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Your search keyword '"Clarke, Matthew L."' showing total 4 results
Start Over Author "Clarke, Matthew L." Search Limiters Peer Reviewed Publication Year Range Last 50 years Journal polyhedron
4 results on '"Clarke, Matthew L."'

4. Preparation and coordination chemistry of Ph2P(CH2)nNHPiPr2 (n=2, 3)

Author

Appleby, Tracey, Aucott, Stephen M., Clarke, Matthew L., Slawin, Alexandra M.Z., and Derek Woollins, J.

Subjects
*LIGAND field theory, *CHELATES
Abstract

Unsymmetrical diphosphine ligands of the type Ph2P(CH2)nNHPPri 2 [n=2 (1), 3 (2)] have been obtained by reacting the appropriate (diphenylphosphino)alkylamine, Ph2P(CH2)nNH2 with chlorodi-iso-propylphosphine, in the presence of triethylamine. Reaction of Ph2P(CH2)2NHPPri 2 with PdCl2(PhCN)2, PtCl2(PhCN)2, PtMe2(cod) and PtClMe(cod), NiCl2·6H2O and Fe(CO)2(η5-C5H5)I gives the corresponding chelate complexes, PdCl2L, PtX2L, NiCl2L and Fe(CO)(η5-C5H5)L. Reaction of Ph2P(CH2)3NHPPri 2 with PtCl2(PhCN)2, PtMe2(cod) and PdCl2(PhCN)2 yields the chelate complexes and reaction with PtClMe(cod) led to a 50:50 mixture of chelate isomers. [Copyright &y& Elsevier]

Published
2002
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