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Solid supported catalysts such as amines are in high demand for the chemical fixation of CO2 into commodity chemicals. Here, we demonstrate an accelerated platform for 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-ionic liquid (IL) catalyzed CO2 fixation via the grafting of DBU-ILs over magnetically separable Fe3O4 nanoparticles (MNPs). The DBU-ILs were covalently immobilized over Fe3O4 MNPs utilizing the thio–ene reaction of allyl-DBU with –SH modified Fe3O4 MNPs. The DBU-IL-grafted Fe3O4 (Fe3O4@DBU-ILs) materials were characterized by Fourier-transform infrared (FT-IR) spectroscopy, field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and vibrating-sample magnetometry (VSM). TEM revealed that the MNPs have a spherical structure with a particle size of 12–20 nm. VSM showed the gradual decrease in magnetization after stepwise grafting from Fe3O4 to Fe3O4@DBU-ILs. The efficacy of the two different Fe3O4@DBU-ILs, Fe3O4@[HDBU+][TFE−] and Fe3O4@[HDBU+][AcO−] prepared by neutralization of  Fe3O4@DBU with 2,2,2-trifluoroethanol (TFE) and acetic acid (AcOH), was investigated by simultaneous fixation of CO2 into the important heterocyclic compounds quinazoline-2,4(1H,3H)-dione and benzimidazolone. This approach shows excellent recyclability with a nominal decrease (2–3%) in product yields after each cycle. In particular, the energy-dispersive X-ray spectroscopy (EDX) mapping of Fe3O4@[HDBU+][TFE−] used for five cycles demonstrated significant leaching of TFE. Interestingly, after retreatment with TFE, Fe3O4@[HDBU+][TFE−] showed a similar yield to that of a fresh catalyst. [ABSTRACT FROM AUTHOR]