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1. Synthesis of an orthogonally protected precursor to the glycan repeating unit of the bacterial cell wall.

Author

Saha SL, Van Nieuwenhze MS, Hornback WJ, Aikins JA, and Blaszczak LC

Subjects
Cell Wall chemistry, Indicators and Reagents, Oxidation-Reduction, Bacteria chemistry, Disaccharides chemical synthesis, Diterpenes chemical synthesis, Peptidoglycan chemistry
Abstract

[reaction: see text]. A synthesis of stereochemically pure and orthogonally protected N-acetyl-(2-deoxy-2-aminoglucopyranosyl)-beta-[1,4]-N-acetylmuramyl (NAG-NAM) monopeptide (2), the glycopeptide core of lipid II and of the bacterial cell wall repeating unit, is reported.

Published
2001
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