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Fiber-reinforced composites are commonly exposed to environments associated with moisture and solution, resulting in uptake, which causes changes in the bulk resin, the fiber–matrix interface, and even the fiber itself. Knowledge about uptake behavior and diffusion mechanisms and characteristics are critical to better understanding the response of these materials to environmental exposure faced through service to developing better materials through selection of constituents and to the prediction of long-term durability. This paper reviews aspects of uptake mechanisms and subsequent response, as well as models that describe the sorption process, with the aim of providing a comprehensive understanding of moisture-uptake-related phenomena and characteristics such as uptake rate, diffusion and relaxation/deterioration constants, transitions in regimes, and overall response.

The aim of this study was to investigate the tribological characteristics of commercially available high-strength polyphthalamide-based composites with great contents (30–50 wt.%) of both carbon and glass fibers in point and linear contacts against metal and ceramic counterfaces under dry friction and oil-lubricated conditions at various loads and sliding speeds. The lengths of both types of fibers were varied simultaneously with their contents while samples were fabricated from granules by injection molding. When loading PPA with 30 wt.% SCFs at an aspect ratio (AR) of 200, the ultimate tensile strength and the elastic modulus increased up to 142.7 ± 12.5 MPa and 12.9 ± 0.6 GPa, respectively. In the composites with the higher contents of reinforcing fibers PPA/40CCF and AR~1000, the ultimate tensile strength and the elastic modulus were 240 ± 3 MPa and 33.7 ± 1.9 GPa, respectively. Under the applied test conditions, a composite reinforced with 40 wt.% carbon fibers up to 100 μm long at an aspect ratio of ~1000 possessed the best both mechanical properties and tribological characteristics. One of the reasons that should be considered for improving the tribological characteristics of the composite is the fatigue wear mechanism, which is facilitated by the high filling degree, the strong interfacial adhesion, and the great aspect ratio for fibers. Under the oil-lubricated conditions, both friction coefficients and wear rates decreased, so such friction units could be implemented whenever possible. The reported data can be used as practical recommendations for applying fibrous polyphthalamide-based composites as friction unit components.

FDM (Fused Deposition Modeling) is one of the most used and industrially applied additive manufacturing processes due to its fast prototyping and manufacturing, simplicity, and low cost of the equipment. However, the mechanical properties of the printed products have a large dependence on orientation and interface strength between layers which is mainly related to the thermal union obtained. This thermal union has a large dependence on the melting and cooling down process. Additionally, the materials used must be extruded in a continuous filament before their use, which limits the materials used. However, a pellet extruder could be used directly in the printing equipment, avoiding filament extrusion. In this work, specimens of PLA (Poly(lactic acid)) with different bead orientations have been produced via filament or pellet extrusion to compare the effect of the different melting processes in the manufacturing methodology. Pellet extruded specimens showed higher infill and mechanical properties. These results were related to better adhesion between layers due to the longer melting and cooling process. The result was confirmed using DSC and XRD techniques, where a higher crystallinity was observed. A bicomponent specimen (50% pellet–50% filament) was prepared and tested, showing higher mechanical results than expected, which was, again, due to the better thermal union obtained in the pellet extruder.

In this study, a thermomechanical model is developed to simulate a finite drilling set of Carbon Fibre Reinforced Polymers (CFRP)/Titanium (Ti) hybrid structures widely known for their energy saving performance. The model applies different heat fluxes at the trim plane of the two phases of the composite, owing to cutting forces, in order to simulate the temperature evolution at the workpiece during the cutting step. A user-defined subroutine VDFLUX was implemented to address the temperature-coupled displacement approach. A user-material subroutine VUMAT was developed to describe Hashin damage-coupled elasticity model for the CFRP phase while Johnson–Cook damage criteria was considered for describing the behavior of titanium phase. The two subroutines coordinate to evaluate sensitively the heat effects at the CFRP/Ti interface and within the subsurface of the structure at each increment. The proposed model has been first calibrated based on tensile standard tests. The material removal process was then investigated versus cutting conditions. Predictions show discontinuity in temperature field at interface that should further favor damage to localize especially at CFRP phase. The obtained results highlight the significant effects of fibre orientation in dominating cutting temperature and thermal effects over the whole hybrid structure.

A systematic study was performed to provide better understanding of the effect of elastomeric materials on the behavior of polycarbonate blends (PC). Thus, blends of PC with different amounts of elastomers, such as copolyether ester elastomer (COPE), acrylonitrile–butadiene–styrene (ABS), maleic anhydride-grafted ABS (ABS-g-MA), and styrene–ethylene–butylene–styrene (SEBS-g-MA) were prepared in a co-rotating twin-screw extruder. The materials were characterized by an electronic microscopy (SEM), an infrared spectroscopy (FTIR), and thermal (DSC) and thermo-mechanical (DMA) techniques. The incorporation of elastomeric phases was observed by changes in the FTIR band’s intensity, whereas a new shoulder of the ester band of COPE at 1728 cm−1 indicates the occurrence of a transesterification reaction. Unmodified and modified ABS (5% and 10%) did not affect the glass transition temperature (Tg) of PC, while 1% SEBS-g-MA slightly increased this value. PC/10% COPE showed that a decrease in Tg of 25 °C has a result of better compatibilization between both phases, which is visible via SEM. SEM analysis identified three main toughening mechanisms, depending on the type of elastomer. Unlike any other study, this work deepens the knowledge, in a comparative way, to understand the elastomeric effect at the interface and consequently, on the mechanical behavior of PC systems.

The aim of this work is to analyze the difference between silicone/composite and silicone/metal interphases, both in terms of water diffusion behavior and failure of the aged joints. For that, silicone joints with two different suhbstrates were prepared. The substrates were polybutylene terephthalate with 30% of short glass fiber (PBT-GF30) and 6082-T6 aluminum. It is assumed that the water uptake of the joints is equal to the water uptake of the substrate, adhesive, and interphase. Therefore, knowing the first three, the last could be isolated. To study the water diffusion behavior of the complete joint, rectangular joints were prepared, immersed in water and their water uptake was measured. The water immersion was conducted at 70 °C. It was concluded that the aluminum/silicone joints absorbed more water through the interphase region than the PBT-GF30/silicone joints, since the difference between the expected water uptake and the experimentally measured mass gain is significantly higher, causing adhesive failure of the joint. The same was not observed in the PBT-GF30/silicone, with a more stable interphase, that does not absorb measurable quantities of water and always exhibits cohesive failure.

Composites from polypropylene (PP) reinforced with hemp strands (HS) are prepared in the current work with the aim of deepening on the influence of this reinforcement on the impact performance of these specific composites. Despite all the research conducted in this field, the effect of this natural reinforcement on the absorbed energy during crack formation and propagation is not fully tackled in previous research works. From the methodology and samples’ geometry, the results concluded that the quality of the interface has a noticeable role in the impact resistance of these materials. The interface strength, fiber dispersion and fiber pullout are the main contributors to crack formation, whereas fiber pullout is the main one responsible for crack propagation. Maximum values of absorbed energy were found for PP composites comprising 20–30 wt% of HS and 8 wt% of the coupling agent for the un-notched samples, whereas maximum absorbed energy values corresponded to PP composites with 40 wt% of HS and 4 wt% of coupling agent for the notched samples. The water-absorption behavior in different humid environments is also examined. From the kinetic study, the water diffusion followed a Fickean behavior showing low-diffusion coefficients, increasing with fiber content. This systematic investigation represents a contribution to the analysis of the potential of reinforcing conventional polymers with natural materials, as a strategy towards more sustainable development.

Natural fibers-reinforced polymer composites have progressed rapidly due to their undeniable advantages. Most of the commercial polypropylene (PP)-based materials are characterized by either high impact toughness or high stiffness, while the manufacture of PP composites with both good toughness and stiffness is challenging at present. In this work, poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS) and poly(styrene-b-butadiene-b-styrene) (SBS) copolymers were used in different amounts as modifiers in PP/hemp fibers (HF) composites, with the aim to use them for electrical vehicle parts. The interface in these multiphase systems was controlled by the addition of maleated polypropylene (MAPP). SEBS and SBS showed different effects on the elongation at break of the blends and the corresponding composites due to the HF that stiffened the multiphase systems. Similarly, a different action of MAPP was observed in the composites containing SEBS or SBS: higher Young’s and storage moduli were obtained for the composite containing SBS, while greater elongation at break and impact strength values were recorded for the SEBS-containing system. In addition, a remarkable dispersion in the MAPP-containing composite and two times smaller average particle size were revealed by the SEM analysis for the SEBS particles compared to the SBS ones. The higher affinity of SEBS for PP compared to that for SBS and the different morphological characteristics of the systems containing SEBS and SBS may explain the different effects of these impact modifiers on the mechanical properties of the composites. The composites developed in this work were designed as substitutes for the fully synthetic polymeric materials or metal components used in the manufacturing of automotive parts.

The aim of this study was to investigate the tribological characteristics of commercially available high-strength polyphthalamide-based composites with great contents (30-50 wt.%) of both carbon and glass fibers in point and linear contacts against metal and ceramic counterfaces under dry friction and oil-lubricated conditions at various loads and sliding speeds. The lengths of both types of fibers were varied simultaneously with their contents while samples were fabricated from granules by injection molding. When loading PPA with 30 wt.% SCFs at an aspect ratio (AR) of 200, the ultimate tensile strength and the elastic modulus increased up to 142.7 ± 12.5 MPa and 12.9 ± 0.6 GPa, respectively. In the composites with the higher contents of reinforcing fibers PPA/40CCF and AR~1000, the ultimate tensile strength and the elastic modulus were 240 ± 3 MPa and 33.7 ± 1.9 GPa, respectively. Under the applied test conditions, a composite reinforced with 40 wt.% carbon fibers up to 100 μm long at an aspect ratio of ~1000 possessed the best both mechanical properties and tribological characteristics. One of the reasons that should be considered for improving the tribological characteristics of the composite is the fatigue wear mechanism, which is facilitated by the high filling degree, the strong interfacial adhesion, and the great aspect ratio for fibers. Under the oil-lubricated conditions, both friction coefficients and wear rates decreased, so such friction units could be implemented whenever possible. The reported data can be used as practical recommendations for applying fibrous polyphthalamide-based composites as friction unit components.

Fiber-reinforced composites are commonly exposed to environments associated with moisture and solution, resulting in uptake, which causes changes in the bulk resin, the fiber-matrix interface, and even the fiber itself. Knowledge about uptake behavior and diffusion mechanisms and characteristics are critical to better understanding the response of these materials to environmental exposure faced through service to developing better materials through selection of constituents and to the prediction of long-term durability. This paper reviews aspects of uptake mechanisms and subsequent response, as well as models that describe the sorption process, with the aim of providing a comprehensive understanding of moisture-uptake-related phenomena and characteristics such as uptake rate, diffusion and relaxation/deterioration constants, transitions in regimes, and overall response.

In this study, tensile properties of abaca-reinforced HDPE and BioPE composites have been researched. The strength of the interface between the matrix and the reinforcement of a composite material noticeably impacts its mechanical properties. Thus, the strength of the interface between the reinforcements and the matrices has been studied using micromechanics models. Natural fibers are hydrophilic and the matrices are hydrophobic, resulting in weak interfaces. In the study, a coupling agent based on polyethylene functionalised with maleic acid was used, to increase the strength of the interface. The results show that 8 wt% coupling agent contents noticeably increased the tensile strength of the composites and the interface. Tensile properties obtained for HDPE and BioPE-based coupled composites were statistically similar or better for BioPE-based materials. The use of bio-based matrices increases the possibility of decreasing the environmental impact of the materials, obtaining fully bio-based composites. The article shows the ability of fully bio-based composites to replace others using oil-based matrices.

How to improve the bonding strength of polymers to metals has been one of the challenges in joining fields. It is generally assumed that laser transmission joining is better than laser conduction joining (LCJ) for transparent polymers, and few studies have been focused on LCJ. However, by introducing beam oscillation, an excellent result was obtained in the LCJ of transparent polyethylene terephthalate (PET) to 304 stainless steel. The interface defects of thermal decomposition and bubbles could be eliminated or reduced more efficiently in oscillating laser conduction joining (O-LCJ) rather than transmission joining. Correspondingly, the tensile shear force of joint O-LCJ could be increased by 23.8%, and the plasticity characterized by tensile displacement could be increased by seven times. The improvement mechanism was attributed to two factors by calculating the interface energy distribution and analyzing the force state at the interface. One is the homogenization of interface energy distribution caused by beam oscillation, which decreases the degradation and destruction of polymer macromolecular chains induced by high temperature. The other is the formation of interface bi-directional forces that both inhibit the porosity formation and intensify the chemical reactions. The results bring new insights and provide a new pathway to improve the joining performances of dissimilar polymers to metals.

Trapped space charges in epoxy composite distort the electric field, which will induce the failure of the insulation system, and nano graphene oxide may inhibit the curing behavior of epoxy resin matrix. This paper analyzes how the two interfaces affect the electron traps of epoxy resin/graphene oxide systems with different nanofiller contents. The electron affinity energy of epoxy resin matrix and nano filler molecules in the epoxy resin/graphene oxide system is calculated based on quantum chemistry. It is found that nano graphene oxide has a strong electron affinity energy and is easier to capture electrons. Then the influence of the interface formed by the epoxy resin matrix and the nano graphene oxide on the electron transfer ability is calculated. The epoxy resin matrix contains the electron transfer ability of interfaces formed by nano graphene oxide and the molecular chain is different from that of unreacted molecules. The results can provide a reference for the modification of epoxy resin/graphene oxide nanocomposites.

The surface of carbon fibers (CFs) is often modified by multi-walled carbon nanotubes (MWCNTs), and the effect of the interface on the mechanical properties has been reported mostly for epoxy matrices. We achieved effective surface modification of CFs by a simple two-step process to graft a large amount of MWCNTs using a highly reactive polymer to enhance the bonding between CFs and MWCNTs. The first step was the reactive mono-molecular coating of a reactive polymer (poly-2-isopropenyl-2-oxazoline; Pipozo) that has high reactivity with COOH from CFs and MWCNTs. The high reactivity between the oxazoline group and COOH or phenol OH was confirmed for low-molecular-weight reactions. The second step was the coating of MWCNTs from a dispersion in a solvent. This simple process resulted in a substantial amount of MWCNTs strongly bonded to CF, even after washing. The MWCNTs grafted onto CFs remained even after melt-mixing. The effect on the interface, i.e., physical anchoring, led to an improvement of the mechanical properties. The novelty of the present study is that Pipozo acted as a molecular bonding layer between CFs and MWCNTs as a physical anchoring structure formed by a simple process, and the interface caused a 20% improvement in the tensile strength and modulus. This concept of a composite having a physical anchoring structure of MWCNTs on CFs has potential applications for lightweight thermoplastics, such as in the automotive industry.

The dispersion level of carbon nanotubes (CNTs) and interface design are two of the most crucial roles in developing the superior mechanical performance of polymer/CNT nanocomposites. In this work, a series of azide-terminated poly(glycidyl methacrylate)-block-poly(hexyl methacrylate) (PGMA-b-PHMA) copolymers with different PHMA chain lengths and similar PGMA chain lengths were grafted on the surface of multiwall carbon nanotubes (MWNTs). PHMA length changes significantly impact the grafting density and solubility in organic solvents of as-prepared block copolymer functionalized MWNTs(bc@fMWNTs). Then, the bc@fMWNTs were introduced to epoxy, and the resulted epoxy/bc@fMWNT composites show better mechanical properties than neat epoxy and epoxy/p-MWNT composites. The results suggest that longer PHMA chains cause the two competitive and opposing effects on the dispersion state and soft interface. On the one hand, the longer PHMA chains on the surface of MWNTs would afford higher deformation for the matrix and enhanced mobility for MWNTs because of the soft and flexible nature of PHMA, enhancing the energy dissipation during strain. On the other hand, as the length of PHMA extends, the dispersion level of bc@fMWNTs in epoxy declines, which is harmful to the composite’s mechanical properties. Hence, epoxy/bc@fMWNTs composites with relatively short PHMA chains show the best tensile and fracture properties.

The self-propulsion of bodies floating in water is of great interest for developing new robotic and intelligent systems at different scales, and whenever possible, Marangoni propulsion is an attractive candidate for the locomotion of untethered micro-robots. Significant cases have been shown using liquid and solid surfactants that allow an effective propulsion for bodies floating on water to be achieved. Here, we show for the first time a strategy for activating a twofold functionality where the self-propulsion of a floating body is combined with the formation of a polymer thin film at the water surface. In fact, we demonstrate that by using polymer droplets with an appropriate concentration of solvent and delivering such drops at specific locations onto freely floating objects, it is possible to form “on-the-fly” thin polymer films at the free water surface. By exploiting self-propulsion, a polymer thin film can be formed that could cover quite extensive areas with different shapes depending on the motion of the floating object. This intriguing twice-functionality activated though a single phenomenon, i.e., film formation and related locomotion, could be used in perspective to perform complex operations at water surfaces, such as dynamic liquid packaging, cleaning, and moving away floating particles, monolayer films, or macro-sized objects, as discussed in the text.

Three different blending procedures were used to create multiwalled carbon nanotube (MWCNT)-modified chloroprene rubber (CR)/natural rubber (NR) blended composites (MWCNT/CR–NR). The effects of the blending process on the morphology of the conductive network and interfacial contacts were researched, as well as the resistance–strain response behavior of the composites and the mechanism of composite sensitivity change under different processes. The results show that MWCNT/CR–NR composites have a wide strain range (ε = 300%) and high dynamic resistance–strain response repeatability. Different blending procedures have different effects on the morphology of the conductive network and the interfacial interactions of the composites. If the blending procedures have wider conductive phase spacing and stronger interfacial contacts, the change in the conductive path and tunneling distance occurs more rapidly, and the material has a higher resistance–strain response sensitivity.

Polymer nanocomposites can serve as promising electrostatic shielding materials; however, the underlying physical mechanisms governing the carrier transport properties between nanofillers and polymers remain unclear. Herein, the structural and electronic properties of two polyethylene/graphene (PE/G) interfaces, i.e., type-H and type-A, have been systematically investigated under different electric fields using first principle calculations. The results testify that the bandgaps of 128.6 and 67.8 meV are opened at the Dirac point for type-H and type-A PE/G interfaces, respectively, accompanied by an electron-rich area around the graphene layer, and a hole-rich area around the PE layer. Moreover, the Fermi level shifts towards the valence band maximum (VBM) of the PE layer, forming a p-type Schottky contact at the interface. Upon application of an electric field perpendicular to the PE/G interface, the Schottky contact can be transformed into an Ohmic contact via the tuning of the Schottky barrier height (SBH) of the PE/G interface. Compared with the A-type PE/G interfaces, the H-type requires a lower electric field to induce an Ohmic contact. All these results can provide deeper insights into the conduction mechanism of graphene-based polymer composites as field-shielding materials.

For delayed crosslinking of waterborne epoxy varnishes, dicyandiamide (DICY) is often used as a latent curing agent. While, for amine-based curing agents such as diaminoethane (DAE), chemical interactions with metal oxides are well described, so far, no studies have been performed for DICY and waterborne epoxy varnishes. Hence, in this work X-ray photoelectron spectroscopy (XPS) was used to investigate reactions of DICY and varnishes with technical surfaces of Al, Zn, and Sn. To directly study the reaction of DICY with metal oxides, immersion tests in a boiling solution of DICY in pure water were performed. A clear indication of the formation of metal–organic complexes was deduced from the change in the N1s peak of DICY. To understand the interfacial interaction and consequently the interphase formation during coating of waterborne epoxy varnishes, advanced cryo ultra-low-angle microtomy (cryo-ULAM) was implemented. Interestingly, a comparable reaction mechanism and the formation of metal complexes were confirmed for varnishes. The coatings exhibited a pronounced enrichment of the DICY hardener at the metal oxide–polymer interface.

The mechanical properties of cementitious materials injected by epoxy have seldom been modeled quantitatively, and the atomic origin of the shear strength of polymer/concrete interfaces is still unknown. To understand the main parameters that affect crack filling and interface strength in mode II, we simulated polymethylmethacrylate (PMMA) injection and PMMA/silica interface shear deformation with Molecular Dynamics (MD). Injection simulation results indicate that the notch filling ratio increases with injection pressure (100 MPa–500 MPa) and temperature (200 K–400 K) and decreases with the chain length (4–16). Interface shear strength increases with the strain rate (1×108 s−1–1×109 s−1). Smooth interfaces have lower shear strengths than polymer alone, and under similar injection conditions, rough interfaces tend to be stronger than smooth ones. The shear strength of rough interfaces increases with the filling ratio and the length of the polymer chains; it is not significantly affected by temperatures under 400 K, but it drops dramatically when the temperature reaches 400 K, which corresponds to the PMMA melting temperature for the range of pressures tested. For the same injection work input, a higher interface shear strength can be achieved with the entanglement of long molecule chains rather than with asperity filling by short molecule chains. Overall, the mechanical work needed to break silica/PMMA interfaces in mode II is mainly contributed by van der Waals forces, but it is noted that interlocking forces play a critical role in interfaces created with long polymer chains, in which less non-bond energy is required to reach failure in comparison to an interface with the same shear strength created with shorter polymer chains. In general, rough interfaces with low filling ratios and long polymer chains perform better than rough interfaces with high filling ratios and short polymer chains, indicating that for the same injection work input, it is more efficient to use polymers with high polymerization.

This paper investigated the modification of the advanced active screen plasma (ASP) technology on PAN-derived carbon fibres (CFs) with gas mixtures of N2-H2 and N2-H2-Ar, separately. A more-than-30% improvement was found in the interfacial shear strength (IFSS) between the modified CFs and the epoxy substrate in the resulting composites, as disclosed by single fibre push-out tests. Based on the study of surface morphology, surface chemistry and water-sorption behaviour, the interfacial adhesion enhancement mechanisms were attributed to (1) the increased chemical bonding between the introduced functional groups on the fibre surface and the matrix; (2) the improved surface hydrophilicity of CFs; and (3) the enhanced van der Waals bonding due to the removal of surface contaminations.

Welding and riveting hybrid bonding technology was applied to join 6061 aluminum alloy and carbon fiber reinforced plastics (CFRP). The laser-arc hybrid welding process and stepped rivets were used in the experiments to reduce the impact of the poor heat resistance of composites. The effect of hybrid welding arc current on the formation and mechanical properties of 6061 Al/CFRP joints was studied. Tensile shear load up to 4.65 kN was achieved by adjusting process parameters. The welding process and mode of the fracture were analyzed. The hybrid bonded joint obtained consisted of two parts: a welded joint of Al plate and Al rivet, and a bonded interface between Al plate and CFRP plate. The mechanical properties of the hybrid joint were mainly determined by the Al plate/Al rivet welded joint. The results of the study show that there are three interfacial bonding mechanisms between aluminum and CFRP. In addition to mechanical bonding between the Al plate and CFRP plate, there were also metallurgical bonding of Al-Mg intermetallic compounds with resin matrix and chemical reactions of aluminum with resin and carbon fibers at the interface, which could improve the mechanical properties of the joints.

A combination of mechanical and chemical treatments was utilized to modify the surface textures of copper and duralumin inserts in order to enhance the adhesion at the metal–polymer interface and provide an adhesive joint with a high loadbearing capacity. Pretreatment of the surfaces with sandblasting was followed by etching with various chemical mixtures. The resulting surface textures were evaluated with a scanning electron microscope (SEM) and an optical confocal microscope. Surface geometry parameters (Sa, Sz, and Sdr) were measured and their relationships to the adhesion joint strength were studied. It was found that the virgin and purely mechanically treated inserts resulted in joints with poor loadbearing capacity, while a hundredfold (duralumin) and ninetyfold (copper) increase in the force to break was observed for some combinations of mechanical and chemical treatments. It was determined that the critical factor is overcoming a certain surface roughness threshold with the mechanical pretreatment to maximize the potential of the mechanical/chemical approach for the particular combination of material and etchant.

The mechanical and dynamic mechanical properties, interface adhesion and microstructures of the amino silicone oil emulsion (ASO) modified short ramie fiber reinforced polypropylene composites (RFPCs) with different fiber fractions were investigated. The RFPCs were made through a combined process of extrusion and injection molding. Mechanical property tests of the RFPCs revealed enhancements in tensile and flexural strengths with increase of the fiber fraction due to the high stiffness of the fiber filler and a better interfacial bonding from ASO treatment. The dynamic mechanical analysis (DMA) results indicated that fiber incorporation plays an important role in DMA parameters (storage modulus, loss modulus, and damping ratio) at Tg by forming an improved interfacial adhesion and providing more effective stress transfer rate and energy dissipation between matrix and fiber. The phase behavior analysis suggests all the RFPCs are a kind of heterogeneity system based on the Cole-Cole plot analysis.

Biodegradable polymeric microparticles are widely used in drug delivery systems with prolonged-release profiles and/or cell microcarriers. Their fabrication via the oil/water emulsion solvent evaporation technique has normally required emulsifiers in the aqueous phase. The present work aims to evaluate the effectiveness of various polysaccharides, such as chitosan, hyaluronic acid, cellulose, arabinogalactan, guar and their derivatives, as an alternative to synthetic surfactants for polylactide microparticle stabilization during their fabrication. Targeted modification of the biopolymer’s chemical structure was also tested as a tool to enhance polysaccharides’ emulsifying ability. The transformation of biomacromolecules into a form of nanoparticle via bottom-up or top-down methods and their subsequent application for microparticle fabrication via the Pickering emulsion solvent evaporation technique was useful as a one-step approach towards the preparation of core/shell microparticles. The effect of polysaccharides’ chemical structure and the form of their application on the polylactide microparticles’ total yield, size distribution and morphology was evaluated. The application of polysaccharides has great potential in terms of the development of green chemistry and the biocompatibility of the formed microparticles, which is especially important in biomedicine application.

Interfacial localization of carbon fillers in cocontinuous-structured polymer blends is well-known as a high-efficiency strategy for conductive network formation. However, a comparison with interfacial localization of carbon fillers in sea-island-structured polymer blends is lacking. Here, three types of highly efficient conductive networks formed on the basis of interfacial localization of carbon black (CB) in polyamide 6 (PA6)/poly(butylene terephthalate) (PBT) blends with different blend compositions (80/20, 50/50 and 20/80 vol/vol) were investigated and compared in terms of electrical resistivity, morphology as well as rheological and mechanical properties. The order of the electrical percolation threshold of CB in the three blends is 50/50 < 20/80 < 80/20, which can be attributed to different network structures. The rheological percolation thresholds are close to the electrical ones, confirming the formation of CB networks. The formation mechanisms for the three types of CB network structures are analyzed. All the three types of PA6/PBT-6 vol% CB composites showed improved tensile strength compared with PA6/PBT blends, being in favor for practical applications.

Low-density polyethylene is the most common polymer for manufacturing containers, bottles, tubes, plastic bags, computer components and so on. There is an urgent need to find solutions for its recycling and reintegration in high volume production components such as non-structural auto applications. The reinforcement of recycled low-density polyethylene with natural fibers represents a solution for the re-use of the recycled low-density polyethylene. However, there is a lack of understanding of how the natural fibers influence the behavior of the bare low-density polyethylene, and furthermore, how the interface between the fibers and the matrix can be controlled in composite to obtain the designed toughness, strength, stiffness and damping. In this sense, the study presents an in-depth analysis of the behavior of three coupling agents used in the chemically functionalized bamboo fibers interface for reinforcing low-density polyethylene composites. Through mechanical tests, the mechanical properties are determined and compared and finally, a correlation between the viscous behavior of the resulted composites and the toughening mechanism is proposed. The conclusion of the study enables a flexible design of polymer composite components fabricated of recycled and non-recycled low-density polyethylene and natural fibers.

Wood was designed, after millions of years of evolution, to perform in a wet environment. Nature is programmed to recycle it, in a timely way, back to the basic building blocks of carbon dioxide and water. All recycling chemistries start with an invasion of the wood surface. The surface of wood is porous, hygroscopic, viscoelastic, and anisotropic that is better defined in interface/interphase zones. This surface is dynamic and in constant change with changing humidity, temperature, oxygen levels, ultraviolet energy, microorganisms and stress. This chapter is a review of the chemical properties of a wood surface and performance issues associated with it.

High performing proton exchange membrane fuel cells (PEMFCs) that can operate at low relative humidity is a continuing technical challenge for PEMFC developers. In this work, micro-patterned membranes are demonstrated at the cathode side by solution casting techniques using stainless steel moulds with laser-imposed periodic surface structures (LIPSS). Three types of patterns, lotus, lines, and sharklet, are investigated for their influence on the PEMFC power performance at varying humidity conditions. The experimental results show that the cathode electrolyte pattern, in all cases, enhances the fuel cell power performance at 100% relative humidity (RH). However, only the sharklet pattern exhibits a significant improvement at 25% RH, where a peak power density of 450 mW cm−2 is recorded compared with 150 mW cm−2 of the conventional flat membrane. The improvements are explored based on high-frequency resistance, electrochemically active surface area (ECSA), and hydrogen crossover by in situ membrane electrode assembly (MEA) testing.

The aim of this study was to optimize the ultrasonic consolidation (USC) parameters for 'PEI adherend/Prepreg (CF-PEI fabric)/PEI adherend' lap joints. For this purpose, artificial neural network (ANN) simulation was carried out. Two ANNs were trained using an ultra-small data sample, which did not provide acceptable predictive accuracy for the applied simulation methods. To solve this issue, it was proposed to artificially increase the learning sample by including additional data synthesized according to the knowledge and experience of experts. As a result, a relationship between the USC parameters and the functional characteristics of the lap joints was determined. The results of ANN simulation were successfully verified; the developed USC procedures were able to form a laminate with an even regular structure characterized by a minimum number of discontinuities and minimal damage to the consolidated components.

To further explore the long-term stability of nano-dielectrics, experiments were carried out to investigate the moisture absorption characteristics and electrical properties of silicone rubber (SiR) doped with different inorganic nanoparticles. Thermogravimetric analysis (TGA) is utilized to research the moisture absorption characteristics including mass fraction and binding forms. The trap depth and electron orbitals are calculated by density functional theory to explain the influence mechanism of water molecules on SiR. It is found that the addition of nanoparticles will increase the moisture content of SiR. Additionally, the nano-TiO2-doped SiR absorbs more water and binds with water relatively more loosely than nano-Al2O3. There is a degradation of space charge inhibition capability and breakdown strength after moisture absorption, which might be explained by shallow traps brought by water molecules and the narrowed forbidden bandwidth of SiR.

The goal of this study was to investigate the effect of the structure of Mn-Al layered double hydroxide (LDH) on the adhesion behavior of composite adhesives on two Al alloys (L3005 and L8079). The composite adhesives were made out of the UV-curing Bisphenol A glycidylmethacrylate/triethylene glycol dimethacrylate (BT) as polymer matrix and the addition of 1, 3, and 5 wt. % of Mn-Al LDH as adhesion enhancers. Adhesion was evaluated by using the micro Vickers hardness testing procedure. The wetting angle of composite adhesives to the Al substrates was measured and compared to the adhesion parameter b obtained from the microhardness tests. The highest increase in adhesion was observed for BT with 5 wt. % of Mn-Al LDH on L3005 substrate, which was more than 15 times higher than the adhesion for the neat BT. The morphological segregation of composite adhesives after the contact with Al substrates was examined by optical microscopy and a higher compatibility of Mn-Al LDH particles with L3005 substrate was found. The methods used for the adhesion properties assessment suggested that the Mn-Al LDH was the best adhesion enhancer of the BT matrix for L3005 substrate containing a higher content of Mn and surface hydroxyl groups.

The interface between the semiconductor and the dielectric layer plays a crucial role in organic field-effect transistors (OFETs) because it is at the interface that charge carriers are accumulated and transported. In this study, four zwitterionic benzoquinonemonoimine dyes featuring alkyl and aryl N-substituents were used to cover the dielectric layers in OFET structures. The best interlayer material, containing aliphatic side groups, increased charge carrier mobility in the measured systems. This improvement can be explained by the reduction in the number of the charge carrier trapping sites at the dielectric active layer interface from 1014 eV−1 cm−2 to 2 × 1013 eV−1 cm−2. The density of the traps was one order of magnitude lower compared to the unmodified transistors. This resulted in an increase in charge carrier mobility in the tested poly [2,5-(2-octyldodecyl)-3,6-diketopyrrolopyrrole-alt-5,5-(2,5-di(thien-2-yl)thieno [3,2-b]thiophene)] (DPPDTT)-based transistors to 5.4 × 10−1 cm2 V−1 s−1.

Single wall carbon nanotubes (SWCNTs) were grown on either sized or desized carbon fabric in a self-designed reactor by Pulsed Laser Deposition (PLD). The uniqueness of the PLD system lies, among other things, in the ability to keep the substrate at a low temperature, compared to the 1100 °C needed for the SWCNTs synthesis, thus, rendering it undamaged. Samples were placed at different positions on a cold finger (CF), where a temperature gradient develops, in the range 25–565 °C. The chemical composition and morphology of desized and surface treatments, as well as SWCNTs grown on carbon fibres, were verified by Scanning Electron Microscopy (SEM) equipped with Energy Dispersive X-Ray Spectroscopy (EDX), while the quality of SWCNTs was proven by confocal micro-Raman Spectroscopy and High-Resolution Scanning Transmission Electron Microscopy (HR-STEM). Fibres covered with SWCNTs by PLD were characterized using contact angle and the surface free energy was calculated. A micro-droplet pull-out test was used to evaluate the effect of SWCNTs over interfacial properties of a carbon-epoxy composite. A 20% increase in interfacial shear strength (IFSS) was observed by deposition at 290 °C, compared to the commercial carbon fibre sizing. The carbon fibres kept their tensile properties due to the low deposition temperatures.

Polypropylene (PP) is a commodity material that has been increasingly used in different industries in the past two decades due to its versatile properties when enhanced with additives. Homo polypropylene, in general, has weak mechanical properties and limited chemical resistance; thus, using a different type of fillers to adjust such properties to fit the required applications opened a large market for this commodity. Understanding the interface constituent between the polymer matrix and the added filler and the nucleation behavior is a key to fine control of the enhancement of PP properties. In this study, PP was incorporated with nano calcium carbonate (CaCO3) at 2 and 5 wt% in the presence of maleic anhydride (MAH) to overcome the weak interface due to low polymer polarity. The mix was compounded in a twin screws extruder at a temperature range of 180–200 °C ; then, the prepared samples were left to dry for 24 h at 25 °C. Nuclear Magnetic Resonance (NMR) was used to study the interface adhesion of the nanofiller and the curved revealed that at 2% of nano CaCO3 PP structure remained the same and the nano experienced good adhesion to the polymer matrix. The mechanical impact resistance results showed a real enhancement to the polymer matrix of the nanocomposite by 37%. Moreover, DSC results showed a faster crystallinity rate due to the nanofiller acting as a nucleating agent and rheology tests indicated that low content of nano additive (2%) has better processability behavior, with suitable viscosity complex values at high frequencies.

3D printed neat thermoplastic polymers (TPs) and continuous fiber-reinforced thermoplastic composites (CFRTPCs) by fused filament fabrication (FFF) are becoming attractive materials for numerous applications. However, the structure of these materials exhibits interfaces at different scales, engendering non-optimal mechanical properties. The first part of the review presents a description of these interfaces and highlights the different strategies to improve interfacial bonding. The actual knowledge on the structural aspects of the thermoplastic matrix is also summarized in this contribution with a focus on crystallization and orientation. The research to be tackled to further improve the structural properties of the 3D printed materials is identified. The second part of the review provides an overview of structural health monitoring technologies relying on the use of fiber Bragg grating sensors, strain gauge sensors and self-sensing. After a brief discussion on these three technologies, the needed research to further stimulate the development of FFF is identified. Finally, in the third part of this contribution the technology landscape of FFF processes for CFRTPCs is provided, including the future trends.

A computational framework based on novel differential effective medium approximation and mean-field homogenization is used to design high-performance filler-laden polymer thermal interface materials (TIMs). The proposed design strategy has the capability to handle non-dilute filler concentration in the polymer matrix. The effective thermal conductivity of intended thermal interface composites can be tailored in a wide range by varying filler attributes such as size, aspect ratio, orientation, as well as filler–matrix interface with an upper limit imposed by the shear modulus. Serval potential polymers and fillers are considered at the design stage. High-density polyethylene (HDPE) and thermoplastic polyurethane (TPU) with a non-dilute concentration (~60 vol%) of ceramic fillers exhibit high thermal conductivity (4–5 W m−1 K−1) without compromising the high compliance of TIMs. The predicted thermal conductivity and coefficient of thermal expansion are in excellent agreement with measured data of various binary composite systems considering HDPE, TPU, and polypropylene (PP) loaded with Al2O3 and AlN fillers in varying sizes, shapes, and concentrations, prepared via the melt-mixing and compression-molding route. The model also validates that manipulating filler alignment and aspect ratio can significantly contribute to making heat-conducting networks in composites, which results in ultra-high thermal conductivity.

The article presents a study on the adhesion of thermoplastic films to a room temperature-hardening epoxy resin, which deals with an important question on sensor integration into fibre composites. By means of a morphological box, a test specimen is developed, which allows to test strength values for the adhesion of thermoplastic films to epoxy resin. Polyimide (PI), which is typically used as a carrier material for flexible sensors, is compared with the thermoplastics polyetherimide (PEI), polyethersulfone (PES) and polyamide 6 (PA6). To evaluate the spatial formation of the interface, images taken with a light microscope, fluorescence microscope and electron microscope and an energy-dispersive X-ray spectroscopy (EDX) analysis are presented. The images show that during the curing process of the epoxy resin the initially expected pronounced interphase does not form. In this respect, it is surprising that PEI achieves such a high adhesion strength even without extended interphase formation, that the failure of the test specimen occurs in the epoxy resin region at a tensile stress of 70 MPa and not at the interface between epoxy and PEI, as might initially be assumed. It is also surprising that PES exhibits the lowest adhesion strength of 5 MPa to room temperature-hardening epoxy resin, although in previous investigations it was often used as a soluble toughness modifier for epoxy resins. The tensile adhesion strength of PI to epoxy resin was found at 27 MPa and the tensile adhesion strength of PA6 to epoxy resin was found at 13 MPa. For sensor integration, the findings mean that flexible sensors on PEI substrates promise a low tendency to delaminate even in the room temperature-hardening epoxy resin used, while the other materials tested indicate an increased tendency to delaminate.

The study on durability of carbon fiber reinforced plastics (CFRP) in complex environments is critical because of its wide applications. Herein, mechanical behavior of carbon fiber reinforced epoxy composites in the fatigue process were investigated under different humidity via molecular dynamics (MD) simulation method. Transversely isotropic atom based models were established to simulate the structure of CFRP at the atomistic level. Owing to the weak performance in vertical fiber direction, mechanical behavior in a 90° orientation was investigated. Mean stress and energy were both employed to describe the evolution of mechanical performance while mean squared displacement (MSD), radius of gyration (Rg), and free volume were performed to describe the evolution of structural change during the fatigue process. The results show that the humidity led to a weakened interfacial adhesive performance. Free volume became larger under cyclic load, which caused the water molecules to diffuse into the inside of epoxy resin. The distance between the matrix and fiber became larger in the dry system while it reduced because of the diffusion of water molecules in wet system. The rate of performance degradation decreased with the increase in humidity because of poor initial performance at high humidity.

Cork is a unique material and its by-products are attracting an ever-growing interest for preparing new materials in an attempt to extend the outstanding properties of cork toward innovative and high value applications. Yet, the miscibility of cork particles with thermoplastic matrices is not easy due to its low density and surface properties. Here, cork is functionalized with poly(methyl methacrylate) (PMMA) via atom transfer radical polymerization (ATRP) to yield cork grafted with PMMA chains particles (cork-g-PMMA). Both the ATRP macroinitiator and the cork-g-PMMA obtained are fully characterized by Fourier-transform infrared spectroscopy (FT-IR), 13C cross-polarized magic-angle spinning solid-state nuclear magnetic resonance (13C CP/MAS solid state NMR), scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD) and thermogravimetric analyses (TGA). The functionalized cork particles are then blended with commercial PMMA to afford cork-g-PMMA/PMMA. To compare, cork also is mixed with PMMA and the ensuing cork/PMMA sample and its morphology, thermal, and mechanical properties are compared with those of cork-g-PMMA/PMMA and commercial PMMA. The cork surface modification via ATRP of the methyl methacrylate (MMA) yields better dispersion in the matrix. Consequently, a blend with enhanced mechanical performance, higher thermal stability, and a higher melt flow index (MFI) is obtained when compared to the blend prepared using unmodified particles. The similarity of the MFI of cork-g-PMMA/PMMA to that of PMMA suggests good printability. Indeed, a three-dimensional (3D) printed specimen is obtained confirming that grafting using ATRP is a promising route for the preparation of high quality 3D printed products.

In this work, the localization of reactive compatibilizer (RC, containing poly(methyl methacrylate) (PMMA) backbone with randomly distributed glycidyl methacrylate (GMA) on it) at the polyvinylidene fluoride/poly(l-lactic acid) (PVDF/PLLA) interface has been manipulated by means of GMA contents. At the very beginning of mixing, RC tends to stay in the PVDF phase due to the miscibility between PVDF and PMMA. Upon further shearing, more and more PLLA chains have been grafted on PMMA backbone, producing PLLA–g–PMMA copolymer. The balanced stress on two sides accounts for the localization of compatibilizers at the PVDF/PLLA interface. Finally, the stress of the PLLA side has been enhanced remarkably due to the higher graft density of PLLA, resulting in the enrichment of the copolymer in the PLLA matrix. The migration of RC from the PVDF phase to the immiscible interface and PLLA matrix can be accelerated by employing RC with higher GMA content. Furthermore, the compatibilizer localization produces a significant influence on the morphology and ductility of the PVDF/PLLA blend. Only when the compatibilizers precisely localize at the interface, the blend exhibits the smallest domain and highest elongation at break. Our results are of great significance for not only the fabrication of PLLA with high ductility, but also the precise localization of compatibilizers at the interface of the immiscible blend.

The aim of this work was to study the interfacial behavior of basalt-fiber-reinforced thermoplastic blends of polypropylene and poly(butylene terephthalate) (PP/PBT). We examined the effect of two compatibilizers and two basalt fiber (BF) sizings: commercial (REF) and experimental (EXP). Differential scanning calorimetry was used to assess the influence of BFs on the phase structure of obtained composites. Furthermore, dielectric relaxation spectroscopy was used for the first time to non-destructively study the interfacial adhesion within an entire volume of BF-reinforced composites by assessing the α relaxation, DC conductivity, and Maxwell–Wagner–Sillars (MWS) polarization. The fiber–matrix adhesion was further investigated using the Havriliak–Negami model. Using complex plane analysis, the dielectric strength, which is inversely related to the adhesion, was calculated. The composites reinforced with EXP fibers showed significantly lower values of dielectric strength compared to the REF fibers, indicating better adhesion between the reinforcement and blend matrix. Static bending tests also confirmed improved fiber adhesion with EXP fibers, while also suggesting a synergistic effect between compatibilizer and sizing in enhancing interfacial properties. Thus, we conclude that substantially improved adhesion of PP/PBT BF-reinforced composites is the result of mutual interactions of functional groups of blend matrix, mostly from blend compatibilizer, and fiber surface due to sizing.

In this work, date palm waste (DPW) stemming from the annual pruning of date palm was used as reinforcing filler in polypropylene (PP) matrix at 40% w/w. Three pre-treatment routes were performed for the DPW, namely (i) defibration, (ii) soft alkali treatment, and (iii) enzymatic treatment, to obtain date palm fibers (DPF) and to investigate the effect of each process on their chemical composition, which will ultimately affect the mechanical properties of the resulting composites. The enzymatic and alkali treatment, combined with maleated polypropylene (MAPP) as a coupling agent, resulted in a composite with higher strength and stiffness than the neat PP. The differences in the reinforcing effect were explained by the change in the morphology of DPF and their chemical surface composition according to the selected treatment of DPW. Enzymatic treatment maximized the tensile strength of the compound as a consequence of an improvement in the interfacial shear strength and the intrinsic resistance of the fibers.

Previous experiments of water vapor penetration into polyelectrolyte membrane (PEM) thin films have indicated the influence of the water concentration gradient and polymer chemistry on the interface evolution, which will eventually affect the efficiency of the fuel cell operation. Moreover, PEMs of different side chains have shown differences in water cluster structure and diffusion. The evolution of the interface between water and polyelectrolyte membranes (PEMs), which are used in fuel cells and flow batteries, of three different side-chain lengths has been studied using dissipative particle dynamics (DPD) simulations. Higher and faster water uptake is usually beneficial in the operation of fuel cells and flow batteries. The simulated water uptake increased with the increasing side chain length. In addition, the water uptake was rapid initially and slowed down afterwards, which is in agreement with the experimental observations. The water cluster formation rate was also found to increase with the increasing side-chain length, whereas the water cluster shapes were unaffected. Water diffusion in the membranes, which affects proton mobility in the PEMs, increased with the side-chain length at all distances from the interface. In conclusion, side-chain length was found to have a strong influence on the interface water structure and water penetration rates, which can be harnessed for the better design of PEMs. Since the PEM can undergo cycles of dehydration and rehydration, faster water uptake increases the efficiency of these devices. We show that the longer side chains with backbone structure similar to Nafion should be more suitable for fuel cell/flow battery usage.

A novel and effective strategy was first proposed for the codeposition of a mussel-inspired nanohybrid coating with excellent wettability onto the surface of carbon fibers (CFs) by simultaneous polymerization of bioinspired dopamine (DA) and hydrolysis of commercial tetraethoxysilane (TEOS) in an eco-friendly one-pot process. Mussel-inspired nanohybrids could be adhered onto the surface of CFs firmly. The novel modification could afford sufficient polar groups and significantly improve fiber surface roughness and energy without decreasing fiber intrinsic strength, which were advantageous to promote interfacial compatibility and wettability between CFs and matrix resin. As a result, the interfacial shear strength of composites increased to 48.21 ± 1.45 MPa compared to that of untreated composites 29.47 ± 0.88 MPa. Meanwhile, the nanohybrid coating increased significantly composites’ hydrothermal aging resistance. The efficient strategy shows a promising and green platform of surface functionalization of CFs for preparing advanced polymer composites arising from broadly mechanical-demanding and energy-saving usages.

Near-monodispersed micrometer-sized polystyrene (PS) particles carrying amidino and carboxyl groups on their surfaces were synthesized by soap-free emulsion polymerization using an amphoteric free radical initiator. The resulting amphoteric PS particles were characterized in terms of diameter, morphology, disperibility in aqueous media and surface charge using scanning electron microscopy (SEM), optical microscopy (OM), sedimentation rate and electrophoretic measurements. At pH 2.0, where the amidino groups are protonated (positively charged), and at pH 11.0, where the carboxyl groups are deprotonated (negatively charged), the PS particles were well dispersed in aqueous media via electrostatic repulsion. At pH 4.8, where the surface charges are neutral, the PS particles were weakly aggregated. Furthermore, it was confirmed that the PS particles can function as a pH-sensitive foam stabilizer: foamability and foam stability were higher at pH 2.0 and 4.8, where the PS particles can be adsorbed to the air–water interface, and lower at pH 11.0, where the PS particles tend to disperse in bulk aqueous medium. SEM and OM studies indicated that hexagonally close-packed arrays of PS particles were formed on the bubble surfaces and moiré patterns were observed on the dried foams. Moreover, the fragments of dried foams showed iridescent character under white light.

The focus of this paper is the realization and verification of a modified fiber bundle pull-out test setup to estimate the adhesion properties between threads and elastic matrix materials with a more realistic failure mode than single fiber debond techniques. This testing device including a modified specimen holder provides the basis for an adequate estimation of the interlaminar adhesion of fiber bundles including the opportunity of a faster, easier, and more economic handling compared to single fiber tests. The verification was done with the single-fiber and microbond test. Overall, the modified test setup showed the typical pull-out behavior, and the relative comparability between different test scales is given.

In the present research, to enhance interfacial wettability and adhesion between carbon fibers (CFs) and matrix resin, hydrophilic silica nanoparticles (SiO2) were utilized to graft the surface of CFs. Polydopamine (PDA) as a “bio-glue” was architecturally built between SiO2 and CFs to obtain a strong adhesion strength and homogenous SiO2 distribution onto the surface of CFs. The facile modification strategy was designed by self-polymerization of dopamine followed by the hydrolysis of tetraethoxysilane (TEOS) onto carbon fibers. Surface microstructures and interfacial properties of CFs, before and after modification, were systematically investigated. The tight and homogeneous coverage of SiO2 layers onto the CF surface, with the assistance of a PDA layer by self-polymerization of dopamine, significantly enhanced fiber surface roughness and wettability, resulting in an obvious improvement of mechanical interlocking and interfacial interactions between CFs and matrix resin. The interlaminar shear strength (ILSS) and the interfacial shear strength (IFSS) of CF/PDA/SiO2 reinforced composites exhibited 57.28% and 41.84% enhancements compared with those of untreated composites. In addition, impact strength and the hydrothermal aging resistance of the resulting composites showed great improvements after modification. The possible reinforcing mechanisms during the modification process have been discussed. This novel strategy of developed SiO2-modified CFs has interesting potential for interfacial improvements for advanced polymer composites.