1. Judd–Ofelt analysis and radiative properties of LiLa(1−x)Eux(PO3)4.
- Author
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Ferhi, M., Bouzidi, C., Horchani-Naifer, K., Elhouichet, H., and Ferid, M.
- Subjects
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POLYCRYSTALS , *EMISSION spectroscopy , *RADIATIVE transitions , *PHONONS , *RARE earth ions , *POLYPHOSPHATES - Abstract
Judd–Ofelt (J–O) theory has been applied to a series of LiLa 1− x Eu x (PO 3 ) 4 ( x = 5%; 10%; 15%; 20% and 30%) polycrystalline powders based on their emission spectra. J–O intensity parameters Ω λ ( λ = 2, 4) and various radiative properties such as the radiative transition probability ( A ), radiative life time ( τ R ), branching ratio ( β R ) and stimulated emission cross-section ( σ e ) have been determined. The observed trend for J–O parameters ( Ω 2 < Ω 4 ) reveals the ionic character of La(Eu)–O bond as well as the symmetry environment around the Eu 3+ ion in LiLa(PO 3 ) 4 . The experimental decay curves of the 5 D 0 level in LiLa 1− x Eu x (PO 3 ) 4 have a single exponential profile. The registered long life time, low multiphonon relaxation rates ( W NR ), high quantum efficiency ( η ) and the best optical gain parameter ( σ e x τ exp ) have been discussed as function of Eu 3+ concentration, chemical composition and crystal structure of the host matrix and particle-size distribution. A comparative study reveals that LiLa 1− x Eu x (PO 3 ) 4 is promising for use in optical devices as well as for developing visible red lasers to emit at 613 nm. The optical band gap energies of LiLa 1− x Eu x (PO 3 ) 4 have been calculated from the diffuse reflection spectral measurements. The results were discussed as a function of Eu 3+ concentration and compared to reported theoretical results. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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