1. The synthesis and structures of arene-substituted azadipyrromethenes.
- Author
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Chanawanno, Kullapa, Hasheminasab, Abed, Engle, James T., and Ziegler, Christopher J.
- Subjects
- *
DIPYRRINS , *CRYSTAL structure , *SUBSTITUTION reactions , *AROMATIC compound synthesis , *CHALCONE synthase , *HYDROGEN bonding - Abstract
We present the synthesis of several azadipyrromethenes with four peripheral arene units which can be readily generated via the well-established chalcone synthetic method. The stability and yields of these azadipyrromethenes is highly dependent on the nature of the arene substituent, with the bis-pyridine systems exhibiting the highest degree of instability. The structures of several of the compounds and their BF 2 adducts are presented; intramolecular hydrogen bonding is observed in the free base ADPMs. We also present a study into the absorption and emission properties of the ADPMs and their BF 2 adducts and observe that they are also highly dependent on the identity of the substituents. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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