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Bismuth ferrite (BiFeO 3 ), one of the most prominent members of multiferroics, has multiple promising characteristics useful for multifunctional applications. Multi-doped (Cd, Ti) complex bismuth ferrite [i.e., Bi(Cd 1/4 Ti 1/4 Fe 1/2 )O 3 ] ceramic was synthesized through a mixed-oxide route. X-ray structural analysis of the prepared material provides its basic crystal data of a single-phase orthorhombic system. The scattered crystallite size and lattice strain of the material were estimated using Scherrer and Williamson–Hall approaches respectively using X-ray diffraction peaks. Analysis of the micrograph of field emission scanning electron microscope shows uniform and densely packed grains on the surfaces of the pellet sample suggesting the formation of good quality and high-density sample. A significant effect of substitution of multiple elements at the Fe-site on dielectric constant and tangent loss of BiFeO 3 has been observed. Detailed studies of temperature (25–500 °C) and frequency (1–1000 kHz) dependence of impedance and ac-conductivity have provided the effect of grains and grain boundaries on the conduction mechanism and dielectric relaxation of the material. Based on the magnetic measurements, it is concluded that (Cd, Ti) modified bismuth ferrite has provided saturation magnetisation (M s ) and coercivity (H c ) of 2.66 emu g −1 and 653.75 Oe respectively which are consistent with those of many compounds of similar type. [ABSTRACT FROM AUTHOR]