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• CH 4 was generated by the thermal decomposition of the carbonaceous wall-rocks. • CH 4 added, which contributed to the system from oxidized to reduced conditions. • Ore elements were deposited via fluid boiling process. High f O 2 conditions characterize the majority of global porphyry copper deposits and contain highly oxidized minerals, such as magnetite and anhydrite. In contrast, the No. 1 porphyry Cu–Au deposit in the Xiongcun district (Tibet, China) has abundant pyrrhotite, reduced fluids (CH 4 ≫ CO 2), and a relative lack of highly oxidized minerals, which are indicative of low f O 2 conditions. Scanning electron microscopy, fluid inclusion, C–H–O–He–Ar isotopes, and whole-rock organic carbon contents and isotope analysis were used to constrain the evolution of ore-forming fluid, the origin of CH 4 and metal deposition mechanisms for the No. 1 deposit. The He–Ar isotopic compositions (3He/4He = 0.11–0.96 Ra, 40Ar/36Ar = 418.7–2920.2) suggest that the ore-forming fluids predominantly derived from crust source with minor mantle input. The H–O isotopic analysis results (δ18O H2O = −1.8 to +5.2‰, δD = −106 to −89.9‰) indicate that the ore-forming fluids were derived from a magmatic source that mixed with some meteoric waters. The element compositions of zircons and fluid/melt inclusions from the mineralized Middle Jurassic quartz diorite porphyry reveal that the primary magma was characterized by high log f O 2 (>NNO) conditions. The quartz diorite porphyry intruded into the carbon-bearing wall rocks produced abundant CH 4 by thermal decomposition of organic matter (δ13C CH4 = −26.3 to −28.5‰), which changed the redox state of the porphyry copper system from oxidized to reduced condition. Ore elements were deposited via fluid boiling as a consequence of the rapid decrease in temperature and pressure. [ABSTRACT FROM AUTHOR]