Search

Your search keyword '"Wang, Xue-Qi"' showing total 4 results
Start Over Author "Wang, Xue-Qi" Journal organic letters
4 results on '"Wang, Xue-Qi"'

4. Iron-Catalyzed Alkoxyl Radical-Induced C-C Bond Cleavage/ gem -Difluoroalkylation Cascade.

Author

Zhang TY, Wu Y, Liu S, Tao JQ, Yang X, Wang XQ, Duan XH, and Guo LN

Subjects
Lactones, Catalysis, Iron, Ketones
Abstract

An inexpensive iron-catalyzed alkoxyl radical-induced C-C bond cleavage/ gem -difluoroalkylation cascade is presented. Regulated by the structure of alkoxyl radical precursors, fluorinated distal diketones were synthesized through a ring-opening strategy and difluoroalkylated medium-sized lactones and macrolactones were constructed via a ring-expansion strategy. Both protocols proceeded under mild and redox neutral conditions with a broad substrate scope and good functional group compatibility.

Published
2023
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results