201. Enhancement of light absorption in photocatalytic devices with multilayered ultra-thin silver elements
- Author
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Ali Ghaffarinejad, Yadollah Shahamat, and Mohammad Vahedi
- Subjects
Materials science ,Absorption spectroscopy ,business.industry ,Physics::Optics ,02 engineering and technology ,Grating ,021001 nanoscience & nanotechnology ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,010309 optics ,Optics ,Absorption band ,0103 physical sciences ,Photocatalysis ,Optoelectronics ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,0210 nano-technology ,business ,Absorption (electromagnetic radiation) ,Rigorous coupled-wave analysis ,Plasmon ,Excitation - Abstract
In this paper, we propose an effective light trapping mechanism through engineering a silver grating to significantly increase the photocatalytic activity of a TiO2-based system. The presented structure contains an asymmetric ultra-thin multilayer silver stripe. Optical properties of the structure are numerically simulated with the rigorous coupled wave analysis (RCWA) method. Two different symmetric and asymmetric designs are investigated. It is shown that several absorption peaks will appear in the absorption spectrum of the symmetric and asymmetric systems, which are attributed to the excitation of localized SP modes at the silver–TiO2 interface. Moreover, the effects of the incident angle of the sunlight and the geometrical parameters of the asymmetric design are studied to achieve an optimum configuration. It is shown that the absorption band of the structure can be tuned by adjusting the geometrical parameters. Furthermore, the results indicate that the photocatalytic activity of the asymmetric structure is significantly improved compared to the symmetric case. Moreover, the results obtained here clarify the role of plasmon resonances in photocatalytic systems. The proposed plasmonic structure can pave a promising way for designing photocatalytic structures with high performance and low-cost.
- Published
- 2019