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A proof-of-concept gas sensor based on a miniaturized and integrated fiber-optic photoacoustic detection module was introduced and demonstrated for the purpose of developing a custom tuning-fork (TF)-enhanced photoacoustic gas sensor. Instead of piezoelectric quartz tuning fork (QTF) in conventional quartz-enhanced photoacoustic spectroscopy (QEPAS), a low-cost custom aluminum alloy TF fabricated by mechanical processing was employed as a photoacoustic transducer and the vibration of TF was measured by fiber-optic Fabry-Pérot (FP) interferometer (FPI). The mechanical processing-based TF design scheme greatly increases the flexibility of the TF design with respect to the complex and expensive manufacture process of custom QTFs, and thus it can be better exploited to detect gases with slow vibrational-translational (V-T) relaxation rates and combine with light sources with poor beam quality. The resonance frequency and the quality factor of the designed custom TF at atmospheric pressure were experimentally determined to be 7.3 kHz and 4733, respectively. Dual-prong differential measurement method was proposed to double the photoacoustic signal and suppress the external same-direction noise. After detailed optimizing and investigating for the operating parameters by measuring H2O, the feasibility of the developed sensor for gas detection was demonstrated with a H2O minimum detection limit (MDL) of 1.2 ppm, corresponding to a normalized noise equivalent absorption (NNEA) coefficient of 3.8 × 10−8 cm−1 W/Hz1/2, which are better than the QTF-based photoacoustic sensors. The proposed gas sensing approach combined the advantages of QEPAS and fiber-optic sensing, which can greatly expand the application domains of PAS-based gas sensors.

In this paper, we propose and experimentally demonstrate a symmetric multi-resonant cavity photoacoustic cell (MR-PAC) with dual microphones detection, based on multi-resonator photoacoustic spectroscopy (MR-PAS). The designed photoacoustic cell contains three interconnected acoustic resonators to facilitate simultaneous control of three lasers for multi-gas sensing. Two microphones are symmetrically located at both sides of photoacoustic cell to implement two-point detection. The length of acoustic resonator is about 50 mm to minimize the photoacoustic cell, and the resonant frequency is around 3000 Hz. Feasibility and performance of the MR-PAC was demonstrated by simultaneous detection of C2H2, NO and CF4 using a near infrared diode laser and two mid infrared quantum cascade lasers. The minimum detection limits (MDLs) of C2H2, NO and CF4 are 480 ppb, 260 ppb and 0.57 ppb respectively with a 1 s integration time at normal atmospheric pressure. This minimized MR-PAS system is promising for the portable multi-gas sensing.

A small-volume highly-sensitive photoacoustic spectroscopy (PAS) methane detection system based on differential silicon cantilever optical microphones (SCOMs) is proposed and experimentally demonstrated. The system contains a compact non-resonant photoacoustic cell with a small volume of 1.2 mL and symmetrically-located dual SCOMs, as well as a distributed feedback laser at 1650.96 nm. The two identical SCOMs utilize the Fabry-Perot interferometric fiber-optic structure, with the differential Q-point demodulation algorithm to suppress the external vibration noise. Experimental results show that the SCOM has a high displacement sensitivity about 7.1 µm/Pa at 150 Hz and within 2.5 dB fluctuation between 5 Hz and 250 Hz. In the PAS gas sensing experiment, the normalized noise equivalent absorption coefficient of the PAS system is estimated to be 1.2 × 10−9 cm−1·W·Hz−1/2 and the minimum detection limit for methane is about 111.2 ppb with 1 s integration time. External disturbance is also applied to the dual SCOM system and results show excellent stability and noise resistance. The proposed PAS system exhibits superiorities of low gas consumption, high sensitivity and immunity to vibration and electromagnetic interference, which has an enormous potential in medicine, industry and environment.

All-optical light-induced thermoacoustic spectroscopy (AO-LITS) is reported for the first time for highly sensitive and selective gas sensing, in which a commercial standard quartz tuning fork (QTF) is employed as a photothermal detector. The vibration of the QTF was measured by the highly sensitive fiber-optic Fabry-Pérot (FP) interferometry (FPI) technique, instead of the piezoelectric detection in the conventional LITS. To improve the stability of the sensor system, a compact QTF-based fiber-optic FPI module is fabricated by 3D printing technique and a dual-wavelength demodulation method with the ellipse-fitting differential-cross-multiplication algorithm (DW-EF-DCM) is exploited for the FPI measurement. The all-optical detection scheme has the advantages of remote detection and immunity to electromagnetic interference. A minimum detection limit (MDL) of 422 ppb was achieved for hydrogen sulfide (H2S), which was ~ 3 times lower than a conventional electrical LITS sensor system. The AO-LITS can provide a promising approach for remote and non-contact gas sensing in the whole infrared spectral region.

In this paper, we propose and experimentally demonstrate an ultra-sensitive all-optical PAS gas sensor, incorporating with a near-infrared (NIR) diode laser, fiber-optic microphones (FOMs) and a double channel differential T-type photoacoustic cell. The FOM is realized by Fabry-Perot interferometry and novel gold-chromium (Au-Cr) composite nanomembranes. To meet the demand of high sensitivity and flat frequency response for the FOMs, the Au-Cr composite diaphragm is deliberately designed and fabricated by E-beam evaporation deposition with 330 nm in thickness and 6.35 mm in radius. Experimental results show that the FOM has a sensitivity of about 30 V/Pa and a flat frequency response from 300 to 900 Hz with fluctuation below 1 dB. Moreover, a double channel differential T-type photoacoustic cell is designed and employed in the all-optical PAS gas sensor, with the first-order resonant frequency of 610 Hz. The all-optical gas sensor is established and verified for CH4 detection and the normalized noise equivalent absorption (NNEA) is 4.42 × 10−10 W∙cm−1∙Hz−1/2. The minimum detection limit (MDL) of 36.45 ppb is achieved with a 1 s integration time. The MDL could be further enhanced to 4.87 ppb with an integration time of 81 s, allowing ultra-sensitive trace gas detection.