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Droplet deformation and alignment are achieved in holographic polymer-dispersed liquid-crystal reflection gratings by applying an in situ shear during recording. High diffraction efficiency (99%) is obtained for light polarized parallel to the shear, with nearly zero efficiency for perpendicular polarization, and no increase of incoherent scattering. Permanent polarization dependence is related to stress-induced morphology changes of liquid-crystal droplets that are frozen by polymerization. The system is studied by electron microscopy and modeled by anisotropic coupled-wave and scattering theory. The morphology is consistent with the theory of small deformations of liquid droplets in fluid flow. Diffraction efficiency measurements are in agreement with theory incorporating this morphology as well as concomitant orientation and alignment of liquid-crystal molecules.

We report storage and electrical switching of holographic image data in an economical polymer-dispersed liquidcrystal material. The hologram is recorded in a fast, single-step process and can be reversibly erased and restored repeatedly by the application of fields of approximately 10-15 V/ microm, with a response time of 22 micros and a relaxation time of 42 micros. Simple (quasi-sinusoidal) holographic transmission gratings also are studied with switching fields of <5 V/ microm and with response and relaxation times of 25 and 44 micros, respectively.

We have observed double-peaked phase-conjugate pulses in the degenerate four-wave mixing of nanosecond laser pulses in solutions of diphenyl polyenes. We attribute this to the superposition of fast and slow gratings, where the slow grating is due to two-photon absorption. This is supported by the results of time delay and polarization experiments as well as evidence of a second spatial harmonic grating.