deal of attention because they can introduce a variety of plant-derived comonomers, such as β-pinene and limonene, into polyolefins. However, due to their sterically encumbered property, incorporating these monomers is difficult. Herein, we succeeded in the copolymerization of ethylene with various hydroxy- or siloxy-substituted vinylidenes using a fluorenylamido-ligated titanium catalyst–MMAO system. This is the first example of ethylene/polar 1,1-disubstituted olefins' copolymerization using an early transition metal catalyst system. The polymerization proceeded at room temperature without pressurizing ethylene, and high-molecular-weight, functionalized polyethylene was obtained. The obtained copolymer showed a reduced water contact angle compared with that of the ethylene/isobutene copolymer, demonstrating the increment in hydrophilicity by hydroxy groups. [ABSTRACT FROM AUTHOR]

To investigate the effect of the structure of microcapsules on the properties of cross-linked polyethylene (XLPE) composites, three XLPE specimens filled with multilayered shell–core-structured microcapsules are designed. In this paper, the microcapsules are first analyzed morphologically and chemically. In addition, the effect of the microcapsule structure on the typical electrical properties of the composites is explored. Finally, the self-healing ability of XLPE specimens filled with microcapsules is verified. The results show that the SiO2 on the surface of the trilayer shell–core microcapsules can make the microcapsules and the XLPE matrix have a better mechanical interlocking ability, which makes the typical properties of the trilayer shell–core microcapsules slightly better than those of the bilayer shell–core microcapsules. Moreover, when the bilayer shell–core or trilayer shell–core microcapsules rupture under the action of an electric field, the repair material reacts with the water tree under capillary action to consume the residual water while generating organic matter to fill in the cavity, thus repairing the damaged area of the water tree and ultimately achieving the self-healing of the composite water tree. [ABSTRACT FROM AUTHOR]

In this paper, a new multifunctional compound, 1,1′-(oxalylbis(4,1-phenylene))bis(1H-pyrrole-2,5-dione) (BVM), is grafted onto crosslinked polyethylene (XLPE) by radical-initiated grafting to play triple roles as a voltage stabilizer, space-charge inhibitor and crosslinking auxiliary and to achieve the purpose of comprehensively enhancing the DC dielectric properties of polymers while decreasing the type and number of additives. By analyzing the DC breakdown field strength, current density and space-charge distribution of the materials at different temperatures, it is demonstrated that BVM grafting can comprehensively and effectively enhance the electrical properties of the materials, with little dependence on temperature. The BVM molecule has two polar groups and an effective molecular structure that acts as a voltage stabilizer, thus enabling the introduction of dense, uniform, deeply trapped energy levels within the material to inhibit the space charge and to capture high-energy electrons to prevent damage to the material structure; however, the two functions do not affect each other. This is also consistent with first-principles calculations and quantum-chemical calculations. Gel content testing shows no effect on polymer crosslinking, even with a 27.8% reduction in the amount of the crosslinking agent di-isopropyl peroxide (DCP), which reduces the damage to the polymer's electrical resistance caused by the byproducts of DCP decomposition. Therefore, grafting multifunctional BVM compounds to improve the dielectric characteristics of polymers is a viable area of study in the development of high-voltage direct current (HVDC) cable materials. [ABSTRACT FROM AUTHOR]

Polypropylene-based multiphase compositions with a disperse elastomer phase provide superior impact strength. Making this property indifferent to processing steps requires stabilization of the morphology of these materials. Various approaches have been tested over time, each of which shows limitations in terms of performance or applicability. Using polyethylene (PE) homo- and copolymers capable of silane-based crosslinking as modifiers was explored in the present study, which allows decoupling of the mixing and crosslinking processes. Commercial silane-copolymerized low-density PE (LD-PEX) from a high-pressure process and silane-grafted high-density PE (HD-PEX) were studied as impact modifiers for different types of PP copolymers, including non-modified reference PE grades, LDPE and HDPE. Blends based on ethylene–propylene random copolymers (PPR) and based on impact- (PPI) and random-impact (PPRI) copolymers show improvements of the stiffness–impact balance; however, to different degrees. While the absolute softest and most ductile compositions are achieved with the already soft PPRI copolymer base, the strongest relative effects are found for the PPR based blends. Modifiers with lower density are clearly superior in the toughening effect, with the LD-PEX including acrylate as second comonomer sticking out due to its glass transition around −40 °C. The impact strength improvement found in most compositions (except at very high content) results, however, not from the expected phase stabilization. For comparable systems, particle sizes are normally higher with crosslinking, probably because the process already starts during mixing. Thermoplastic processability could be retained in all cases, but the drop in melt flow rate limits the practical applicability of such systems. [ABSTRACT FROM AUTHOR]

Available literature on the aging of plasma-activated polyethylene due to hydrophobic recovery has been reviewed and critically assessed. A common method for the evaluation of hydrophobic recovery is the determination of the static water contact angle, while the surface free energy does not reveal significant correlations. Surface-sensitive methods for the characterization of chemical composition and structure have limited applicability in studying the aging phenomenon. Aging is driven by thermodynamics, so it is observed even upon storage in a vacuum, and hydrophobic recovery increases with increasing temperature. Storage of plasma-activated polyethylene in the air at ambient conditions follows almost logarithmic behavior during the period studied by most authors; i.e., up to one month. The influence of the storage medium is somehow controversial because some authors reported aging suppression by storing in polar liquids, but others reported the loss of hydrophilicity even after a brief immersion into distilled water. Methods for suppressing aging by hydrophobic recovery include plasma treatment at elevated temperature followed by brief treatment at room temperature and application of energetic ions and photons in the vacuum ultraviolet range. Storing at low temperatures is a trivial alternative, but not very practical. The aging of plasma-activated polyethylene suppresses the adhesion of many coatings, but the correlation between the surface free energy and the adhesion force has yet to be addressed adequately. [ABSTRACT FROM AUTHOR]

Injection-molded polyethylene plates exhibit highly anisotropic mechanical behavior due to, e.g., the uneven orientation of the polymer chains during the molding process and the differential cooling, especially in the thickness direction. Elastoplastic finite element modeling of these plates in particular is used with isotropic yield criteria like von Mises, trading off accuracy in favor of simpler constitutive characterization and faster solution. This article studies three different anisotropic yield criteria, namely, Hill 1948, Barlat Yld91, and Barlat Yld2004-18P, for the finite element modeling of low-density polyethylene (LDPE) at large uniaxial tensile deformation and compares the accuracy and computation time with von Mises. A simplified calibration technique is investigated to identify the constitutive parameters of the studied Barlat group yield criteria. The calibration process is simplified in the sense that only uniaxial tensile tests with digital image correlation measurements are used for the calibration of all the yield criteria studied in this article, although a standard calibration procedure for the Barlat group yield criteria requires additional material testing using more demanding test setups. It is concluded that both Barlat Yld91 and Barlat Yld2004-18P yield criteria can be calibrated with only a few tensile tests and still capture anisotropy in deformation–stress–strain at different levels of accuracy. [ABSTRACT FROM AUTHOR]

At present, the challenging issue of the compatibility between stab resistance and flexibility of materials frequently appears. Thus, this study proposes a novel method to enhance the comprehensive performance of the material matrix with stab resistance. Based on the stab-resistant mechanism analysis of the textile matrix, the influence of four factors on the performance of ultra-high molecular weight polyethylene (UHMWPE) knitted fabric was discussed. And, the optimal process conditions of material for achieving high stab resistance and high flexibility were obtained by the response surface method. A series of experiments proved that among all factors, the fabric structure had the greatest influence on the flexible stab-resistant knitted material. Following that, the thickness of the yarn also plays a significant role. Under the optimal process conditions, the stab peak force of the knitted material was promoted to 52.450 N, and the flexibility was enhanced to 93.6%. Meanwhile, through comparison with products that have undergone the same treatment, there was little difference in stab resistance but significantly improved flexibility. It achieves the initial stab resistance and comfortable wearing softness of the fabric through process optimization. This improvement in overall performance of the textile matrix enables further enhancement treatments. [ABSTRACT FROM AUTHOR]

A twin-screw extruder was used to fabricate poly(butylene succinate) (PBS)/high-density polyethylene (HDPE) blends (7:3 weight ratio) and blend-based nanocomposites. Carbon nanotubes (CNTs), graphene nanoplatelets (GNPs), and organoclays (15A and 30B) served as the nanofiller, while maleated HDPE (PEgMA) acted as an efficient compatibilizer for the blend. In the composites, individual nanofillers were mostly localized in HDPE domains, but some fillers were also observed at PBS–HDPE interfaces. The sea–island morphology of the compatibilized blend evolved into a pseudo-co-continuous morphology in the composites. Differential scanning calorimetry results confirmed that PEgMA with HDPE evidently accelerated the crystallization of PBS in the blend. The possible nucleation effect of added fillers on PBS crystallization was obscured by the formation of quasi-connected HDPE domains, causing fewer PBS nucleation sites. The presence of nanofillers improved the thermal stability and burning anti-dripping behavior of the parent blend. The anti-dripping efficiency of added fillers followed the sequence CNT > 15A > 30B > GNP. The rigidity of the blend was increased after the formation of nanocomposites. In particular, adding GNP resulted in 19% and 31% increases in the Young's modulus and flexural modulus, respectively. The development of a pseudo-network structure in the composites was confirmed by measurement of rheological properties. The electrical resistivity of the blend was reduced by more than six orders of magnitude at 3 phr CNT loading, demonstrating the achievement of double percolation morphology. [ABSTRACT FROM AUTHOR]

Nanocomposite doping is an effective method to improve the dielectric properties of polyethylene. Meanwhile, the introduction of thermal conductivity groups in crosslinked polyethylene (XLPE) is also an effective way to improve the thermal conductivity. Nano-zeolite is an inorganic material with a porous structure that can be doped into polyethylene to improve the insulation performance. In this paper, hyperbranched polyarylamide (HBP) with a high thermal conductivity and an auxiliary crosslinking agent (TAIC) was grafted on the surface of ZSM-5 nano-zeolite successively to obtain functionalized nano-zeolite (TAICS-ZSM-5-HBP) (the "S" in TAICS means plural). The prepared functionalized nano-zeolite was doped in polyethylene and grafted under a thermal crosslinking reaction to prepare nanocomposites (XLPE/TAICS-ZSM-5-HBP). The structural characterization showed that the nanocomposite was successfully prepared and that the nanoparticles were uniformly dispersed in the polyethylene matrix. The space charge of the TAICS-ZSM-5-HBP 5wt% nanocomposite under a high electric field was obviously inhibited. The space charge short-circuit test showed that the porous structure of the nano-zeolite introduced more deep traps, which made the trapped charge difficult to break off, hindering the charge injection. The introduction of TAICS-ZSM-5-HBP particles can greatly improve the thermal conductivity of nanocomposites. The thermal conductivity of the XLPE/5wt% and XLPE/7wt% TAICS-ZSM-5-HBP nanocomposites increased by 42.21% and 69.59% compared to that of XLPE at 20 °C, and by 34.27% and 62.83% at 80 °C. [ABSTRACT FROM AUTHOR]

Coil–rod copolymers with a dendritic polyethylene (DPE) core and multiple helical poly(γ-benzyl-L-glutamate) (PBLG) arms (DPE-(PBLG)n) were prepared by palladium-catalyzed copolymerization in tandem with ring-opening polymerization (ROP). Macroinitiator (DPE–(NH2)11) was firstly prepared by the group transformation of DPE–(OH)11 generated from palladium-catalyzed copolymerization of ethylene and acrylate comonomer. Coil–helical DPE-(PBLG)11 copolymers were prepared by ROP of γ-benzyl-L-glutamate-N-carboxyanhydride (BLG-NCA). These DPE-(PBLG)11 copolymers could form thermoreversible gels in toluene solvent, and the dendritic topology of the DPE core increased the critical gelation concentrations. The self-assembled nanostructure of gels was fully characterized by transmission electron microscopy (TEM), atomic force microscopy (AFM), small-angle X-ray scattering (SAXS), and wide-angle X-ray diffraction (WAXD), and the morphology of the fibrous structure was a twisted flat ribbon through a self-assembled nanoribbon mechanism. The self-assembled fibers formed by DPE-(PBLG45)11 are more heterogeneous and ramified than previously observed fibers formed by PBLG homopolymer and block copolymers. [ABSTRACT FROM AUTHOR]

In this review, we summarize and discuss our experimental data published in a number of papers on the transfer reactions of polymer chains in the polymerization of ethylene, propylene, and hexene-1, and the copolymerization of ethylene with α-olefins over multisite supported titanium–magnesium catalysts (TMC). Three groups of transfer reactions are discussed in the review: (1) transfer reactions with AlEt3 cocatalyst, (2) transfer reactions with hydrogen, and (3) transfer reactions with participation of α-olefins in the case of ethylene copolymerization with α-olefins. We have found polymerization conditions where it is possible to observe heterogeneity of active sites of TMC for all three groups of the indicated reactions. It is shown that (1) the transfer reaction with AlEt3 proceeds with higher reactivity on the active sites that produce polymers with low molecular weight; (2) the transfer reaction with hydrogen, in the case of α-olefin polymerization and copolymerization of ethylene with α-olefins, proceeds with higher reactivity on the active sites which produce polymers with high molecular weight; (3) the transfer reaction with α-olefins proceed with higher reactivity on the active sites that produce high molecular weight polymers. [ABSTRACT FROM AUTHOR]

Semicrystalline polymers are lightweight, multiphase materials that exhibit attractive shock dissipation characteristics and have potential applications as protective armor for people and equipment. For shocks of 10 GPa or less, we analyzed various mechanisms for the storage and dissipation of shock wave energy in a realistic, united atom (UA) model of semicrystalline polyethylene. Systems characterized by different levels of crystallinity were simulated using equilibrium molecular dynamics with a Hugoniostat to ensure that the resulting states conform to the Rankine–Hugoniot conditions. To determine the role of structural rearrangements, order parameters and configuration time series were collected during the course of the shock simulations. We conclude that the major mechanisms responsible for the storage and dissipation of shock energy in semicrystalline polyethylene are those associated with plastic deformation and melting of the crystalline domain. For this UA model, plastic deformation occurs primarily through fine crystallographic slip and the formation of kink bands, whose long period decreases with increasing shock pressure. [ABSTRACT FROM AUTHOR]

The novel ultra-high molecular weight polypropylene (UHMWPP) as a dispersed component was melt blended with conventional high-density polyethylene (PE) and maleic anhydride grafted-polyethylene (mPE) in different proportions through a kneader. Ultra-high molecular weight polypropylene is a high-performance polymer material that has excellent mechanical properties and toughness compared to other polymers. Mechanical, thermal, and rheological properties were presented for various UHMWPP loadings, and correlations between mechanical and rheological properties were examined. Optimal comprehensive mechanical properties are achieved when the UHMWPP content reaches approximately 50 wt%, although the elongation properties do not match those of pure PE or mPE. However, it is worth noting that the elongation properties of these blends did not match those of PE or mPE. Particularly, for the PE/UHMWPP blends, a significant drop in tensile strength was observed as the UHMWPP content decreased (from 30.24 MPa for P50U50 to 13.12 MPa for P90U10). In contrast, the mPE/UHMWPP blends demonstrated only minimal changes in tensile strength (ranging from 29 MPa for mP50U50 to 24.64 MPa for mP90U10) as UHMWPP content varied. The storage modulus of the PE/UHMWPP blends increased drastically with the UHMWPP content due to the UHMWPP chain entanglements and rigidity. Additionally, we noted a substantial reduction in the melt index of the blend system when the UHMWPP content exceeded 10% by weight. [ABSTRACT FROM AUTHOR]

This paper provides evidence and discusses the variability in the thermomechanical behaviour of virgin and recycled polypropylene/high-density polyethylene blends without the addition of other components, which is sparse in the literature. Understanding the performance variability in recycled polymer blends is of critical importance in order to facilitate the re-entering of recycled materials to the consumer market and, thus, contribute towards a circular economy. This is an area that requires further research due to the inhomogeneity of recycled materials. Therefore, the thermal and mechanical properties of virgin and recycled polypropylene/high-density polyethylene blends were investigated systematically. Differential scanning calorimetry concludes that both the recycled and virgin blends are immiscible. Generally, recycled blends have lower overall crystallinity and melting temperatures compared with virgin blends while, remarkably, their crystallisation temperatures are compared favourably. Dynamical mechanical analysis showed little variation in the storage modulus of recycled and virgin blends. However, the alpha and beta relaxation temperatures are lower in recycled blends due to structural deterioration. Deterioration in the thermal and mechanical properties of recycled blends is thought to be caused by the presence of contaminants and structural degradation during reprocessing, resulting in shorter polymeric chains and the formation of imperfect crystallites. The tensile properties of recycled blends are also affected by the recycling process. The Young's modulus and yield strength of the recycled blends are inferior to those of virgin blends due to the deterioration during the recycling process. However, the elongation at break of the recycled blends is higher compared with the virgin blends, possibly due to the plasticity effect of the low-molecular-weight chain fragments. [ABSTRACT FROM AUTHOR]

3D printing of polyolefins, such as polyethylene (PE) and polypropylene (PP), is of great practical interest due to the combination of high properties of these materials. However, the use of these materials in 3D printing is associated with many problems due to their high rate of crystallization, which causes shrinkage and warpage of the printed object. In this regard, blends of PE and ethylene-vinyl acetate copolymer (EVA) of various compositions were investigated for 3D printing. It was found that with an increase in the concentration of EVA, an increase in the pseudoplastic effect and amorphization of PE occurs. It has been shown that with an increase in the EVA content, the degree of crystallinity of PE decreases slightly (by 11% at a content of 80% EVA); however, a significant decrease in the rate of crystallization of PE is observed (by 87.5% at the same EVA concentration). It was found that PE and EVA are completely compatible in the amorphous phase and partially compatible in the crystalline phase, which leads to a slight decrease in the melting point of PE. The introduction of EVA also leads to a significant increase in impact strength: the maximum value is achieved at a 50/50 ratio, which is five times the value of the initial PE and two times the value of the initial EVA. At the same time, it was revealed that EVA leads to a gradual decrease in the elastic modulus and strength of PE, the change of which generally obeys the additivity rule. The resulting printing filaments are characterized by a certain ovality due to their shrinkage, which decreases with increasing EVA content and reaches a minimum value at a PE/EVA ratio of 30/70. This composition also demonstrates the lowest shrinkage of the printed sample and higher processability during printing. [ABSTRACT FROM AUTHOR]

Effective insulation of buildings and other industrial objects requires the use of materials and system solutions that ensure maximum uniformity and density of insulation shells. The study focuses on the development of insulation systems based on expanded polyethylene and, in particular, on the development of modified polyethylene with reduced flammability containing a flame-retardant modified montmorillonite clay, which does not hinder gas formation, and silicate nanofillers in layered construction. Active experiments based on mathematical design methods allowed us to establish an analytical relationship between flame-retardant and modifier consumption and extruder pressure and response functions: average density of polyethylene foam and flammability criterion. The flammability criterion was taken as the oxygen index of the modified polyethylene foam. A foaming agent masterbatch was used as the flame retardant. Analytical optimization of mathematical models obtained as a result of active experiments allowed us to determine the optimal flame-retardant consumption, which was 3.7–3.8% of the polymer mass. Optimised systems for average density and oxygen index of flammability of modified polyethylene were obtained. A nomogram for predicting the material properties and selecting the composition, and an algorithm for a computer program for evaluating the properties of modified polyethylene foam as a function of the values of various factors, were developed. Taking into account the possible expansion of the scope of application of rolled polyethylene foam and seamless insulation shells based on it, possible solutions for insulation systems were studied using the program THERM, and a combined insulation system was adopted. [ABSTRACT FROM AUTHOR]

Collecting energy from the ambient environment through green and sustainable methods is highly expected to alleviate pollution and energy problems worldwide. Here, we report a facile and flexible hydrovoltaic generator capable of utilizing natural water evaporation for sustainable electricity production. The generator was fabricated by coating nano-Al2O3 on a twistable polyethylene terephthalate film. An open circuit voltage of 1.7 V was obtained on a piece of centimeter-sized hydrovoltaic generator under ambient conditions. The supercapacitor charged by the hydrovoltaic device can power a mini-motor efficiently. Moreover, by expanding the size or connecting it in series/parallel, the energy output of the generator can be further improved. Finally, the influence factors and the mechanism for power generation were primarily investigated. Electrical energy is produced by the migration of water through charged capillary channels. The environmental conditions, the properties of the solution and the morphology of the film have important effects on the electrical performance. This study is anticipated to offer enlightenment into designing novel hydrovoltaic devices, providing diverse energy sources for various self-powered devices and systems. [ABSTRACT FROM AUTHOR]

The addition of toxic flame retardants to commercially available polymers is often required for safety reasons due to the high flammability of these materials. In this work, the preparation and incorporation of efficient biodegradable starch-based flame retardants into a low-density polyethylene (LDPE) matrix was investigated. Thermoplastic starch was first obtained by plasticizing starch with glycerol/water or glycerol/water/choline phytate to obtain TPS-G and TPS-G-CPA, respectively. Various LDPE/TPS blends were prepared by means of melt blending using polyethylene graft maleic anhydride as a compatibilizer and by varying the content of TPS and a halogenated commercial flame retardant. By replacing 38% and 76% of the harmful commercial flame retardant with safe TPS-G-CPA and TPS-G, respectively, blends with promising fire behavior were obtained, while the limiting oxygen index (LOI ≈ 28%) remained the same. The presence of choline phytate improved both the charring ability and fire retardancy of starch and resulted in a 43% reduction in fire growth index compared to the blend with commercial flame retardant only, as confirmed by means of cone calorimetry. Standard UL 94 vertical tests showed that blends containing TPS exhibited dripping behavior (rated V2), while those with commercial flame retardant were rated V0. Overall, this work demonstrates the potential of starch as a natural flame retardant that could reduce the cost and increase the safety of polymer-based materials. [ABSTRACT FROM AUTHOR]

Polyethylene (PE) is widely used as a gas-sealing material in packing films and gas transport pipes. A technique for evaluating the permeability of water-insoluble gases has recently been developed. This technique is a volumetric analysis that is used to calculate the gas permeability by measuring the gas uptake and diffusivity. With this technique, we investigated the permeability of pure gases, such as H2, He, N2, O2 and Ar, enriched under high pressure up to 9 MPa in low-density polyethylene (LDPE), ultrahigh molecular weight polyethylene (UHMWPE) and high-density polyethylene (HDPE). The gas uptake showed a linear pressure-dependent behavior that followed Henry's law, and the diffusivity was independent of the pressure. Furthermore, the logarithmic diffusivity values of the five gases linearly decreased as their molecular kinetic diameters increased. The logarithmic solubility values linearly increased as the critical temperatures of the gases increased. The calculated permeability results were correlated with the volume fraction of the amorphous phase and the fractional free volume. This result newly showed that the amorphous phase was directly correlated to the fractional free volume. [ABSTRACT FROM AUTHOR]

Composite materials based on NiFe2O4 nanoparticles and polyethylene matrix have been synthesized by thermal decomposition to expand the application area of high-pressure polyethylene by filling it with nanoscale particles. The synthesized compositions were obtained in the form of a dark gray powder and compressed for further study According to TEM, the average particle size in composites was 2, 3, and 4 nm in samples with a filling of 10%, 20% and 30%. The concentration dependences of the specific electrical resistivity ρV, dielectric permittivity ε, saturation magnetization MS and the parameters of reflection and attenuation of microwave power of the obtained composites were investigated. The threshold for percolation in such materials is found to be within a concentration range of 20...30%. The electronic and atomic structure of composites was studied by methods of Mössbauer spectroscopy, X-ray diffraction and X-ray absorption spectroscopy. The closest atomic environment of nickel and iron in nanoparticles is close to that of crystalline NiFe2O4. The dependence of the nanoparticles size as well as the dependence of the number of tetrahedral or octahedral iron positions in nickel ferrite nanoparticles to their content in polyethylene matrix is established. It is shown that composite materials based on NiFe2O4 nanoparticles and polyethylene matrix can be used as components of electromagnetic compatibility systems. [ABSTRACT FROM AUTHOR]

During an overload fault in an energized wire, the hot metal core modifies the structure of the insulation material. Therefore, understanding the thermal decomposition kinetics of the insulation materials of the overloaded wire is essential for fire prevention and control. This study investigates the thermal decomposition process of new and overloaded cross-linked polyethylene (XLPE) copper wires using thermogravimetry–Fourier-transform infrared spectroscopy and cone calorimetry. The thermal decomposition onset temperature and activation energy of the overloaded XLPE insulation materials were reduced by approximately 15 K and 20 kJ mol−1, respectively, and its reaction mechanism function changed from D-ZLT3 to A2 (0 < α < 0.5). The FTIR shows that the major spectral components produced during the pyrolysis of the XLPE insulation material are C-H stretching, H2O, CO2, C-H scissor vibrations, and C=O and C=C stretching. Additionally, the four functional groups in the PE chains produced the spectral components in the following decreasing order of wavenumber: C–H stretching > CO2 > C–H scissor vibration > C=O and C=C stretching. [ABSTRACT FROM AUTHOR]

Polyolefins play a role in industries and are typically manufactured using two types of reactors: high-pressure tubular reactors and fluidized bed reactors. An innovative technology called the Multizone Circulating reactor (MZCR) has emerged, which introduces an innovative approach with interconnected polymerization zones creating a continuous loop of polymer flow. This study focuses on modeling and simulating ethylene gas phase polymerization within the MZCR in the presence of internal cooling to gain insights into its behavior. To achieve this, a comprehensive computational fluid dynamics (CFD) simulation was developed. It considered momentum, material, and energy balance aspects. The model equations were solved using the finite difference method in COMSOL Multiphysics version 6.1. The investigation primarily focused on studying the impact of incorporating a cooler into the riser section on the temperature profile within the reactor and ethylene conversion. The presence of this cooler resulted in a reduction in temperature change along the riser from approximately 8.0 °C to 4.0 °C. Moreover, it led to an increase of 7%, in ethylene single-pass conversion. [ABSTRACT FROM AUTHOR]