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Start Over Author "Inhee Cho" Journal organic letters
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1. Bidirectional metalation of hydrobenzoin: direct access to new chiral ligands and auxiliaries

Author

Inhee Cho, Robert Britton, and Labros Meimetis

Subjects
Molecular Structure, Ligand, Stereochemistry, Metalation, Organic Chemistry, Diol, Enantioselective synthesis, Stereoisomerism, Ligands, Biochemistry, Combinatorial chemistry, Catalysis, chemistry.chemical_compound, Benzoin, chemistry, Physical and Theoretical Chemistry
Abstract

A bidirectional ortho metalation of the readily available chiral diol hydrobenzoin has been developed that provides direct access to new ortho-functionalized hydrobenzoin derivatives. This one-pot procedure should broaden the utility of hydrobenzoin as an auxiliary and ligand in asymmetric synthesis.

Published
2009

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