40 results on '"Solans, Xavier"'
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2. Cyclopalladation of Schiff Bases from Methyl Esters of α-Amino Acids. Unexpected Activation of the O−Me Bond with Formation of a Bianionic Tridentate Metallacycle
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3. Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCH═N-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4), n = 2 or 1, and R1 = H or Ph}
4. Synthesis and Reactivity of P-Chiral Tethered (η1:η6-phosphinoarene)ruthenium Complexes
5. Highly Efficient Pyridylpyrazole Ligands for the Heck Reaction. A Combined Experimental and Computational Study
6. Imidazolium−Calix[4]arene Molecular Frameworks: Bis(N-heterocyclic carbenes) as Bidentate Ligands
7. New (η3-Allyl)palladium Complexes with Pyridylpyrazole Ligands: Synthesis, Characterization, and Study of the Influence of N1 Substituents on the Apparent Allyl Rotation
8. A Comparative Study of the Chelating Ability of the −N(R)−(CH2)n−CO−N(R)2 Framework in σ-Aryl Palladium(II) Complexes Derived from 2-Iodoanilines and 2-Iodobenzylamines. Synthesis of New Types of Terdentate [C,N,O] Pd(II) Complexes and C,N-Bridged Binuclear Pd(II) Compounds
9. Novel Palladacycles Containing [C(sp2, ferrocene), N, O]- or [C(sp2, ferrocene), N, O]2- Terdentate Ligands
10. Allylpalladium Complexes with P-Stereogenic Monodentate Phosphines. Application in the Asymmetric Hydrovinylation of Styrene
11. Compound [PtPh2(SMe2)2] as a Versatile Metalating Agent in the Preparation of New Types of [C,N,N‘] Cyclometalated Platinum Compounds
12. Synthesis and Reactivity of Four-Membered Azapalladacycles Derived from N,N-Dialkyl-2-iodoanilines: Insertion Reactions of Carbenes into the Carbon−Palladium Bond
13. Novel Five-Membered Pallada- and Platinacycles Containing a [C(sp2, ferrocene), N, S]- Terdentate Ligand. Theoretical Interpretation of Their Electrochemical and Electronic Properties Based on Density Functional Calculations
14. Comparative Study of the Reactivity of Cyclopalladated Compounds Containing [C(sp2,ferrocene),N,N‘]- Terdentate Ligands versus Symmetric Alkynes
15. Reactivity of [ClCCo3(CO)9] with Metal Iron Carbonyl Clusters. Formation of Carbide and Dicarbide Mixed Metal Clusters
16. Preparation of Metallacycles with Anionic Terdentate [C,N,N‘] Ligands by Intramolecular Oxidative Addition of C−X (X = Br, Cl) Bonds to [Pt(dba)2]. An Unexpected Effect of Chloro Substituents
17. Unexpected Formal Aryl Insertion in a Cyclometalated Diphenylplatinum(IV) Complex: The First Seven-Membered Cyclometalated Platinum Compound Structurally Characterized
18. Electrophilic Additions of Metal Fragments Containing 11- and 12-Group Elements to the Anion Carbide Cluster [Fe5MoC(CO)17]2-. X-ray Crystal Structures of (NEt4)[Fe5MoAuC(CO)17(PMe3)] and [Fe5MoAu2C(CO)17(dppm)]
19. Activation of σ(C−H) Bonds in C6H5CHNCH2CH2SEt Induced by Platinum(II). X-ray Crystal Structure of [Pt{C6H4CHNCH2CH2SEt}Cl]
20. Heterodi- and Heterotrimetallic Compounds Containing Five-Membered Rings and σ(Pd−Csp2, ferrocene) Bonds. X-ray Crystal Structure of the meso-Form of [Pd2{Fe[(η5-C5H3)−C(CH3)N−C6H5]}2Cl2(PPh3)2]
21. A New Reagent for Chiral Recognition Containing a Five-Membered Palladacycle with a σ(Pd-Csp2,ferrocene) Bond
22. Activation of C−F and C−H Bonds by Platinum in Trifluorinated [C,N,N‘] Ligands. Crystal Structures of [PtFMe2{Me2NCH2CH2NHCH(CH2COMe)(2,4-C6H2F2)}] and [PtMe{Me2NCH2CH2NCH(2,3,4-C6HF3)}]
23. Preparation of Five-Membered Nickelacycles with Anionic C−N−N‘ Terdentate Ligands. X-ray Crystal Structure of [NiCl{2-(CHNCH2CH2NMe2)-3-ClC6H3}]
24. Mechanism of the Insertion Reactions of Alkynes with Phosphanickelacycles
25. Preparation of Five-Membered Nickelacycles of N-Donor Ligands by Activation of C-X Bonds (X = F, Cl, or Br). X-ray Crystal Structure of [NiBr{2-(CH:NCH2Ph)C6H4}(2,4,6-Me3C5H2N)]
26. Optically Active Exocyclic Cyclopalladated Derivatives of Benzylidene-(R)-(1-phenylethyl)amines: Syntheses and X-ray Molecular Structures of [Pd(2-{(E)-(R)-CHMeN:CH-2',6'-Cl2C6H3}C6H4)Cl(PPh3)] and [Pd(2-{(Z)-(R)-CHMeN:CH-2',6'-F2C6H3}C6H4)I(PPh3)]
27. Cyclometalated Platinum(II) Compounds with Fluorinated Iminic Ligands: Synthesis and Reactivity Tuning. Crystal Structures of the Compounds [PtMe(RCH:NCH2C6H5)(PPh3)] (R = 2,3,4-C6HF3 and 2,3-C6H2F2)
28. Electrophilic Additions of AuPR3+ and Au2(.mu.-L)2+ (L = Diphosphine) Units to the [Fe3(CO)11]2- Anion
29. Cyclometalated complexes of palladium(II) and platinum(II) with N-benzyl- and N-(phenylethyl)-.alpha.-benzoylbenzylideneamine. Delocalization in the cyclometalated ring as a driving force for the orthometalation
30. Syntheses and mechanistic studies in the formation of endo- and exo-cyclometalated platinum compounds of N-benzylidenebenzylamines
31. Stoichiometric model reactions in olefin hydroformylation by platinum-tin systems
32. Trialkylphosphine-carbon disulfide adducts as eight-electron bridging ligands. X-ray structures of dimanganese complex [Mn2(CO)6(.mu.-S2CPCy3)] and [Mn2(CO)4(.mu.-S2CPCy3)(.mu.-dppm)]
33. Five- and six-membered exo-cyclopalladated compounds of N-benzylideneamines. Synthesis and x-ray crystal structure of [cyclic] [PdBr{p-MeOC6H3(CH2)2N:CH(2,6-Cl2C6H3)}(PPh3)] and [PdBr{C6H4CH2N:CH(2,6-Cl2C6H3)}(PEt3)2]
34. Carbon-carbon bond formation at a dinuclear iron center. 4. Synthesis of [Fe2(CO)6(.mu.-C(OR)H)(.mu.-CR'=CR'H)]- anions (R = Me, Et; R' = Ph, H) and the subsequent formation by protonation of the bridging vinylcarbene ligands >CHCR'=CR'H or >CR'CH=CR'H, depending on the reaction conditions
35. Study of the reactivity of [Fe2(CO)6(.mu.-CO)(.mu.-CPhCPhH)]- toward the MeOC(O)C.tplbond.CC(O)OMe and CF3C.tplbond.CCF3 alkynes. Crystal structure of the products resulting from two different modes of combination of the alkynes with the bridging ligands [Fe2(CO)6(.mu.-C(C(O)OMe)C(C(O)OMe)C(O)CPhCPhH)]- and [Fe2(CO)6(.mu.-CPhCPhC(CF3)C(CF3)H)]-
36. Synthesis of arylrhodium(III) complexes using organomercury compounds. (o-Nitrophenyl)rhodium(III) complexes. Crystal and molecular structures of chlorobis(2-nitrophenyl-C1,O)(triphenylphosphine)rhodium and chlorobis(2-nitrophenyl-C1,O)carbonylrhodium
37. Reactions of Ru(CO)HCl(PPh3)3 with activated mono- and disubstituted acetylenes. Crystal structure of [cyclic] [(PPh3)2(CO)(MeO2CC.tplbond.C)Ru(MeOOCC:CHCH:CHCO2Me)]
38. Synthesis of heterotrinuclear complexes containing platinum-mercury-metal (metal = Mo, W) chains via platinum(0) insertion reactions. Crystal structure of (PPh3)2(C6Cl5)Pt-Hg-W(CO)3(.eta.-C5H5)
39. Synthesis and reactivity of (chlorovinyl)nickel complexes: an unusual symmetrization reaction. X-ray crystal structure of [Ni(CCl:CCl2)2(PMe2Ph)2]
40. Competitive metalation reactions between aliphatic and aromatic carbon atoms in N-benzylideneamines. X-ray molecular structure of [Pd[1-CH2-2-(HC:NPh)-3,5-(CH3)2C6H2]BrPPh3]
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