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Abstract: In the history of Mars exploration its atmosphere and planetary climatology aroused particular interest. In the study of the minor gases abundance in the Martian atmosphere, water vapour became especially important, both because it is the most variable trace gas, and because it is involved in several processes characterizing the planetary atmosphere. The water vapour photolysis regulates the Martian atmosphere photochemistry, and so it is strictly related to carbon monoxide. The CO study is very important for the so-called “atmosphere stability problem”, solved by the theoretical modelling involving photochemical reactions in which the H2O and the CO gases are main characters. The Planetary Fourier Spectrometer (PFS) on board the ESA Mars Express (MEX) mission can probe the Mars atmosphere in the infrared spectral range between 200 and 2000cm−1 (5–50μm) with the Long Wavelength Channel (LWC) and between 1700 and 8000cm−1 (1.2–5.8μm) with the Short Wavelength Channel (SWC). Although there are several H2O and CO absorption bands in the spectral range covered by PFS, we used the 3845cm−1 (2.6μm) and the 4235cm−1 (2.36μm) bands for the analysis of water vapour and carbon monoxide, respectively, because these ranges are less affected by instrumental problems than the other ones. The gaseous concentrations are retrieved by using an algorithm developed for this purpose. The PFS/SW dataset used in this work covers more than two and a half Martian years from Ls=62° of MY 27 (orbit 634) to Ls=203° of MY 29 (orbit 6537). We measured a mean column density of water vapour of about 9.6pr. μm and a mean mixing ratio of carbon monoxide of about 990ppm, but with strong seasonal variations at high latitudes. The seasonal water vapour map reproduces very well the known seasonal water cycle. In the northern summer, water vapour and CO show a good anticorrelation most of the time. This behaviour is due to the carbon dioxide and water sublimation from the north polar ice cap, which dilutes non-condensable species including carbon monoxide. An analogous process takes place during the winter polar cap, but in this case the condensation of carbon dioxide and water vapour causes an increase of the concentration of non-condensable species. Finally, the results show the seasonal variation of the carbon monoxide mixing ratio with the surface pressure. [Copyright &y& Elsevier]

Abstract: In this study we map the methane gas in the Martian atmosphere. The main goal of this work is to show the methane behaviour across the planet seasonally. To this aim, we analyze the strongest methane band in the short wavelength channel of the Planetary Fourier Spectrometer (PFS) on board ESA Mars Express (MeX) spacecraft. The optical line depth is used to derive the column density of methane. The maps thus obtained show the spatial variability of this non-condensable gas and how the gas is transported in the atmosphere due to the cycle of carbon dioxide. Moreover, the increase of methane over the north polar cap during local summer, which cannot be explained by global circulation, strongly suggests that there could be methane reservoir associated with the polar cap. [Copyright &y& Elsevier]

Abstract: A large number of spectra measured by the planetary Fourier spectrometer aboard the European Mars Express mission have been studied to identify the average properties of methane in the Martian atmosphere. Using the line at 3018cm−1, we have studied the seasonal, diurnal, and spatial variations of methane through the analysis of large averages of spectra (more than 1000 measurements). Methane mixing ratio has been obtained simultaneously with water vapour mixing ratio and water ice content, by best fitting (minimising the χ 2) the computed averages with synthetic spectra. These spectra were computed for different values of the three parameters (methane and water vapour mixing ratio, and water ice optical depth). The methane mixing ratio shows a slow decrease from northern spring to southern summer with an average value of 14±5ppbv (part per billion by volume) and it does not show a particular trend with latitude. The methane mixing ratio seems not to be uniform in longitude in the Martian atmosphere, as already reported by Formisano et al. [2004. Detection of methane in the atmosphere of Mars. Science 306, 1758–1761]. Two maxima are present at −40°E and +70°E longitude. In local time, the methane mixing ratio seems to follow the water vapour diurnal cycle. The most important point for future understanding is, however, that there are special orbits in which methane mixing ratio has a very high value. [Copyright &y& Elsevier]

Abstract: This work presents a review of the observations acquired by the planetary Fourier spectrometer (PFS) in the region of the Hellas basin. Taking advantage of the high spectral resolution of PFS, the vertical air temperature profile can be investigated with a previously unexperienced vertical resolution. Extensive comparisons with the expectations of EMCD 4.0 database highlight moderate discrepancies, strongly dependant on season. Namely, the morning observations acquired around L s=45° show a series of temperature deficiencies with recurrent spatial patterns in different observations, correlated with the topography profile. Trends of integrated dust loads as a function of the field of view (FOV) elevation are also described. Values are consistent with the retrieval hypothesis of a dust scale height equal to the gas one, even far from the season of main dust storms. [Copyright &y& Elsevier]

Abstract: The advance and retreat of the polar caps were one of the first observations that indicated Mars had seasons. Because a large portion of the atmosphere is cycled in and out of the seasonal caps during the year, the frost deposits play a significant role in regional and global atmospheric circulation. Understanding the nature of the seasonal polar caps is imperative if we are to understand the current Martian climate. In this study, we track the seasonal cap edges as a function of season and longitude for the fall and winter seasons (MY27), using data from the Planetary Fourier Spectrometer (PFS) onboard the Mars Express (MEX) ESA mission. Making use of the rapid rise (decrease) in surface temperature that occurs when CO2 ice is removed (deposited), in a first approach, we defined the advancing cap edge to be where the surface temperature drops below 150K, and the retreating cap edge where the surface temperature rises above 160K. In this case, starting from Ls∼50°, the edge progression speed start to be longitude dependent. In the hemisphere that extends form the eastern limit of the Hellas basin to the western limit of the Argyrae basin (and containing the two) the edges progression speed is about a half than that of the other hemisphere; the cap is thus asymmetric and, unexpectedly, no CO2 ice seems to be present inside the basins. This is because the above mentioned surface temperatures used in this approach to detect the cap edges are not adequate (too low) for the high-pressure regions inside the basins where, following the Clausius–Clapeyron''s law, the CO2 condensation temperature can be several degrees higher than that of the adjacent lower-pressure regions. In the second, final approach, special attention has been given to this aspect and the advancing and retreating cap edges are defined where, respectively, the surface temperatures drop below and rise above the CO2 condensation temperature for the actual surface pressure values. Now, the results show an opposite situation than the previous one, with the progression speed being higher and the cap more extended (up to −30° latitude) in the hemisphere containing the two major Martian basins. During the fall season, up to Ls∼50° the South Martian polar cap consists of CO2 frost deposits that advance towards lower latitudes at a constant speed of 10° of latitude per 15 degrees of Ls. The maximum extension (−40° latitude) of the South polar cap occurs somewhere in the 80°–90° Ls range. At the winter solstice, when the edges of the polar night start moving poleward, the cap recession has already started, in response to seasonal changes in insolation. The CO2 ice South polar cap will recede with a constant speed of ∼5° of latitude every 25° degrees of Ls during the whole winter. The longitudinal asymmetries reduce during the cap retreat and completely disappear around Ls=145°. [Copyright &y& Elsevier]

Abstract: The planetary fourier spectrometer (PFS) for the Venus Express mission is an infrared spectrometer optimized for atmospheric studies. This instrument has a short wavelength (SW) channel that covers the spectral range from 1700 to 11400cm−1 (0.9–5.5μm) and a long wavelength (LW) channel that covers 250–1700cm−1 (5.5–45μm). Both channels have a uniform spectral resolution of 1.3cm−1. The instrument field of view FOV is about 1.6 ° (FWHM) for the short wavelength channel and 2.8 ° for the LW channel which corresponds to a spatial resolution of 7 and 12km when Venus is observed from an altitude of 250km. PFS can provide unique data necessary to improve our knowledge not only of the atmospheric properties but also surface properties (temperature) and the surface-atmosphere interaction (volcanic activity). PFS works primarily around the pericentre of the orbit, only occasionally observing Venus from larger distances. Each measurements takes 4.5s, with a repetition time of 11.5s. By working roughly 1.5h around pericentre, a total of 460 measurements per orbit will be acquired plus 60 for calibrations. PFS is able to take measurements at all local times, enabling the retrieval of atmospheric vertical temperature profiles on both the day and the night side. The PFS measures a host of atmospheric and surface phenomena on Venus. These include the:(1) thermal surface flux at several wavelengths near 1μm, with concurrent constraints on surface temperature and emissivity (indicative of composition); (2) the abundances of several highly-diagnostic trace molecular species; (3) atmospheric temperatures from 55 to 100km altitude; (4) cloud opacities and cloud-tracked winds in the lower-level cloud layers near 50-km altitudes; (5) cloud top pressures of the uppermost haze/cloud region near 70–80km altitude; and (6) oxygen airglow near the 100km level. All of these will be observed repeatedly during the 500-day nominal mission of Venus Express to yield an increased understanding of meteorological, dynamical, photochemical, and thermo-chemical processes in the Venus atmosphere. Additionally, PFS will search for and characterize current volcanic activity through spatial and temporal anomalies in both the surface thermal flux and the abundances of volcanic trace species in the lower atmosphere. Measurement of the 15μm CO2 band is very important. Its profile gives, by means of a complex temperature profile retrieval technique, the vertical pressure-temperature relation, basis of the global atmospheric study. PFS is made of four modules called O, E, P and S being, respectively, the interferometer and proximity electronics, the digital control unit, the power supply and the pointing device. [Copyright &y& Elsevier]

Abstract: Observations of water ice clouds and dust are among the main scientific goals of the Planetary Fourier Spectrometer (PFS), a payload instrument of the European Mars Express mission. We report some results, obtained in three orbits: 37, 41 and 68. The temperature profile, and dust and water ice cloud opacities are retrieved from the thermal infrared (long-wavelength channel of PFS) in a self-consistent way using the same spectrum. Orographic ice clouds are identified above Olympus (orbit 37) and Ascraeus Mons (orbit 68). Both volcanoes were observed near noon at Ls=337° and 342°, respectively. The effective radius of ice particles is preliminary estimated as 1–3μm, changing along the flanks. The corresponding visual opacity changes in the interval 0.2–0.4 above Olympus and 0.1–0.6 above Ascraeus Mons. In the case of Ascraeus Mons, the ice clouds were observed mainly above the Southern flank of the volcano with maximum opacity near the summit. In the case of Olympus, the clouds were found above both sides of the top. A different type of ice cloud is observed at latitudes above 50°N (orbit 68) in the polar hood: the effective particle radius is estimated to be 4μm. Below the 1mb level an inversion in the temperature profiles is found with maximum temperature at around 0.6mb. Along orbit 68 it appears above Alba Patera, then it increases to the north and decreases above the CO2 polar cap. Beginning from latitude 20°S above Tharsis (orbit 68), the ice clouds and dust contribute equally to the spectral shape. Further on, the ice clouds are found everywhere along orbit 68 up to the Northern polar cap, except the areas between the Northern flank of Ascraeus Mons (below 10km) and the edge of Alba Patera. Orbit 41 is shifted from the orbit 68 by roughly 180° longitude and passes through Hellas. Ice clouds are not visible in this orbit at latitudes below 80°S. The dust opacity is anticorrelated with the surface altitude. From 70°S to 25°N latitude the vertical dust distribution follows an exponential law with a scale height of 11.5±0.5km, which corresponds to the gaseous scale height near noon and indicates a well-mixed condition. The 9μm dust opacity, reduced to zero surface altitude, is found to be 0.25±0.05, which corresponds to a visual opacity of 0.5–0.7 (depending on the particle size). [Copyright &y& Elsevier]

Abstract: The evaluation of the planetary Fourier spectrometer performance at Mars is presented by comparing an average spectrum with the ISO spectrum published by Lellouch et al. [2000. Planet. Space Sci. 48, 1393.]. First, the average conditions of Mars atmosphere are compared, then the mixing ratios of the major gases are evaluated. Major and minor bands of CO2 are compared, from the point of view of features characteristics and bands depth. The spectral resolution is also compared using several solar lines. The result indicates that PFS radiance is valid to better than 1% in the wavenumber range 1800–4200cm−1 for the average spectrum considered (1680 measurements). The PFS monochromatic transfer function generates an overshooting on the left-hand side of strong narrow lines (solar or atmospheric). The spectral resolution of PFS is of the order of 1.3cm−1 or better. A large number of narrow features to be identified are discovered. [Copyright &y& Elsevier]

Abstract: The Planetary Fourier Spectrometer (PFS) experiment on board the Mars Express mission has two channels covering the 1.2–5μm (SWC) and the 5–50μm (LWC). The Long Wavelength Channel (LWC) measures the thermal emission spectrum of Mars between 200 and 2000cm−1 with a spectral resolution of 1.4cm−1, in absence of apodisation. We present here the calibration of this channel and its performance. The instrument calibration has been performed on ground, before launch, in space during Near Earth Verification (NEV) measurements, and at Mars. Special attention has been given to the problem of microvibrations on board the spacecraft. In order to obtain correct results, the source-instrument–detector interaction is studied very accurately. The instrument variations during a pericentre pass impose a complex procedure for the LW channel calibration, but fortunately the procedure adopted seems to work well. Samples of the calibrated data are given (as single spectrum and as an average over a few spectra) to show the performance of the experiment and its scientific potentialities. [Copyright &y& Elsevier]

Abstract: The Planetary Fourier Spectrometer (PFS) experiment on board the Mars Express mission has two channels covering the 1.2–5.5 m short wavelength channel (SWC) and the 5.5–45 m (LWC). The SWC measures part of the thermal emission spectrum and the solar reflected spectrum of Mars between 1700 and 8200cm−1 with a spectral resolution of 1.3cm−1, in absence of apodisation. We present here the calibration of this channel and its performance. The instrument calibration has been performed on ground, before launch, in space during near earth verification (NEV) measurements, and at Mars. Special attention has been given to the problem of microvibrations on board the spacecraft. In order to obtain correct results, the source–instrument–detector interaction for the thermal part is studied very accurately. The instrument shows a nonlinear behaviour with source intensity. The SNR increases with amplification, hence high gain factors are usually used. The detector is, in space, cooled by a passive radiator, and works around 210–215K. The calibration source (an internal lamp) shows variations during a pericentre pass and therefore impose a complex procedure for the SW channel calibration. Mechanical microvibrations strongly affect part of the spectrum. We discuss the validity of the present calibration, and indicate possible future developments. Samples of the calibrated data are given to show the performance of the experiment and its scientific potentialities. [Copyright &y& Elsevier]

Abstract: The Planetary Fourier Spectrometer (PFS) for the Mars Express mission is an infrared spectrometer optimised for atmospheric studies. This instrument has a short wave (SW) channel that covers the spectral range from 1700 to (1.2–) and a long-wave (LW) channel that covers 250– (5.5–). Both channels have a uniform spectral resolution of . The instrument field of view FOV is about (FWHM) for the Short Wavelength channel (SW) and (FWHM) for the Long Wavelength channel (LW) which corresponds to a spatial resolution of 7 and 12km when Mars is observed from an height of 250 km. PFS can provide unique data necessary to improve our knowledge not only of the atmosphere properties but also about mineralogical composition of the surface and the surface-atmosphere interaction. The SW channel uses a PbSe detector cooled to 200–220K while the LW channel is based on a pyroelectric () detector working at room temperature. The intensity of the interferogram is measured every 150nm of physical mirrors displacement, corresponding to 600nm optical path difference, by using a laser diode monochromatic light interferogram (a sine wave), whose zero crossings control the double pendulum motion. PFS works primarily around the pericentre of the orbit, only occasionally observing Mars from large distances. Each measurements take 4s, with a repetition time of 8.5s. By working roughly 0.6h around pericentre, a total of 330 measurements per orbit will be acquired 270 looking at Mars and 60 for calibrations. PFS is able to take measurements at all local times, facilitating the retrieval of surface temperatures and atmospheric vertical temperature profiles on both the day and the night side. [Copyright &y& Elsevier]

Abstract: The planetary fourier spectrometer (PFS) for the Mars express mission (MEX) is an infrared spectrometer operating in the wavelength range from 1.2 to 45μm by means of two spectral channels, called SWC (short wavelength channel) and LWC (long wavelength channel), covering, respectively, 1.2–5.5 and 5.5–45μm. The middle-spring Martian north polar cap (Ls∼40°) has been observed by PFS/MEX in illuminated conditions during orbit 452. The SWC spectra are here used to study the cap composition in terms of CO2 ice, H2O ice and dust content. Significant spectral variation is noted in the cap interior, and regions of varying CO2 ice grain sizes, water frost abundance, CO2 ice cover and dust contamination can be distinguished. In addition, we correlate the infrared spectra with an image acquired during the same orbit by the OMEGA imaging spectrometer and with the altimetry from MOLA data. Many of the spectra variations correlate with heterogeneities noted in the image, although significant spectral variations are not discernible in the visible. The data have been divided into five regions with different latitude ranges and strong similarities in the spectra, and then averaged. Bi-directional reflectance models have been run with the appropriate lighting geometry and used to fit the observed data, allowing for CO2 ice and H2O ice grain sizes, dust and H2O ice contaminations in the form of intimate granular mixtures and spatial mixtures. A wide annulus of dusty water ice surrounds the recessing CO2 seasonal cap. The inner cap exhibits a layered structure with a thin CO2 layer with varying concentrations of dark dust, on top of an H2O ice underneath ground. In the best-fits, the ices beneath the top layer have been considered as spatial mixtures. The results are still very good everywhere in the spectral range, except where the CO2 ice absorption coefficients are such that even a thin layer is enough to totally absorb the incoming radiation (i.e. the band is saturated). This only happens around 3800cm−1, inside the strong 2.7-μm CO2 ice absorption band. The effect of finite snow depth has been investigated through a layered albedo model. The thickness of the CO2 ice deposits increases with latitude, ranging from 0.5–1gcm−2 within region II to 60–80gcm−2 within the highest-latitude (up to 84°N) region V. Region I is at the cap edge and extends from 65°N to 72°N latitude. No CO2 ice is present in this region, which consists of relatively large grains of water ice (20μm), highly contaminated by dust (0.15wt%). The adjacent region II is a narrow region [76–79°N] right at the edge of the north residual polar cap. This region is very distinct in the OMEGA image, where it appears to surround the whole residual cap. The CO2 ice features are barely visible in these spectra, except for the strong saturated 2.7μm band. It basically consists of a thin layer of 5-mm CO2 ice on top of an H2O ice layer with the same composition as region I. A third interesting region III is found all along the shoulder of the residual cap [79–81°N]. It extends over 1.5km in altitude and over only 2° of latitude and consists of CO2 ice with a large dust content. It is an admixture of CO2 ice (3–4mm), with several tens of ppm by mass of water ice and more than 2ppt by mass of dust. The surface temperatures have been retrieved from the LWC spectra for each observation. We found an increase in the surface temperature in this region, indicating a spatial mixture of cold CO2 ice and warmer dust/H2O ice. Region IV is close to the top of the residual cap [81–84°N]; it is much brighter than region III, with a dust content 10 times lower than the latter. The CO2 grain size is 3mm and strong CO2 ice features are present in the data, indicating a thicker CO2 ice layer than in region II (1–2gcm−2). The final region V is right at the top of the residual cap (⩾84°N). It is “pure” CO2 ice (no dust) of 5mm grain sizes, with 30ppm by weight of water ice. The CO2 ice features are very pronounced and the 2.7μm band is saturated. The optical thickness is close to the semi-infinite limit (30–40gcm−2). Assuming a snowpack density of 0.5gcm−3, we get a minimum thickness of 1–2cm for the top-layer of regions II and III, 4–10cm for region IV, and ⩾60–80cm thickness for region V. These values are in close agreement with several recent results for the south seasonal polar cap. These results should provide new, useful constraints in models of the Martian climate system and volatile cycles. [Copyright &y& Elsevier]

Abstract: The Mars Express spacecraft has a highly inclined orbit around Mars and so has been able to observe the south pole of Mars in illuminated conditions at the end of the southern summer (). Spectra from the planetary Fourier spectrometer (PFS) short wavelength (SW) channel were recorded over the permanent ice cap to study its composition in terms of CO2 ice and H2O ice. Models are fitted to the observed data, which include a spatial mixture of soil (not covered by ice) and CO2 frost (with a specific grain size and a small amount of included dust and H2O ice). Two different kinds of spectra were observed: those over the permanent polar cap with almost pure CO2 ice, negligible water ice, no soil fraction required, and bright; and those over mixed terrain (at the edge of the cap or near troughs) containing a significant soil spatial fraction, more water ice and smaller CO2 grain size. The amount of water ice given by fits to scaled albedo models is less than 10ppm by weight. When using multi-stream reflectance models with the appropriate lighting geometry, the water amount must be 2–5 times greater than the albedo fit (less than 50ppm). At the periphery of the residual polar cap, we found a region almost completely covered by water frost, modeled as a mixture of micron-sized and sub-mm sized grains. Our result using a granular mixture of micron-sized grains of water ice and dust with the CO2 grains is different from the modeling of OMEGA polar cap observations using molecular mixtures. [Copyright &y& Elsevier]

The NOMAD spectrometer suite on the ExoMars Trace Gas Orbiter will map the composition and distribution of Mars׳ atmospheric trace species in unprecedented detail, fulfilling many of the scientific objectives of the joint ESA-Roscosmos ExoMars Trace Gas Orbiter mission. The instrument is a combination of three channels, covering a spectral range from the UV to the IR, and can perform solar occultation, nadir and limb observations. In this paper, we present the science objectives of the instrument and how these objectives have influenced the design of the channels. We also discuss the expected performance of the instrument in terms of coverage and detection sensitivity. [ABSTRACT FROM AUTHOR]

The Mars Express mission was launched in June 2003 and was inserted into orbit around Mars in December 2003. Its main objective is to study the Mars' subsurface, surface, atmosphere and interaction with the solar wind. A secondary objective is to study the martian moons, in particular the largest one Phobos, thanks to a near polar and elliptical orbit which allows the spacecraft to perform close flybys about every five months. The Mars Express data not only consist of high-resolution 3D color images, but also astrometric images, spectra from 0.18 to 20 μm, radar echoes, Doppler signals from gravity experiments, and ion data. A new view of the moons has emerged from this data set, favoring now the idea that they are not captured asteroids, but rather the result of a re-accretion following a major impact on Mars. This unique set of data is available in the ESA Planetary Science Archive (PSA) and mirror imaged in the NASA Planetary Data System (PDS). This paper presents an overview of the Mars Express Phobos flybys, the specificities of their operations and the scientific achievements. [ABSTRACT FROM AUTHOR]

Abstract: The origin of the Martian satellites presents a puzzle of long standing. Addressing the composition of Phobos will help constrain theories of its formation. Visible and near-infrared spectra of Phobos lack deep absorption features, making the compositional interpretation a tricky task. PFS/MEx and TES/MGS observations in the thermal infrared show several spectral features that can be used to investigate the composition of the surface. Our results show that the majority of the spectra are consistent with the presence of phyllosilicates, particularly in the area northeast of Stickney. This area corresponds to the “blue” region as defined by . Analysis of PFS and TES observations in the “red” region defined by are consistent with tectosilicates, especially feldspars/feldspathoids. We discuss several physical and chemical mechanisms that can act to eliminate or reduce the strength of bands in the VIS/NIR spectra, with possibly little or no effect in the mid-IR. Comparison of the TES and PFS data to the meteorites shows that no class of chondritic meteorites provide significant agreement with the spectral features observed. The lack of consistency of the PFS and TES spectra to analogs of ultraprimitive materials (organic residues) suggests that an origin via capture of a transneptunian object is not supported by these observations, although it cannot be completely ruled out. Derived surface temperatures from PFS and TES data are in very good agreement with brightness temperatures derived from Viking orbiter measurements, Earth-based observations, and values predicted by numerical models. Our results show that the surface temperature of Phobos varies with solar incidence angle and heliocentric distance, reconciling the different results. We collect and summarize the compositional clues for the origin of Phobos discussed in this paper, including our results. Currently, the most likely scenario is the in-situ formation of Phobos, although a capture of achrondrite-like meteorites is not ruled out. [Copyright &y& Elsevier]

Abstract: The MIPAS instrument on board Envisat, in Earth orbit, the PFS and OMEGA instruments on Mars Express, and VIRTIS on board Venus Express are currently providing a dataset of limb measurements of the CO2 atmospheric fluorescence emission at from the upper atmosphere of the three planets. These measurements represent an excellent dataset to perform comparative studies between the terrestrial planets’ upper atmospheres, and also to test our theoretical understanding of these emissions. In order to exploit these datasets, we apply a set of non-local thermodynamic equilibrium (non-LTE) models developed at the IAA/CSIC, in Granada, Spain, to a selection of data. In general, the models can explain the main spectral features of the measurements, and also the altitude and solar zenith angle variations. However, the simulations for Mars and Venus give an incorrect ratio of the emissions at two wavelengths, 4.4 and . In order to explain this deficiency, a revision of the most uncertain non-LTE energy transfer parameters has been performed. The quenching rate of quanta of high-energy CO2 states by CO2 itself could reduce the model-data discrepancy if increased by a factor 2–4, still within its current uncertainty range. This factor, however, is subject to the uncertainty in the thermal structure. A number of simulations with the non-LTE models were also used to study and compare the role of radiative transfer in this spectral region in the three terrestrial planets. Sensitivity studies of density and temperature are also presented, and they permit an analysis of how the differences between the planets and between the three instruments affect their sounding capabilities. [Copyright &y& Elsevier]

Abstract: We report here on CO limb observations in Mars, Venus and Earth and their model simulations. A comparative study of the CO emission, including the most recent spacecraft observations of the three planets’ atmospheres, has been performed. Strong daytime emissions near have been recently observed in the limb of the upper atmosphere of the three terrestrial planets by the Planetary Fourier Spectrometer on Mars Express (), the Visible and Infrared Thermal Imaging Spectrometer on Venus Express (), and the Michelson Interferometer for Passive Atmosphere Sounding on Envisat (). Those emissions are produced by solar pumping of molecular vibrations and non-local thermodynamic equilibrium (non-LTE) models are used to explain them in a consistent framework for the three atmospheres. The maximum of the emission occurs on Venus between 90 and 110km, on Mars above 60km, and on Earth around 68km. The observations show that the fundamental band dominates the CO non-LTE emission on Earth, while on Venus and Mars the larger contribution comes from the first hot band transition. The main goal of this study is to understand those differences and similarities with the help of theoretical simulations with optical thickness considerations, and compare the capability of space instrumentation for the remote sounding of the atmospheres in this spectral region. [Copyright &y& Elsevier]

Abstract: We have analyzed spectra of CO recorded with the instrument PFS onboard Mars Express in the (1–0) band. The dataset we used ranges in time from January until June 2004 ( until ; end of Mars Year 26, beginning of Mars Year 27). The aim of this work was to determine the amplitude of the CO mixing ratio departures from the mean globally averaged value currently admitted () [Kaplan, L.D., Connes, J., Connes, P., 1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187–L192] as a function of season, local time and location on the planet. We therefore processed the data from 90 calibrated orbits. The globally averaged CO mixing ratio value we derive from our dataset, , is compatible with the range found by Kaplan et al. [1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187–L192], although somewhat higher than the “standard” value. However, the CO mixing ratio we retrieve exhibits large variations (roughly between and ). Such relative variations have been used on a statistical basis to derive main trends as a function of latitude for three ranges: –, 0– and 30–. For the first range, we seem to have an enhancement of the CO mixing ratio towards the northern latitudes, probably linked to the condensation in winter on the north polar cap. The situation for the two other ranges is not so clear, mainly as we lack data on the southern hemisphere. We roughly agree with the work of Krasnopolsky [2007. Long-term spectroscopic observations of Mars using IRTF/CSHELL: mapping of O2 dayglow, CO and search for CH4. Icarus 190, 93–102] for –, thus confirming the effect of seasonal condensation of on the north polar cap, but we have no agreement for other seasons. [Copyright &y& Elsevier]

Abstract: The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA/Venus Express mission has technical specifications well suited for many science objectives of Venus exploration. VIRTIS will both comprehensively explore a plethora of atmospheric properties and processes and map optical properties of the surface through its three channels, VIRTIS-M-vis (imaging spectrometer in the 0.3–1μm range), VIRTIS-M-IR (imaging spectrometer in the 1–5μm range) and VIRTIS-H (aperture high-resolution spectrometer in the 2–5μm range). The atmospheric composition below the clouds will be repeatedly measured in the night side infrared windows over a wide range of latitudes and longitudes, thereby providing information on Venus''s chemical cycles. In particular, CO, H2O, OCS and SO2 can be studied. The cloud structure will be repeatedly mapped from the brightness contrasts in the near-infrared night side windows, providing new insights into Venusian meteorology. The global circulation and local dynamics of Venus will be extensively studied from infrared and visible spectral images. The thermal structure above the clouds will be retrieved in the night side using the 4.3μm fundamental band of CO2. The surface of Venus is detectable in the short-wave infrared windows on the night side at 1.01, 1.10 and 1.18μm, providing constraints on surface properties and the extent of active volcanism. Many more tentative studies are also possible, such as lightning detection, the composition of volcanic emissions, and mesospheric wave propagation. [Copyright &y& Elsevier]

Abstract: Venus Express is the first European mission to planet Venus. The mission aims at a comprehensive investigation of Venus atmosphere and plasma environment and will address some important aspects of the surface physics from orbit. In particular, Venus Express will focus on the structure, composition, and dynamics of the Venus atmosphere, escape processes and interaction of the atmosphere with the solar wind and so to provide answers to the many questions that still remain unanswered in these fields. Venus Express will enable a breakthrough in Venus science after a long period of silence since the period of intense exploration in the 1970s and the 1980s. The payload consists of seven instruments. Five of them were inherited from the Mars Express and Rosetta projects while two instruments were designed and built specifically for Venus Express. The suite of spectrometers and imaging instruments, together with the radio-science experiment, and the plasma package make up an optimised payload well capable of addressing the mission goals to sufficient depth. Several of the instruments will make specific use of the spectral windows at infrared wavelengths in order to study the atmosphere in three dimensions. The spacecraft is based on the Mars Express design with minor modifications mainly needed to cope with the thermal environment around Venus, and so a very cost-effective mission has been realised in an exceptionally short time. The spacecraft was launched on 9 November 2005 from Baikonur, Kazakhstan, by a Russian Soyuz-Fregat launcher and arrived at Venus on 11 April 2006. Venus Express will carry out observations of the planet from a highly elliptic polar orbit with a 24-h period. In 3 Earth years (4 Venus sidereal days) of operations, it will return about 2Tbit of scientific data. Telecommunications with the Earth is performed by the new ESA ground station in Cebreros, Spain, while a nearly identical ground station in New Norcia, Australia, supports the radio-science investigations. [Copyright &y& Elsevier]

Abstract: The Visual and Infrared Mapping Spectrometer (VIMS) instrument on the Cassini Saturn Orbiter returned spectral imaging data as the spacecraft undertook six close encounters with Titan beginning 7 July, 2004. Three of these flybys each produced overlapping coverage of two distinct regions of Titan''s surface. Twenty-four points were selected on approximately opposite hemispheres to serve as photometric controls. Six points were selected in each of four reflectance classes. On one hemisphere each control point was observed at three distinct phase angles. From the derived phase coefficients, preliminary normal reflectances were derived for each reflectance class. The normal reflectance of Titan''s surface units at 2.0178μm ranged from 0.079 to 0.185 for the most absorbing to the most reflective units assuming no contribution from absorbing haze. When a modest haze contribution of τ =0.1 is considered these numbers increase to 0.089–0.215. We find that the lowest three reflectance classes have comparable normal reflectance on either hemisphere. However, for the highest brightness class the normal reflectance is higher on the hemisphere encompassing longitude 14–65° compared to the same high brightness class for the hemisphere encompassing 122–156° longitude. We conclude that an albedo dichotomy observed in continental sized units on Titan is due not only to one unit having more areal coverage of reflective material than the other but the material on the brighter unit is intrinsically more reflective than the most reflective material on the other unit. This suggests that surface renewal processes are more widespread on Titan''s more reflective units than on its less reflective units. We note that one of our photometric control points has increased in reflectance by 12% relative to the surrounding terrain from July of 2004 to April and May of 2005. Possible causes of this effect include atmospheric processes such as ground fog or orographic clouds; the suggestion of active volcanism cannot be ruled out. Several interesting circular features which resembled impact craters were identified on Titan''s surface at the time of the initial Titan flyby in July of 2004. We traced photometric profiles through two of these candidate craters and attempted to fit these profiles to the photometric properties expected from model depressions. We find that the best-fit attempt to model these features as craters requires that they be unrealistically deep, approximately 70km deep. We conclude that despite their appearance, these circular features are not craters, however, the possibility that they are palimpsests cannot be ruled out. We used two methods to test for the presence of vast expanses of liquids on Titan''s surface that had been suggested to resemble oceans. Specular reflection of sunlight would be indicative of widespread liquids on the surface; we found no evidence of this. A large liquid body should also show uniformity in photometric profile; we found the profiles to be highly variable. The lack of specular reflection and the high photometric variability in the profiles across candidate oceans is inconsistent with the presence of vast expanses of flat-lying liquids on Titan''s surface. While liquid accumulation may be present as small, sub-pixel-sized bodies, or in areas of the surface which still remain to be observed by VIMS, the presence of large ocean-sized accumulations of liquids can be ruled out. The Cassini orbital tour offers the opportunity for VIMS to image the same parts of Titan''s surface repeatedly at many different illumination and observation geometries. This creates the possibility of understanding the properties of Titan''s atmosphere and haze by iteratively adapting models to create a best fit to the surface reflectance properties. [Copyright &y& Elsevier]

Abstract: Titan''s bulk density along with Solar System formation models indicates considerable water as well as silicates as its major constituents. This satellite''s dense atmosphere of nitrogen with methane is unique. Deposits or even oceans of organic compounds have been suggested to exist on Titan''s solid surface due to UV-induced photochemistry in the atmosphere. Thus, the composition of the surface is a major piece of evidence needed to determine Titan''s history. However, studies of the surface are hindered by the thick, absorbing, hazy and in some places cloudy atmosphere. Ground-based telescope investigations of the integral disk of Titan attempted to observe the surface albedo in spectral windows between methane absorptions by calculating and removing the haze effects. Their results were reported to be consistent with water ice on the surface that is contaminated with a small amount of dark material, perhaps organic material like tholin. We analyze here the recent Cassini Mission''s visual and infrared mapping spectrometer (VIMS) observations that resolve regions on Titan. VIMS is able to see surface features and shows that there are spectral and therefore likely compositional units. By several methods, spectral albedo estimates within methane absorption windows between 0.75 and 5μm were obtained for different surface units using VIMS image cubes from the Cassini-Huygens Titan Ta encounter. Of the spots studied, there appears to be two compositional classes present that are associated with the lower albedo and the higher albedo materials, with some variety among the brighter regions. These were compared with spectra of several different candidate materials. Our results show that the spectrum of water ice contaminated with a darker material matches the reflectance of the lower albedo Titan regions if the spectral slope from 2.71 to 2.79μm in the poorly understood 2.8-μm methane window is ignored. The spectra for brighter regions are not matched by the spectrum of water ice or unoxidized tholin, in pure form or in mixtures with sufficient ice or tholin present to allow the water ice or tholin spectral features to be discerned. We find that the 2.8-μm methane absorption window is complex and seems to consist of two weak subwindows at 2.7 and 2.8μm that have unknown opacities. A ratio image at these two wavelengths reveals an anomalous region on Titan that has a reflectance unlike any material so far identified, but it is unclear how much the reflectances in these two subwindows pertain to the surface. [Copyright &y& Elsevier]

Abstract: Venus Express is the first European mission to the planet Venus. Its payload consists of seven instruments and will investigate the atmosphere, the plasma environment, and the surface of Venus from orbit. Science planning is a complex process that takes into account requests from all experiments and the operational constraints. The planning of the science operations is based on synergetic approach to provide good coverage of science themes derived from the main mission goals. Typical observations in a single orbit—so-called “science cases” are used to build the mission science activity plan. The nominal science mission (from June 4, 2006 till October 2, 2007) is divided in nine phases depending on observational conditions, occurrences of the solar and Earth occultation, and particular science goals. The observation timelines for each phase were developed in a coordinated way to optimize the payload activity, maximize the overall mission science return, and to fit into the available mission budgets. [Copyright &y& Elsevier]

Abstract: The Visual Infrared Mapping Spectrometer (VIMS) onboard the CASSINI spacecraft obtained new spectral data of the icy satellites of Saturn after its arrival at Saturn in June 2004. VIMS operates in a spectral range from 0.35 to 5.2μm, generating image cubes in which each pixel represents a spectrum consisting of 352 contiguous wavebands. As an imaging spectrometer VIMS combines the characteristics of both a spectrometer and an imaging instrument. This makes it possible to analyze the spectrum of each pixel separately and to map the spectral characteristics spatially, which is important to study the relationships between spectral information and geological and geomorphologic surface features. The spatial analysis of the spectral data requires the determination of the exact geographic position of each pixel on the specific surface and that all 352 spectral elements of each pixel show the same region of the target. We developed a method to reproject each pixel geometrically and to convert the spectral data into map projected image cubes. This method can also be applied to mosaic different VIMS observations. Based on these mosaics, maps of the spectral properties for each Saturnian satellite can be derived and attributed to geographic positions as well as to geological and geomorphologic surface features. These map-projected mosaics are the basis for all further investigations. [Copyright &y& Elsevier]

Abstract: Daytime nadir spectra of the Martian atmosphere taken by the planetary Fourier spectrometer/Mars Express (PFS) and by the infrared space observatory (ISO) in the region are analyzed using a theoretical non-LTE model of the infrared emissions in that atmosphere. Averaged spectra from these instruments show a double peak structure which can be explained by the strong solar pumping at of the () and () vibrational states of the major isotope. After the initial absorption, these states relax radiatively by emission in the second hot bands, whose R- and P-branches produce such structure. It is shown that an LTE atmosphere could not produce such structure. A good fit to the measured spectra is obtained, particularly with PFS, using the currently assumed non-LTE parameters without special adjustments. Analysis of individual bands contributions, their dependence with the thermal structure and solar zenith angle, and the simulation of the altitude variation of the different non-LTE features are presented and discussed. These results confirm the prediction of the non-LTE model and have allowed to identify the main spectral features observed in PFS and ISO data. The dominant double maxima are due to the second hot bands while the individual lines come from the fundamental band. Also the Q-branch of the first hot band and the absence of emission lines in the center of the fundamental band in the PFS spectrum are well reproduced by the simulations. [Copyright &y& Elsevier]

Abstract: This work reports the first observations of the Martian atmosphere returned by the planetary Fourier spectrometer (PFS) on board of Mars express (MEX) satellite in the vicinity of the greatest volcanic domes of the planet. Two of the early MEX orbits have already covered the region of Olympus Mons and Ascraeus Mons. These measurements are very similar in terms of local time (14LT) and season ( and 342, respectively). The long wavelength channel (LWC) of the instrument works in the thermal IR (300–1500cm−1); its data allow the simultaneous retrieval of surface temperature, integrated content of water ice and dust suspended in the atmosphere and air thermal field up to an altitude of about 50km. Results of the code described in the companion paper by Grassi et al. for the two orbits are presented and compared with the state expected by the European Martian climate dataset v3.1. The parent global circulation model LMD-Oxford-AAS is able to take into account a wide number of physical phenomena, but the results included in EMCD are affected by a relatively coarse spatial resolution, that does not properly describe the great volcanic domes. The comparison demonstrated that observed data follow quite strictly the trends foreseen by the model in low altitude regions, while the behavior shows remarkable differences above the relief, where orography likely plays an important role. Namely, extended mid-altitude minima in air temperature fields above the summit of volcanic domes are observed. The integrated content of dust shows a minima above Olympus, as expected for a dust particle concentration that decays with height. Measurements are consistent with an exponential decay characterized by a scale height of ∼10km. Consistently, the surface temperature presents a maxima over the dome, as expected for conditions of clearer sky. Water ice clouds are clearly detected around Ascreus Mons, with a strong asymmetry in latitude. Further comparison with the results of the thermal emission spectrometer (TES) on board of Mars global surveyor (MGS) is also provided, partially supporting our observations of air temperature fields. Possible explanation of these trends is represented by thermal circulation, driven by air heating close to the surface. If confirmed by future observations, these data can represent important constraint by PFS data to mesospheric simulation, with possible implications on the Global Circulation Models. [Copyright &y& Elsevier]

Abstract: This work presents an algorithm for the scientific analysis of individual calibrated measurements from the Planetary Fourier spectrometer (PFS). The instrument, included in the scientific payload of the ESA Mars Express mission to Mars, acquires spectra in the range between 250 and 8200cm−1, with a sampling step of ∼1cm−1 and an effective resolution of ∼2cm−1. The observed radiance depends on several parameters of the atmosphere and surface of Mars as described by the radiative transfer equation. Adopting the very general formalism of Bayesian analysis, we determined which quantities are actually retrievable from individual measurements. Namely, they are: the surface temperature, the column density of dust and water ice aerosols in the atmosphere, the air temperature as a function of altitude (in the indicative range 5–45km above the surface), the surface pressure, and the column density of water vapor and carbon monoxide. These evaluations are carried out taking into account the noise equivalent radiance (NER) of the instrument and the natural variabilities of the investigated parameters in the Martian environment, as estimated from the expectations of the European Martian Climate Dataset v3.1 (EMCD). Other parameters included in the radiative transfer equation shall be assumed as known, because they are not retrievable from individual measurements due to the instrumental NER or an underconstrained inverse problem: the surface emissivity in the thermal infrared, the optical properties of suspended dust and the analytical shape of dust concentration vs. altitude. During the development of the algorithm devoted to these studies, different approaches were evaluated on the basis of formal, computational and scientific considerations, with the aim to develop the general design of an integrated software package. The resulting code was extensively tested on a wide set of simulated PFS spectra. These spectra were computed from the atmospheric and surface conditions extracted from the EMCD, assumed to be representative of the Martian environment for different values of latitude, local time and season. Their comparison with the retrievals from simulated observations allowed us to evaluate the systematic and random errors affecting the procedures with respect to the different quantities involved. The code evaluates the surface temperature with an error in the order of 1K, while the vertical air temperature profile is computed with an uncertainty less than 2K from in the region between 5 and 20km above the surface, increasing up to 7K at 50km. The column opacity of dust, measured in terms of integrated optical thickness at 1100cm−1, is computed with an error of around 0.13. The surface pressure determination is carried out with a typical uncertainty of 0.2–0.3millibar. Several auxiliary tests allowed us to study the correlations between the different retrieval errors and the possible causes of incorrect PFS data interpretation. The choice of a suitable model for the dust optical properties is demonstrated to be particularly critical. This paper also presents the first discussion about application of the procedure to actual PFS Martian data. Despite the calibration issues still affecting the determination of absolute radiance in the near-infrared, the algorithm is able to achieve a satisfactory modeling of observations in a wide range of situations. [Copyright &y& Elsevier]