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Abstract Glass fibre (GF), nanoclay (NC) and hybrid composites compatibilised with maleic anhydride polypropylene (MAPP) were prepared by extrusion and injection moulding. The fourier transform infra-red spectra revealed the characteristic absorption peaks of MAPP in the compatibilised GF and NC composites. A decrement in the peak intensity of X-ray diffraction patterns of NC composite was obtained as the MAPP content increased indicating a partial exfoliation of NC. The thermogravimetric analysis showed that the incorporation of MAPP into hybrid composites reduced the thermal stability of the material. The dynamic mechanical analysis showed an increase in the storage modulus in the hybrid composites with lower content of MAPP due to the enhancement in the interfacial adhesion between the GF, NC and PP matrix.

AbstractAcid surface modified carbon nanotube (MCNT)-, Carbon nanotube (CNT)-filled fluoroelastomer (FE) and unfilled-FE were prepared (MCNT/FE, CNT/FE and FE). The compounds were subjected to thermogravimetric analysis (TGA) and heat air aging, and characterized by Energy Dispersive X-Ray (EDX). Results showed that MCNT improved the thermal properties of FE, resulting in a larger amount of FE and char remaining in the temperature range of 400-900 °C relative to unfilled FE and CNT/FE. The MCNT/FE TGA curve shifted towards higher temperatures compared to CNT/FE and FE. The same results also revealed that higher percentages of FE were undegraded or less degraded especially near MCNT in the temperature range of 400-540 °C. Energy Dispersive X-Ray (EDX) results indicated that the percentage of carbon and fluorine in the residue of TGA scans, up to 560 °C, of MCNT/FE were the same as CNT/FE, and were higher than FE. EDX results of TGA residue (run up to 900 °C) showed that most of the undegraded FE, which was not degraded at temperatures below 560 °C, was degraded from 560 °C to 900 °C in both MCNT/FE and CNT/FE, with the char in MCNT/FE being more than that in CNT/FE. EDX analysis of thermal aged specimens under air showed that, with increasing aging time, a greater percentage of C, O and F was lost from the surface of filler/FE and FE. The order of element loss after 24 hour aging time was: MCNT/FE > FE > CNT/FE.