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Start Over Author "Gerardo S. Bodner" Journal organometallics
7 results on '"Gerardo S. Bodner"'

1. Mechanism of isomerization of rhenium alkylidene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(:CRCHR'R')]+X- to alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(RHC:CR'R')]+X-: an organometallic Wagner-Meerwein-type rearrangement

Author

Gerardo S. Bodner, Christophe Roger, John A. Gladysz, and William G. Hatton

Subjects
Inorganic Chemistry, chemistry.chemical_classification, Wagner–Meerwein rearrangement, Reaction mechanism, chemistry, Stereochemistry, Alkene, Organic Chemistry, chemistry.chemical_element, Physical and Theoretical Chemistry, Rhenium, Isomerization
Published
1991
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2. Synthesis, structure, and reactivity of chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)PPh3)(H2C:CHR)]+ X

Author

John A. Gladysz, Atta M. Arif, Tang Sheng Peng, and Gerardo S. Bodner

Subjects
chemistry.chemical_classification, Chemistry, Alkene, Stereochemistry, Organic Chemistry, chemistry.chemical_element, Nuclear magnetic resonance spectroscopy, Crystal structure, Rhenium, Inorganic Chemistry, Crystallography, X-ray crystallography, Molecule, Reactivity (chemistry), Physical and Theoretical Chemistry
Published
1990
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3. Synthesis, structure, and reactivity of the chiral rhenium phenyl complex (.eta.5-C5H5)Re(NO)(PPh3)(C6H5)

Author

Sename K. Agbossou, John A. Gladysz, Gerardo S. Bodner, and Alan T. Patton

Subjects
Inorganic Chemistry, chemistry, Stereochemistry, Organic Chemistry, X-ray crystallography, chemistry.chemical_element, Molecule, Reactivity (chemistry), Crystal structure, Physical and Theoretical Chemistry, Rhenium, Medicinal chemistry, Monoclinic crystal system
Abstract

Reaction of (η 5 -C 5 H 5 )Re(NO)(PPh 3 )(Cl) and C 6 H 5 Cu gives chiral, racemic phenyl complex (η 5 -C 5 H 5 )-Re(NO)(PPh 3 )(C 6 H 5 ), which undergoes a spontaneous resolution when crystallized from CH 2 Cl 2 /hexanes. Crystal structure monoclinic, P2 1

Published
1990
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4. Electrochemical oxidation of rhenium alkyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(R): evidence for one-electron charge transfer

Author

Gerardo S. Bodner, Merete. Folmer Nielsen, Vernon D. Parker, and John A. Gladysz

Subjects
chemistry.chemical_classification, Organic Chemistry, Inorganic chemistry, chemistry.chemical_element, Chronoamperometry, Rhenium, Electrochemistry, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Transition metal, Physical chemistry, Physical and Theoretical Chemistry, Triphenylphosphine, Cyclic voltammetry, Acetonitrile, Alkyl
Published
1987
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5. Electrochemical oxidation of rhenium alkyl complexes of the type [Re(.eta.-C5H5)(NO)(PPh3)R]: implications for the mechanism of hydride abstraction by Ph3C+PF6

Author

Marianna F. Asaro, Stephen R. Cooper, Gerardo S. Bodner, John A. Gladysz, and N. John Cooper

Subjects
chemistry.chemical_classification, Cyclopentadiene, Hydride, Organic Chemistry, Inorganic chemistry, chemistry.chemical_element, Rhenium, Electrochemistry, Medicinal chemistry, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Physical and Theoretical Chemistry, Triphenylphosphine, Inorganic compound, Alkyl
Abstract

Donnees obtenues sur l'oxydation electrochimique de 12 complexes du type [Re(η-C 5 H 5 )(PPh 3 )(NO)R] avec R=CH 3 , CH 2 -CH 3 , CH 2 CH 2 Ph, etc, dans CH 2 Cl 2 , par voltammetrie cyclique

Published
1985
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7. Crystallographic and theoretical analyses of the structures of rhenium formyl and acyl complexes of the formula (.eta.5-C5H5)Re(NO)(PR3)(COR')

Author

Charles E. Strouse, John A. Gladysz, Savas Georgiou, Gerardo S. Bodner, Wai-Kwok Wong, Wilson Tam, Alan T. Patton, and Danny E. Smith

Subjects
chemistry.chemical_classification, Organic Chemistry, chemistry.chemical_element, Crystal structure, Rhenium, Inorganic Chemistry, chemistry.chemical_compound, Crystallography, chemistry, X-ray crystallography, Molecule, Physical and Theoretical Chemistry, Triphenylphosphine, Inorganic compound
Abstract

[(η 5 -C 5 H 5 )Re(NO)(PPh 3 )(CHO)] cristallise dans le systeme monoclinique, groupe d'espace P2 1 /c et sa structure est affinee jusqu'a R=0,044, [(η 5 -C 5 H 5 )Re(NO)(PPh 3 )(COCH(CH 3 )CH 2 C 6 H 5 )•(THF) 0,5 (2•(THF) 0,5 )] cristallise dans le systeme triclinique, groupe d'espace P1 avec R=0,040

Published
1987
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