1. Geochemical assessment of oils from the Mero Field, Santos Basin, Brazil.
- Author
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Rocha, Ygor dos Santos, Pereira, Rosana Cardoso Lopes, and Mendonça Filho, João Graciano
- Subjects
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PETROLEUM , *CARBON isotopes , *ANALYTICAL geochemistry , *HEAVY oil - Abstract
Highlights • Petroleomics of crude oils recovered from the Mero Field, Santos Basin, Brazil. • The samples were generated under a thermal condition related to the peak of the oil window (0.7–0.9%Ro). • The samples were generated by a source-rock deposited in a lacustrine environment. • ESI FT-ICR MS is a trustworthy way to achieve a geochemical assessment. Abstract Three crude oils recovered from three different wells of the Mero Field in the pre-salt of the Santos Basin were selected for detailed geochemical analysis. The samples were analyzed using a 7.2 T LTQ FT-ICR MS instrument by negative electrospray ionization (–ESI), focusing on the polar compounds, i.e., nitrogen-, sulfur-, and oxygen-containing compounds (NSO). Additionally, a combination of traditional geochemical methods including GC-FID, GC-MS, and carbon isotopic composition (whole oil and n -alkanes) were used to assess the samples. Through this work, it was demonstrated that –ESI FT-ICR MS is a reliable method for assessing crude oil composition and providing information about the origin and thermal maturity of the samples. Results showed that the dominant heteroatom classes are N 1 , O 2 , N 1 O 1 , and O 1. Due to the similarity of double bound equivalent (DBE), which means number of unsaturation present in an organic molecule, and carbon number distributions for the N 1 class species it is possible to suggest that Mero's filling history had an oil charge representing the peak of the oil window (0.7–0.9 %Ro) and that the oils were generated by a source rock deposited in a lacustrine environment. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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