Search

Your search keyword '"David L. Thorn"' showing total 9 results
Start Over Author "David L. Thorn" Journal organometallics
9 results on '"David L. Thorn"'

1. Single-Crystal X-ray and Solution 13C NMR Study of Fluoro(p-nitrophenyl)bis(triphenylphosphine)palladium(II). Are There Effects of Through-Conjugation?

Author

David L. Thorn, William J. Marshall, and Vladimir V. Grushin

Subjects
Inorganic Chemistry, chemistry.chemical_compound, Crystallography, chemistry, Organic Chemistry, X-ray, chemistry.chemical_element, Physical and Theoretical Chemistry, Carbon-13 NMR, Triphenylphosphine, Photochemistry, Single crystal, Palladium
Abstract

The Pd−F and Pd−C bond distances in the X-ray structure of trans-fluoro(p-nitrophenyl)bis(triphenylphosphine)palladium(II), 1, are shorter by ca. 0.036 and 0.013 A, respectively, than those in the ...

Published
1998
Full Text
View/download PDF

2. Ligand Metalation in Triisopropylphosphine−Platinum(II) Compounds

Author

David L. Thorn

Subjects
Ligand, Metalation, Organic Chemistry, chemistry.chemical_element, Medicinal chemistry, Triisopropylphosphine, Methane, Catalysis, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Organic chemistry, Physical and Theoretical Chemistry, Platinum
Abstract

The compound trans-(methyl)(trifluoromethanesulfonato)(bis(triisopropylphosphine))platinum(II) (1) is stable in solution at room temperature, but when treated with a catalytic amount of HCl, it undergoes rapid loss of methane and forms the metalated compound (triisopropylphosphine)(trifluoromethanesulfonato)(2,2-diisopropyl-3-methyl-1-platina-2-phosphacyclobutane) (2). The key intermediate is trans-chloro(trifluoromethanesulfonato)(bis(triisopropylphosphine))platinum(II) (3), which rapidly undergoes metalation with loss of trifluoromethanesulfonic acid.

Published
1998
Full Text
View/download PDF

3. Syntheses and reactions of a cationic hydrido(hydroxymethyl)iridium complex. The crystal and molecular structure of hydrido(hydroxymethyl)tetrakis(trimethylphosphine)iridium(III) hexafluorophosphate, [IrH(CH2OH) (PMe3)4][PF6]

Author

David L. Thorn and Thomas H. Tulip

Subjects
Chemistry, Organic Chemistry, Trimethylphosphine, Cationic polymerization, chemistry.chemical_element, Inorganic Chemistry, Crystal, chemistry.chemical_compound, Hexafluorophosphate, Polymer chemistry, Organic chemistry, Molecule, Hydroxymethyl, Iridium, Physical and Theoretical Chemistry
Published
1982
Full Text
View/download PDF

6. Ligand exchange reactions of iridium hydrido formyl compounds

Author

D. C. Roe and David L. Thorn

Subjects
Inorganic Chemistry, chemistry.chemical_compound, Isotopes of carbon, Chemistry, Ligand, Organic Chemistry, Polymer chemistry, Trimethylphosphine, chemistry.chemical_element, Organic chemistry, Iridium, Physical and Theoretical Chemistry
Published
1987
Full Text
View/download PDF

7. Conversion of a (methoxymethyl)iridium(I) acetylene complex to a metallacyclobutene iridium(III) complex. Crystal and molecular structures of Ir(CH2OMe)(p-tol-C.tplbond.C-p-tol)(PMe3)3 and [cyclic] fac-Ir[CH2C(p-tol):C(p-tol)]Br(PMe3)3 (p-tol = p-tolyl)

Author

D. C. Roe, Thomas H. Tulip, David L. Thorn, and Joseph C. Calabrese

Subjects
Inorganic Chemistry, Crystal, chemistry.chemical_compound, Acetylene, Stereochemistry, Chemistry, Organic Chemistry, chemistry.chemical_element, Iridium, Physical and Theoretical Chemistry
Published
1984
Full Text
View/download PDF

8. Coupling of iridium-bound methylene with ethylene

Author

David L. Thorn

Subjects
Inorganic Chemistry, Coupling (electronics), chemistry.chemical_compound, Ethylene, chemistry, Organic Chemistry, chemistry.chemical_element, Iridium, Physical and Theoretical Chemistry, Methylene, Photochemistry
Published
1982
Full Text
View/download PDF

9. Reactions of a methyl(methoxymethyl)rhodium(III) complex. The .alpha.-carbon-hydrogen and carbon-oxygen bond cleavage and carbon-carbon bond formation

Author

David L. Thorn

Subjects
chemistry.chemical_classification, Hydrogen, Organic Chemistry, Inorganic chemistry, Trimethylphosphine, chemistry.chemical_element, Medicinal chemistry, Rhodium, Inorganic Chemistry, Alpha cleavage, chemistry.chemical_compound, chemistry, Carbon–carbon bond, Physical and Theoretical Chemistry, Carbon, Bond cleavage, Carbon–oxygen bond
Published
1985
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results