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1. Synthesis of sulfones from organozinc reagents, DABSO, and alkyl halides.

Author

Rocke BN, Bahnck KB, Herr M, Lavergne S, Mascitti V, Perreault C, Polivkova J, and Shavnya A

Subjects
Molecular Structure, Sulfones chemistry, Dapsone chemistry, Hydrocarbons, Halogenated chemistry, Organometallic Compounds chemistry, Sulfones chemical synthesis, Zinc chemistry
Abstract

Organozinc reagents react with the SO2 surrogate DABSO, and the resulting zinc sulfinate salts are alkylated in situ to afford sulfones. This transformation has a broad scope and is compatible with a wide range of structural motifs of medicinal chemistry relevance including nitrile, secondary carbamates, and nitrogen-containing heterocycles.

Published
2014
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