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Frontal polymerization (FP) is a self-sustaining reaction that relies on polymerization exothermicity and heat transfer. This study explores the inplane and in-depth FP mechanisms of continuous fiber-reinforced epoxy composites. First, the effects of initiator and diluent concentrations on the FP behaviors of neat epoxy resins were examined. It was found that the frontal velocity and frontal temperature of the neat resins increase with an increase of either the initiator concentration or the diluent content, depending on the polymerization enthalpy and curing kinetics. Then, the FP behaviors of continuous carbon fiber and glass fiber-reinforced epoxy woven composites were investigated. The results showed that the in-plane FP behavior of the composites was primarily controlled by the thermal conductivity and specific heat capacity of the continuous fibers, whereas the in-depth FP behavior mainly depended on the pores of the woven fabrics. Highlights • Frontal velocity and temperature of neat resins are controlled by the polymerization enthalpy and curing kinetics. • The in-plane FP behavior of continuous fiber reinforced composites is dependent on the thermal conductivity and specific heat capacity of the fibers. • The in-depth FP behavior of composite is determined by both the thermal conductivity of fibers and the pores of fabrics. [ABSTRACT FROM AUTHOR]

In this study, we compare the effect of various precursor‐based graphene oxide (GO) nanofillers on enhancing the mechanical performance of E‐glass fiber‐reinforced epoxy resin composites (EGFPs). GO derived from bituminous coal (BC‐GO) and graphite (Gr‐GO) were dispersed into an epoxy resin matrix. The resulting mixture was combined with E‐glass fiber mats using vacuum‐assisted resin infusion molding. Notable improvements (38.9% in flexural strength, 22.9% in tensile strength, and 21.6% in impact strength) were observed in BC‐GO‐reinforced EGFPs at 0.25 phr loading of BC‐GO. The improvements for Gr‐GO‐reinforced EGFPs were 28%, 9.3%, and 6.8%, respectively. XRD analysis of BC‐GO showed a diffraction peak at 2θ = 20.9°. Except for this peak, no other crystalline peaks were observed when BC‐GO was incorporated into EGFPs. FTIR spectra of both composite samples, with or without the nanofiller, were similar due to the spectral peaks overlap. TEM demonstrated the exfoliated morphology of BC‐GO in EGFPs. These findings underscore the potential of BC‐GO as a cost‐effective reinforcement for polymer nanocomposites across various industrial applications, including the development of lightweight and strong materials for aerospace and automotive industries, protective coatings, petroleum, and aerospace production systems. Highlights: BC‐GO demonstrates superior mechanical performance compared to Gr‐GO in EGFPs.0.25 phr BC‐GO improves 38.9% flexural, 22.9% tensile, and 21.6% impact strengths.Beyond 0.25 phr, BC‐GO and Gr‐GO showed a decline in mechanical enhancement.Role of particle size, loading & adhesion to matrix analyzed using XRD, FTIR, and DLS.Coal‐GO is an attractive alternative nanofiller for EGFPs. [ABSTRACT FROM AUTHOR]

Glass fibers (GFs) are frequently employed as reinforcement fibers for polymer resins such as epoxy and polyester. The mechanical behaviors of GFs polymer composites are nevertheless constrained by weak interfacial adhesion between polymer matrix and GFs. Herein, we invented a cross‐linking modified sizing agent using polyethyleneimine and bisphenol A epoxy emulsion, and studied the effect of cross‐linking extent on GF surface characteristics and GF/epoxy interfacial adhesion. The treatment of GFs with cross‐linking modified sizing agent facilitated the formation of interpenetrating polymer networks in composites for strengthening interface interaction. The results show that the modified GFs have a rough surface and improved interfacial adhesion with epoxy matrix. When sizing agents with cross‐linking extent of the 23.0%, the GF/epoxy composites show advanced interfacial shear strength (IFSS) and transverse fiber bundle tension (TFBT) strength. This work demonstrates that the cross‐linking extent of sizing agent could regulate interfacial adhesion, which is a facile and promising strategy in reinforcing glass fiber polymer composites. Highlights: Crosslink the sizing agent to enhance GF mechanical properties was reported.GF surface energy was enhanced and thickness of GF/epoxy interphase increased.IFSS and TFBT strength of the GF/resin composites increased by 23.65% and 30.54%, respectively. [ABSTRACT FROM AUTHOR]

Glass fiber‐reinforced polymer‐matrix (GFRP) composites are used to manufacture devices such as radomes, electrical insulators, and radar‐absorbing structures, many of which are used in applications with strict mechanical and dielectric property requirements. As such, designs and properties of GFRP composite materials should be regularly improved to guarantee their safe operation and meet their constantly evolving application requirements. In this study, glass fiber (GF) particles and epoxy resin 128 (EP‐128) were used to manufacture high‐performance EP/GF‐X composites with GF particle contents ranging from 5% to 40%. An investigation into their mechanical and dielectric properties revealed that EP/GF‐20 composite specimens presented the best mechanical performance with their bending strength and modulus reaching 159.68 MPa and 6521.92 MPa, respectively, and an average dielectric constant of 4.862 within the 10–105 Hz frequency range. A theoretical analysis of the EP/GF‐X composite specimens' dielectric constants using classic dielectric models based on the Lichtenecker, Bruggeman, Jaysundere‐Smith, and Maxwell‐Garnett rule‐of‐mixture equations indicated that the dielectric model based on the Bruggeman rule‐of‐mixture equation provided the dielectric constants closest to the measured values with a maximum deviation of less than −0.321% for EP/GF‐40 composites. This study provides a feasible strategy to control the mechanical and dielectric properties of GFRP composites. Highlights: Glass fiber (GF) particles and epoxy 128 (EP‐128) resin were used to manufacture high‐performance glass fiber‐reinforced epoxy (EP/GF‐X) composites.The composite manufacturing process was carefully controlled to ensure uniform distribution and orientation of GF particles in the EP‐128 resin.The mechanical and dielectric properties of the manufactured EP/GF‐X composites were effectively tailored by controlling the content and distribution of GF particles in the EP‐128 resin matrix.The dielectric constants of the EP/GF‐X composites were measured experimentally and predicted using various theoretical dielectric models.The Bruggeman model provided the dielectric constants of the EP/GF‐X composites closest to the measured values. [ABSTRACT FROM AUTHOR]

The effect of incorporation of micron sized aluminum trihydrate, multi‐walled carbon nanotubes, and graphene nano platelets into glass fiber reinforced epoxy matrix is investigated using dynamic mechanical analysis. The objective of the investigation was to develop polymer central core of high temperature low sag transmission conductor. The effect of individual and hybrid carbon fillers on the viscoelastic properties of the epoxy composites is investigated and discussed. The storage modulus of the glass reinforced epoxy increases by 20% at room temperature due to incorporation of carbon nanofillers. In glass transition region, the increase is higher between 40% and 60% and it varies up to 90% in the rubbery region. Key attributes of carbon filler addition are limited enhancement of storage modulus at room temperature, higher enhancement over glassy, glass transition, and rubbery regions. The carbon fillers extend the temperature range of the glassy region. The cross‐link density, filler efficiency, and degree of entanglement of fibers are estimated to understand the implications of the carbon fillers on the viscoelastic properties. The loss modulus peak of glass epoxy composite increases from 2800 to 3900 MPa with carbon fillers and the increase in glass transition temperature is 47°C. Incorporation of carbon fillers leads to increase of damping factor peak from 0.2 to 0.28. Cole–Cole plots have established the inherent heterogeneity of epoxy systems due to the presence of carbon fillers. Prediction models for storage modulus and damping factor have been proposed to highlight the influence of geometry and size of carbon filler. [ABSTRACT FROM AUTHOR]

For commercial civil applications of laminated composite material, characterizations to forecast the interlaminar shear behavior and viscoelastic response across a wide temperature range are essential. In this study, the interlaminar shear strength (ILSS) of glass/epoxy (GE) composites dispersed with binary nanofillers nanosilica‐multilayer graphene (NS‐MLG) and nanosilica‐nanoclay (NS‐NC) was analyzed at an in‐situ testing temperature of 20, 70, and 110°C. Further, the viscoelastic property of the composites was studied using a dynamic mechanical thermal analyzer (DMTA) in the temperature range of 35–165°C. An increase in the ILSS value of around 9% and 10% was observed at room temperature for GE/MLG‐NS and GE/NC‐NS, respectively, compared to control GE composites. In contrast, the trend was seen to change at higher temperatures. There was a slight decrement in the storage modulus (E′) of GE/MLG‐NS and GE/NC‐NS composites in the glassy region compared to control GE composites. The mean Tg of the GE composite (control) was nearly 107.3°C when the E′ decline onset temperature was taken into account, but after the addition of MLG‐NS, it was 10.1°C below. The mean Tg of GE/NC‐NS was determined to be 106.3°C, and in the glass transition as well as rubbery regions, it was observed to compete with the E′ value of the control GE composites. Fractography was done using micrographs obtained from environmental scanning electron microscope (ESEM). Traces of polymeric material found at the fiber surface certified the improved interfacial adhesion between glass fiber and polymer in the matrix‐modified composite samples. [ABSTRACT FROM AUTHOR]

The fabrication of carbon fiber‐reinforced polymer composites generates vast amounts of waste carbon fiber. In the present work, these waste carbon fibers were added in varying contents (0.1, 0.3, and 0.5 wt%) to glass fiber/epoxy (GE) composite as short carbon fibers (SCFs) to improve its ambient and elevated temperature mechanical performance. The flexural and tensile behavior of the SCF modified GE composites were assessed at 30, 50, 70, and 110°C. The most significant improvement in mechanical performance was achieved by adding only 0.1 wt% of SCF into GE composite across most of the temperatures. At elevated temperatures, all the SCF‐modified GE composites showed superior mechanical performance over the control GE composite. An important correlation between SCF content in GE composite and elevated temperature mechanical performance enhancement has been discussed. Differential scanning calorimetry was performed to understand the effect of SCF addition on GE composite's glass transition behavior. Fractography was conducted to study the various failure mechanisms at ambient and elevated temperatures. [ABSTRACT FROM AUTHOR]

The objective of the present work is to understand how the main constituents of sizing modify the interfacial strength, the mechanical properties of epoxy composites as well as their durability. In this study, two model interphases between E‐glass fibers and epoxy resin were designed and studied in terms of adhesion and mechanical strength from nano to macroscale. The first one is made from a reactive sizing of APTMS silane coupling agent and DGEBA pre‐polymer film‐former. The other one contains a non‐reactive MTES silane and neutralized DGEBA film‐former. The sizings were evidenced by SEM/AFM observations and XPS spectroscopy. The characterization of the prepared composites by AFM nano‐mechanic mode, micromechanical tests revealed the effect of the sizing chemistry on the interfacial properties between glass fibers and matrix. The interfacial strength is more important for the composites reinforced with APTMS‐DGEBA sized fibers than those prepared with MTES‐BGEA sized fibers. In each case, an interphase area of around 200 nm width is detected at fibers vicinity. In this area, the elastic modulus is more than 25% lower than the bulk matrix modulus. [ABSTRACT FROM AUTHOR]

This study investigates the influence of reduced graphene oxide (rGO) coated glass fabrics on the strain sensing and the mechanical characteristics of fiber‐reinforced composites. Graphene oxide was applied in two thicknesses (threefold and fivefold coatings) onto a fabric using a padder mangle machine followed by thermal reduction and infused with an epoxy to manufacture rGO‐enhanced composite. The tensile modulus and flexural strength of the rGO‐enhanced composites with threefold coating were improved by 27% and 6.2%, respectively, compared with the equivalent composite manufactured without rGO. The normalized resistance (ΔR/R0) of composites increased by 0.89% and 3.48% under a cyclic tensile force of 1000 and 4000 N. The magnitude of ΔR/R0 was stable within 30 cycles suggesting a consistent strain sensing performance with a gauge factor of 15.55. The electrical response of the rGO‐enhanced composite was evaluated using a new industrial standard for sensors, by assessing calibration curves. The composite showed low hysteresis and low electrical viscosity which make these materials suitable for industrial piezoresistive strain sensors. [ABSTRACT FROM AUTHOR]

In sandwich composites, interfacial bonding between face sheets and core has to be strengthened to prevent debonding. In this work, sandwich composites with polyurethane core and glass fiber reinforced epoxy face sheets were prepared by vacuum infusion process. Chopped fibers of glass, carbon, and kevlar with length 12 mm were introduced between core and face sheets during fabrication in order to improve face‐core bonding. The influence of chopped fibers is investigated by testing flexural, compressive, shear, and fracture toughness properties of prepared specimens according to ASTM standards. Sandwich specimens with chopped glass fibers exhibited, superior interfacial bonding between the face and the core and hence improved the mechanical properties of sandwich composite. The chopped glass fiber embedded sandwich composite has an increased flexural strength of 32.77% and compressive strength of 21.43% when compared with plain sandwich composite. In addition, the shear strength and fracture toughness behavior of specimens with chopped glass fibers are superior when compared to other chopped fibers incorporated in the interfacial region. The interfacial region between skin and core was investigated using scanning electron microscopy (SEM). Chopped glass fibers in the interfacial region showed better adhesion property along with the epoxy. [ABSTRACT FROM AUTHOR]

The article discusses the fabrication, mechanical characterization, and heat resistance of nano ZnO‐TiO2‐filled glass fiber‐reinforced LY556 epoxy composites, with focus on the synergistic effect of ZnO and TiO2 nanofillers. The fabrication of the composite laminates is achieved by the addition of the nanofillers in different wt% ranging from 1 to 5 wt%. The composites are prepared using simple hand layup technique followed by curing under vacuum. The 3D atomic force microscopy scans indicated even distribution of the nanofillers up to 2 wt% loading. Severe agglomeration of the nanofillers is evident for 3 to 5 wt% loading. The surface roughness, microhardness, flexural strength, tensile strength, and impact strength of the composites indicate a relationship with dispersion, wt% loading, and the wettability of the nanofiller with the LY556. In general, it is found that the incorporation of hard nanofillers favored the improvement of impact strength to a greater extent compared to tensile and flexural strengths. Detailed analysis of the obtained mechanical property values favors an optimum 2 wt% incorporation of the selected nanofillers to obtain improvement in various strength values of the fabricated composites. The thermal stability of the fabricated composites improved through the incorporation of ceramic nanofillers. [ABSTRACT FROM AUTHOR]