1. Breakdown of Magnetic Order in the Pressurized Kitaev Iridate β−Li2IrO3
- Author
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M. Majumder, Philipp Gegenwart, F. Freund, Pabitra Kumar Biswas, Satoshi Nishimoto, Liviu Hozoi, T. Dey, Alexander A. Tsirlin, Ravi Yadav, Anton Jesche, Rudra Sekhar Manna, Leonid Dubrovinsky, J. C. Orain, Natalia Dubrovinskaia, Rustem Khasanov, Elena Bykova, and Gediminas Simutis
- Subjects
Materials science ,Condensed matter physics ,Spins ,General Physics and Astronomy ,Magnetostriction ,02 engineering and technology ,Muon spin spectroscopy ,021001 nanoscience & nanotechnology ,01 natural sciences ,Magnetization ,0103 physical sciences ,Condensed Matter::Strongly Correlated Electrons ,Quantum spin liquid ,010306 general physics ,0210 nano-technology ,Ground state ,Néel temperature ,Phase diagram - Abstract
Temperature-pressure phase diagram of the Kitaev hyperhoneycomb iridate β-Li_{2}IrO_{3} is explored using magnetization, thermal expansion, magnetostriction, and muon spin rotation measurements, as well as single-crystal x-ray diffraction under pressure and ab initio calculations. The Neel temperature of β-Li_{2}IrO_{3} increases with the slope of 0.9 K/GPa upon initial compression, but the reduction in the polarization field H_{c} reflects a growing instability of the incommensurate order. At 1.4 GPa, the ordered state breaks down upon a first-order transition, giving way to a new ground state marked by the coexistence of dynamically correlated and frozen spins. This partial freezing in the absence of any conspicuous structural defects may indicate the classical nature of the resulting pressure-induced spin liquid, an observation paralleled to the increase in the nearest-neighbor off-diagonal exchange Γ under pressure.
- Published
- 2018