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In this manuscript, we have demonstrated an efficient and rapid synthetic strategy for preparation of new fluorene–dendron-hybridized blue light-emitting polymers P1–P7 by the reaction of 9,9 long-chain dialkylated fluorenes M2–M8 with dendronized monomer (M1) under microwave-assisted reaction condition. These fluorene–dendron-hybridized polymers P1–P7 were characterized using different spectroscopic techniques. Furthermore, the optophysical properties of these polymers P1–P7 were studied which revealed that these synthesized polymers P1–P7 have potential to emerge as capable materials in the development of diodes, particularly for blue light emission. In the future, similar approaches would be utilized for preparation of light-emitting polymer composite. [ABSTRACT FROM AUTHOR]

We have investigated the effects of localized surface plasmons (LSPs) on the performance of quasi-solid-state dye-sensitized solar cells (DSSCs). Ag and Au nanoparticles (NPs) were prepared by photoreduction in the presence of generation 5 polyester hydroxyl acetylene bis(hydroxymethyl)propanoic acid dendrons (Dendron) as a stabilizer. The plasmon-enhanced DSSCs were achieved by incorporating metal@Dendron NPs into TiO photoanodes. The presence of dendrons prevents the photoelectrons from recombining on the surface of TiO semiconductor and improves the stability of metal NPs. With the addition of Ag@Dendron NPs, the photocurrent and the power conversion efficiency of quasi-solid-state DSSCs increased due to the LSP effect of metal NPs and the barrier effect of dendron, which were confirmed by the increased incident photon-to-photocurrent efficiency and by electrochemical impedance spectroscopy analysis. [ABSTRACT FROM AUTHOR]