1. Island Ripening via a Polymerization-Depolymerization Mechanism
- Author
-
Andrea Locatelli, Alessandro Sala, Martin Hesse, Ronald Imbihl, Tevfik Onur Menteş, and Bernhard von Boehn
- Subjects
Coalescence (physics) ,Crystallography ,chemistry.chemical_compound ,Low-energy electron microscopy ,Materials science ,chemistry ,Polymerization ,Depolymerization ,Monolayer ,General Physics and Astronomy ,Methanol ,Vanadium oxide ,Catalysis - Abstract
In catalytic methanol oxidation on ultrathin vanadium oxide layers on Rh(111) (Θ_{V}≈0.2 monolayer equivalent) we observe a 2D ripening of the VO_{x} islands that is controlled by the catalytic reaction. Neighboring VO_{x} islands move under reaction conditions towards each other and coalesce. The motion and the coalescence of the islands are explained by a polymerization-depolymerization equilibrium that is sensitive to gradients in the adsorbate coverages.
- Published
- 2015