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We present a method to measure the decay rate of the first excited vibrational state of polar molecular ions that are part of a Coulomb crystal in a cryogenic linear Paul trap. Specifically, we have monitored the decay of the ∣ν=1,J=1⟩X towards the ∣ν=0,J=0⟩X level in MgH+ by saturated laser excitation of the ∣ν=0,J=2⟩X-∣ν=1,J=1⟩X transition followed by state selective resonance enhanced two-photon dissociation out of the ∣ν=0,J=2⟩X level. The experimentally observed rate of 6.32(0.69)  s-1 is in excellent agreement with the theory value of 6.13(0.03)  s-1 (this Letter). The technique enables the determination of decay rates, and thus absorption strengths, with an accuracy at the few percent level. [ABSTRACT FROM AUTHOR]

We explore the interaction between two trapped ions mediated by a surrounding quantum degenerate Bose or Fermi gas. Using perturbation theory valid for weak atom-ion interaction, we show analytically that the interaction mediated by a Bose gas has a power-law behavior for large distances whereas it has a Yukawa form for intermediate distances. For a Fermi gas, the mediated interaction is given by a power law for large density and by a Ruderman-Kittel-Kasuya-Yosida form for low density. For strong atom-ion interaction, we use a diagrammatic theory to demonstrate that the mediated interaction can be a significant addition to the bare Coulomb interaction between the ions, when an atom-ion bound state is close to threshold. Finally, we show that the induced interaction leads to substantial and observable shifts in the ion phonon frequencies.

We perform high-resolution spectroscopy of the 3d ^{2}D_{3/2}-3d ^{2}D_{5/2} interval in all stable even isotopes of ^{A}Ca^{+} (A=40, 42, 44, 46, and 48) with an accuracy of ∼20  Hz using direct frequency-comb Raman spectroscopy. Combining these data with isotope shift measurements of the 4s ^{2}S_{1/2}↔3d ^{2}D_{5/2} transition, we carry out a King plot analysis with unprecedented sensitivity to coupling between electrons and neutrons by bosons beyond the standard model. Furthermore, we estimate the sensitivity to such bosons from equivalent spectroscopy in Ba^{+} and Yb^{+}. Finally, the data yield isotope shifts of the 4s ^{2}S_{1/2}↔3d ^{2}D_{3/2} transition at 10 parts per billion through combination with recent data of Knollmann, Patel, and Doret [Phys. Rev. A 100, 022514 (2019)PLRAAN2469-992610.1103/PhysRevA.100.022514].

A highly efficient method for optical or microwave detection and separation of left- and right-handed chiral molecules is proposed. The method utilizes a closed-loop three-state system in which the population dynamics depends on the phases of the three couplings. Because of the different signs of the coupling between two of the states for the opposite chiralities the population dynamics is chirality dependent. By using the "shortcuts to adiabaticity" concept applied to the stimulated Raman adiabatic passage technique, one can achieve 100% contrast between the two enantiomers in the population of a particular state. It can be probed by light-induced fluorescence for large ensembles or through resonantly enhanced multiphoton ionization for single molecules.

We report one-dimensional pinning of a single ion by an optical lattice. A standing-wave cavity produces the lattice potential along the rf-field-free axis of a linear Paul trap. The ion's localization is detected by measuring its fluorescence when excited by standing-wave fields with the same period, but different spatial phases. The experiments agree with an analytical model of the localization process, which we test against numerical simulations. For the best localization achieved, the ion's average coupling to the cavity field is enhanced from 50% to 81(3)% of its maximum possible value, and we infer that the ion is bound in a lattice well with over 97% probability.

Isotope effects in reactions between Mg+ in the 3p{2}P{3/2} excited state and molecular hydrogen at thermal energies are studied through single reaction events. From only approximately 250 reactions with HD, the branching ratio between formation of MgD+ and MgH+ is found to be larger than 5. From an additional 65 reactions with H2 and D2 we find that the overall fragmentation probability of the intermediate MgH2+, MgHD+, or MgD2+ complexes is the same. Our study shows that few single ion reactions can provide quantitative information on ion-neutral reactions. Hence, the method is well suited for reaction studies involving rare species, e.g., rare isotopes or short-lived unstable elements.

A structural transition for laser cooled ion Coulomb crystals in a linear Paul trap just above the stability limit of parametrically resonant excitation of bulk plasma modes has been observed. In contrast to the usual spheroidal shell structures present below the stability limit, the ions arrange in a "string-of-disks" configuration. The spheroidal envelopes of the string-of-disks structures are in agreement with results from cold fluid theory usually valid for ion Coulomb crystals if the ion systems are assumed to be rotating collectively.

We report on structural properties of two-component Coulomb crystals in a linear Paul trap. The crystals consist of two laser cooled ion species, 24Mg+ and 40Ca+. The lighter 24Mg+ ions form an inner cylindrical crystal structure surprisingly similar to that of an infinitely long single component crystal, while the outermost shell of the surrounding 40Ca+ ions have a spheroidal shape, which is highly insensitive to the presence of the 24Mg+ ions. Observed changes in the radial separation of the two ion species with the radius of the inner cylindrical crystal is explained by a simple model.