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Often, the quasi-spherical molecule 1,4-diazabicyclo[2.2.2]octane (2.2.2-dabco) is chosen to prepare switchable materials with a high phase transition temperature. We wished to reduce molecular symmetry but maintain a quasi-spherical shape. Hence, a similar molecule, 1,4-diazabicyclo[3.2.2]nonane (3.2.2-dabcn), was used to react with equimolar amounts of HClO4 or HReO4 in aqueous solution. Two compounds [3.2.2-Hdabcn]X (X = ClO4, 1; ReO4, 2) with high phase-transition points at 418 K for 1 and 394.6 K and 419.2 K for 2, respectively, were isolated, in which one-dimensional cationic chains were connected by different types of hydrogen bonds. Differential scanning calorimetry and dielectric-permittivity measurements revealed that 1 and 2 showed switchable phase transition and dielectric anomalies. Compound 1 also showed a reversible second-harmonic-generation effect. [ABSTRACT FROM AUTHOR]