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Herein, the high temperature stack oxidation (HiTSOx) approach for the fabrication of passivated emitter and rear cells (PERCs) is investigated. This approach features a combination of phosphorus oxychloride (POCl3) diffusion shortened to the phosphosilicate glass (PSG) deposition phase as well as high temperature thermal oxidation using stacked wafers. During the latter thermal oxidation, the incorporated phosphorus is redistributed and diffuses deeper into the silicon wafer. The simultaneously growing thermal dioxide serves as a passivation layer. Due to the use of stacked wafers, the throughput of the HiTSOx approach is three times higher in comparison to state‐of‐the‐art oxidation at moderate temperature. Applying a busbarless metallization layout, a median energy conversion efficiency of η= 22.2% is achieved for the HiTSOx approach, being similar to the performance of the reference group with state‐of‐the‐art PERC processing also with η= 22.2%. Despite stacking of the wafers during the thermal oxidation, an excellent homogeneity of the oxide layer thickness of ±1 nm over the wafer surface is found, whereas the passivation quality features dark saturation current densities j0eas low as j0e= (30 ± 3) fA cm−2at emitter sheet resistances Rsh= (199 ± 6) Ω sq−1. Herein, an approach that uses a shortened phosphorus oxychloride (POCl3) diffusion and subsequent thermal oxidation with wafer stacks enabling higher throughput is shown. For the first time, this approach is introduced into manufacturing for passivated emitter and rear cell (PERC) solar cells and is characterized in terms of cell efficiency. Further, oxide growth, doping profiles, and emitter recombination are characterized.