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Start Over Author "Mohit Khurana" Journal polymer chemistry
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1. Block copolymers containing stable radical and fluorinated blocks with long-range ordered morphologies prepared by anionic polymerization

Author

Alvin Chandra, Teruaki Hayakawa, Mohit Khurana, Alicia Cintora, Hiroki Takano, and Christopher K. Ober

Subjects
chemistry.chemical_classification, Materials science, Polymers and Plastics, Organic Chemistry, Dispersity, Bioengineering, 02 engineering and technology, Polymer, 010402 general chemistry, 021001 nanoscience & nanotechnology, Methacrylate, 01 natural sciences, Biochemistry, Article, Surface energy, 0104 chemical sciences, Anionic addition polymerization, chemistry, Polymer chemistry, Copolymer, Grazing-incidence small-angle scattering, Lamellar structure, 0210 nano-technology
Abstract

We report a facile synthetic approach to create stable radical block copolymers containing a secondary fluorinated block via anionic polymerization using a bulky, sterically hindered countercation composed of a sodium ion and di-benzo-18-crown-6 complex. The synthetic conditions described in this report allowed for controlled molecular weights and dispersity (

Published
2019
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