1. Enhanced electron correlations at theSrxCa1−xVO3surface
- Author
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Bo Chen, Joseph C. Woicik, Kevin E. Smith, Ravi Pratap Singh, Jude Laverock, B. A. Karlin, Geetha Balakrishnan, and Jithesh Kuyyalil
- Subjects
Materials science ,Photoemission spectroscopy ,Binding energy ,Fermi level ,Photoionization ,Electronic structure ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,symbols.namesake ,Ab initio quantum chemistry methods ,Content (measure theory) ,symbols ,Strongly correlated material ,Atomic physics - Abstract
We report hard x-ray photoemission spectroscopy measurements of the electronic structure of the prototypical correlated oxide ${\mathrm{Sr}}_{x}{\mathrm{Ca}}_{1\ensuremath{-}x}{\mathrm{VO}}_{3}$. By comparing spectra recorded at different excitation energies, we show that 2.2 keV photoelectrons contain a substantial surface component, whereas 4.2 keV photoelectrons originate essentially from the bulk of the sample. Bulk-sensitive measurements of the O $2p$ valence band are found to be in good agreement with ab initio calculations of the electronic structure, with some modest adjustments to the orbital-dependent photoionization cross sections. The evolution of the O $2p$ electronic structure as a function of the Sr content is dominated by $A$-site hybridization. Near the Fermi level, the correlated V $3d$ Hubbard bands are found to evolve in both binding energy and spectral weight as a function of distance from the vacuum interface, revealing higher correlation at the surface than in the bulk.
- Published
- 2015
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